Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
This paper reports a simple innovative method to align magnetic cellulose fibers by using a simple permanent magnet to fabricate unidirectional magnetic papers. Magnetic cellulose fibers were made by in situ synthesis of magnetite nanoparticles on alpha cellulose pulp extracted from American southern pine. Scanning el…
We recently developed new NMR methods for monitoring the hydrogen exchange rates of tyrosine hydroxyl (Tyr-OH) and cysteine sulfhydryl (Cys-SH) groups in proteins. These methods facilitate the identification of slowly exchanging polar side-chain protons in proteins, which serve as sources of NOE restraints for protein…
Recently, a simple scaling argument was introduced that allows us to map, with some precautions, Brownian and Monte Carlo dynamics for spherical particles. Here, we extend the scaling to study systems that have orientational degrees of freedom and carefully asses its validity over a wide region of temperature and dens…
Cyclometalated Ru(II) complexes having a 3-phenylbenzo[b][1,6]naphthyridine (phbn) ligand have been synthesized and characterized by spectroscopic methods. The photo- and electrochemical redox behavior of the complexes are demonstrated. Complex [Ru(phbn)(bpy)(2)]PF(6) ([1]PF(6)) readily undergoes proton coupled two el…
Under your skin: Carbon plays an important role in the deactivation process of Co-based FT catalysts. Therefore the adsorption behavior of carbon at various coverages on the surfaces and into the first subsurface layers of fcc-Co(111) and fcc-Co(100) (see picture) was calculated by density functional theory (DFT).
We find Cu 2 (AsO 4 )(OH)·3H 2 O (euchroite) is a model compound for the frustrated delta chain which is composed of corner-shairng triangles. Magnetic susceptibility, specific heat, high field magnetization and 1 H-NMR measurements are carried out using natural mineral samples of euchroite to study magnetic propertie…
An investigation of a runaway chemical reaction in the laboratory highlighted the potential hazards of oxidation chemistry involving hydrogen peroxide in the presence of tungsten catalysts. Under the process conditions, a combination of a high adiabatic temperature rise, an unstable target molecule, and a potentially…
Pyrite type SiP(2) is reinvestigated by first principles calculations on various levels of functionals including local density approximation, generalized gradient approximation, Becke-Lee-Yang-Parr hybrid functional, and the Hartree-Fock method. SiP(2) is seen as a model compound with molecular [P-P] entities and [SiP…
A material in which superconducting and magnetic properties coexist is synthesized by the intercalation of single-molecule magnets into the layered structure of a group V metal dichalcogenide. A molecule-based/solid-state hybrid strategy is here employed, proving as a promising chemical approach for preparing new mate…
Motivated by the experimentally observed $\sqrt{5}\ifmmode\times\else\texttimes\fi{}\sqrt{5}$ iron vacancy order and a block-spin antiferromagnetic phase with large magnetic moment in ${\mathrm{K}}_{0.8}{\mathrm{Fe}}_{1.6}{\mathrm{Se}}_{2}$, we study the magnetic phase diagram of an extended ${J}_{1}\ensuremath{-}{J}_…
White-light electroluminescence (EL) from n-type ZnO (n-ZnO)/p-type GaN (p-GaN) heterojunction light-emitting diodes operated at reverse breakdown bias was reported. The n-ZnO epilayers were grown by atomic layer deposition on p-GaN. The electron tunneling from the deep-level states near the ZnO/GaN interface to the c…
Three holocelluloses (i.e., cellulose and hemicellulose fractions) are prepared from softwood and hardwood by the Wise method. These holocelluloses completely dissolve in 8% lithium chloride/1,3-dimethyl-2-imidazolidinone (LiCl/DMI) after an ethylenediamine (EDA) pretreatment. After diluting the holocellulose solution…
Foreshadowing a new selenium modification …︁? Upon treatment of red, amorphous selenium with the silver salts of two large weakly coordinating anions (WCA), the thermodynamically driven formation of [Ag2Se12]2+ occurred. The structure of the dication is an unprecedented D3d-symmetric 14-vertex cage built from six six-…
We derive a realistic spin-orbital model at finite Hund's exchange for alkali hyperoxides. We find that, due to the geometric frustration of the oxygen lattice, spin and orbital waves destabilize both spin and p -orbital order in almost all potential ground states. We show that the orbital order induced by the lattice…
We demonstrate that aldehyde-substituted donor-acceptor cruciforms [1,4-bis(arylethynyl)-2,5-distyrylbenzenes] are useful dosimeters for primary amines, primary diamines, and secondary amines. The 1,n-diamines are particularly reactive towards this dosimeter and can be detected in less than 100 ppm concentration. Usin…
The recent applications and novelties of lanthanide-sensitized luminescence (LSL) as a detection technique in clinical analysis are here reviewed. In LSL, lanthanide ions form complexes with organic compounds; in these complexes, the energy absorbed by the organic chromophore (usually the analyte) at its characteristi…
This paper examines the validity and accuracy of cylindrical shell theories in predicting the critical buckling strains of axially loaded single-walled carbon nanotubes (CNTs). The shell theories considered are the Donnell thin shell theory (DST), the Sanders thin shell theory (SST), and the first-order shear deformat…
We show that in films of strongly coupled PbSe quantum dots multiple electron-hole pairs can be efficiently produced by absorption of a single photon (carrier multiplication). Moreover, in these films carrier multiplication leads to the generation of free, highly mobile charge carriers rather than excitons. Using the…
Highly porous CdTe nanoarchitectures (aerogels) were prepared by sol-gel assembly of discrete nanocrystals followed by supercritical CO(2) drying. CdTe nanocrystal surface functionalization (either phosphine oxide or thiolate) is found to be immaterial to oxidation induced gel formation suggesting that the standard th…
This research work involves the plasma treatment of polyethylene terephthalate fiber to improve performance of various ionic lubricating agents. To do this, polyester fabric was pre-scoured with detergent, treated with atmospheric-air plasma and then coated with anionic, cationic and nonionic emulsions. Chemical and p…