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Abstract The mean crystal size of coarse crystalline products is determined by secondary nucleation and crystal growth. Secondary unclei are mainly produced by contacts of crystals with parts of the crystallizer or with other crystals. As a consequence, attrition effects are very important. In this paper, a model is p…
Compounds Cu(pcpci)Cl (1) and Cu(pcpci)Br (2)[pcpci =N-(2′-pyridylcarbonyl)pyridine-2-carboximidate] are isostructural and crystallize in the monoclinic space group Pc with two formula units in cells of dimensions [(1)/(2)]: a= 3.963(2)/3.888(3), b= 8.48(3)/8.641(3), c= 18.21(12)/17.944(11)Å, and β= 94.9(2)/92.63(6)°.…
A novel silver–copper anionic cluster [Ag6Cu7(C2Ph)14]– has been synthesized from the reaction of [PhC2AgC2Ph]– and a mixture of [AgC2Ph]n and [CuC2Ph]n; its structure constitutes a central linearly co-ordinated copper atom linked through Cu–Ag interactions to three tetranuclear [Ag2Cu2(C2Ph)4] subclusters, and within…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTetrakis(1,3-dithiol-2-ylidene)cyclopentanone: a new electron donor with remarkably low oxidation potentialToyonari. Sugimoto, Yohji. Misaki, Yoshihisa. Arai, Yukishi. Yamamoto, Zenichi. Yoshida, Yasushi. Kai, and Nobutami. KasaiCite this: J. Am. Chem. Soc. 1988, 110, 2, 628…
Studies have been performed to evaluate both the relative amounts and molecular forms of the collagens synthesized by an established line of cultured rat kidney epithelial (clone NRK52E) cells. The collagens secreted into the culture medium and extracted from the cell layers of cultured NRK52E cells were isolated afte…
We present a method for the quantification of the contrast agent iohexol in serum. Iohexol is deiodinated by alkaline hydrolysis and the released iodine subsequently measured according to the ceric arsenite method. The assay requires 50 microliters of serum and has a high capacity as it involves few analytical steps.…
The polypeptide chain of an enzyme is folded so that the necessary functional groups are brought together in the active site. Conformational changes may disrupt this arrangement and cause loss of enzymic activity. The effect of soluble additives on the unfolding process is discussed. Additives may be classified as sub…
The oxidation of L-alanine by permanganate ion in aqueous phosphate buffers is autocatalysed by the inorganic reaction product, a solube form of colloidal manganese dioxide temporarily stabilized in solution by adsorption of phosphate ion on its surface. The rate of the non-catalytic reaction pathway is first-order in…
Anhydrous citric acid and sodium bicarbonate were granulated with ethanol in an extruder. The influence of the following process variables on intragranular porosity and liquid saturation was investigated: powder flow rate, ethanol concentration, screw speed, die plate and screw configuration.Granule porosity was signi…
The X-ray crystal structure of NH4[Ni{S2C2(CN)2}2]·H2O has revealed that the planar [Ni{S2C2(CN)2}2]– anions form an eclipsed equidistant stack structure with a repeat distance of 3.918(8)Å. At 98 K the repeat distance in the stack direction is double that at room temperature indicating that the anions are now associa…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOxidative additions and luminescence involving iridium-gold-iridium chains formed by binding of gold(I) to the metallamacrocycle Ir2Cl2(CO)2[.mu.-Ph2PCH2As(Ph)CH2PPh2]2Alan L. Balch, Jeffrey K. Nagle, Douglas E. Oram, and Philip E. ReedyCite this: J. Am. Chem. Soc. 1988, 110…
Abstract The block copolymer poly(ethylene succinate)‐b‐poly(ethylene glycol) gave fibres that degrade rapidly and no tensile strength remained after 10 days of degradation, whereas fibres of the block copolymer poly(ethylene succinate)‐b‐poly(tetramethylene glycol) degraded more slowly and the tensile strength was lo…
ЗОННЫЙ МЕТАМАГНЕТИЗМ Р. 3. Левитин, А. С. МаркосянСОДЕРЖАНИЕ 1. Введение . . . . . . . . .
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTActive oxygen on Group VIII metals: activation of formic acid and formaldehyde on Pd(100)Scott W. Jorgensen and Robert J. MadixCite this: J. Am. Chem. Soc. 1988, 110, 2, 397–400Publication Date (Print):January 1, 1988Publication History Published online1 May 2002Published in…
ADVERTISEMENT RETURN TO ISSUEPREVArticleAutoxidation of 2,6-di-tert-butylphenol in water catalyzed by cobalt phthalocyaninetetrasulfonate bound to polymer colloidsHayrettin Turk and Warren T. FordCite this: J. Org. Chem. 1988, 53, 2, 460–462Publication Date (Print):January 1, 1988Publication History Published online1…
The preparation and properties of two new mixed valence Mn complexes, Mn2(biphen)2(biphenH)(bpy)2(3) and Mn2O2Cl2(OAc)(bpy)2(2)(bpy = 2,2′-bipyridine, biphenH2= 2,2′-biphenol) are reported; complex (3) has a rare S= 9/2 ground state confirmed by magnetization studies.
The distribution of {110}〈001〉 oriented grains in the primary recrystallized 3% Si–Fe alloy processed by the one-stage cold rolling method were investigated by SEM-ECC-ECP technique and the X-ray diffraction method. The main findings were in the following:(1) {110}〈001〉 oriented grains present below 30 μm from the sur…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotodynamics of nickel-porphyrins in noncoordinating solvents: characterization of d-d excited states using transient Raman spectroscopyE. W. Findsen, J. A. Shelnutt, and M. R. OndriasCite this: J. Phys. Chem. 1988, 92, 2, 307–314Publication Date (Print):January 1, 1988Publ…
In this paper, we investigated the newly found order-disorder ferroelectrics PbHPO4 along with its deuterated analogue PbDPO4. Because the major contribution of the spontaneous polarization is the dipoles forming by the proton (or deuteron) ordering, not the displacements of heavy atoms as in the case of KDP-type crys…
Abstract Strain‐induced crystallization of poly(ether ether ketone) (PEEK) was studied by the use of a parallel plate rheometer. The experimental variables included preheating time, crystallization temperature, and shear rate. The crystallization kinetics were characterized by means of an induction time defined as the…