Materials Literature
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The electronic properties of ABX3 (A = Cs, CH3NH3, NH2CHNH2; B = Sn, Pb; X = Cl, Br, I) type compounds in the cubic phase are systematically studied using the first-principles calculations. We find that these compounds have direct band gaps at R point where the valance band maximum is an anti-bonding state of B s-X p…
Calculated energy levels from recent \emph{ab initio} studies of the electronic structure of SrCl$_{2}$:Yb$^{2+}$ and CsCaBr$_{3}$:Yb$^{2+}$ are fitted with a semi-empirical "crystal-field" Hamiltonian, which acts within the model space $4f^{14} + 4f^{13}5d + 4f^{13}6s$. Parameters are obtained for the minima of the p…
Since the discovery of room temperature ferromagnetism in (Ti,Co)O2, the mechanism has been under discussion for a decade. Particularly, the central concern has been whether or not the ferromagnetic exchange interaction is mediated by charge carriers like (Ga,Mn)As. Recent two studies on the control of ferromagnetism…
Cavity growth in ductile metal materials under dynamic loading is investigated via the material point method. Two typical cavity effects in the region subjected to rarefaction wave are identified: (i) part of material particles flow away from the cavity in comparison to the initial loading velocity, (ii) local regions…
We report the development of Co9S8 nanocrystals as a cost-effective cathode material that can be readily combined with spraying techniques to fabricate large-area dye-sensitized solar cell (DSSC) devices and can be further connected with series or parallel cell architectures to obtain a relatively high output voltage…
Although zinc oxide (ZnO) nanoparticles (NPs) have been widely formulated in sunscreens, the relationship between reactive oxygen species (ROS) generation induced by these particles, zinc ions, and cytotoxicity is not clearly understood. This study explores whether these factors can be accurately quantified and relate…
Fe-6.5wt%Si silicon steel has excellent soft magnetic properties, but its ductility in room temperature is near zero. A lot of researchers tried to improve the ductility by adding alloy elements. In this paper, we summarized the action mechanism and the content of these alloy elements according to the overseas and dom…
Fluorinated acrylate emulsion was prepared in the presence of TPG as co-solvent, effects of TPG content to the polymerization stability and monomer conversion of the prepared emulsion was studied by the coagulation ratio and conversion rate, respectively. The hydrophobicity and oleophilicity of the polymer film was st…
Three-dimensional short carbon fiber felt reinforced C/SiC composites were prepared by the liquid silicon infiltration (LSI) process. The influences of different porosity ratios, carbon coating, and heat treatment of C/C substrates, on the properties of C/SiC composites were studied. The optimized porosity ratio is ca…
Cu/SiO 2 catalyst by using Na 2 SiO 3 as the silicon source, and the catalytic activity for 2-butanol dehydrogenation was compared with the conventional traditional industrial catalysts (Cu/Al and Cu/Zn). The catalysts were characterized by FTIR and XRD. The copper hydrosilicate was detected as the main phase in the d…
Carbon Nanotubes (CNTs) are purified by Dynamic-oxidation (D-oxidation) technique to enhance the field emission behavior of CNT field emitters. In D-oxidation method, Carbon-type (C-type) impurities are removed out by selective oxidation by heating at constantly increasing temperature in air. It is observed that the t…
To investigate the biodegradability of PBS, films made of PBS were subjected to enzymatic degradation. The declining thermal stability and XRD diagrams showed that the crystallinity of PBS was reduced after degradation. SEM results confirmed that the mode of enzymatic degradation was surface corrosion. In addition, th…
In the present work, we have prepared ZnO nanoparticles by a two-step mechanochemical synthesis method. The reaction was carried out in a paste state at room temperature with a short grinding time of 20 min. The prepared ZnO nanoparticles were characterized by using x-ray diffraction (XRD), transmission electron micro…
The Al 2 O 3 ceramics with high thermal conductivity prepared the spark plasma sintering (SPS) technology. The structure, image and magnetic properties of the SPS Al 2 O 3 ceramics was characterized by X-ray, field emission scanning electron microscope (FE-SEM) and the vibrating sample magnetometer (VSM) at room tempe…
In this paper, a series of novel halogen compounds, melamine halogen acid salts were directly synthesized by melamine and halogen acid in water phase. The chemical structures of melamine halogen acid salts were characterized by Fourier-transform infrared spectroscopy (FT-IR), elemental analysis and 1 H-NMR. Meanwhile,…
The laponite-poly (L-lactide) composite films are prepared by the method of solution blending with polylactide (PLA) and laponite. The result shows that the homogeneous and smooth composite film is prepared with 1, 4-dioxane. Thermogravimetry analysis (TG) and tensile strength studies demonstrate that the thermal stab…
Shape memory alloys (SMAs) are commonly used in micro-electro-mechanical systems (MEMS). Having the unique shape memory, super-elastic affects and now damping capacity SMAs have become an important smart material for a broad range of engineering applications in last years. Copper based SMAs are promising alloys, based…
Agardite-(Y), with a refined formula of Cu(2+) 5.70(Y0.69Ca0.31)[(As0.83P0.17)O4]3(OH)6·3H2O [ideally Cu(2+) 6Y(AsO4)3(OH)6·3H2O, hexa-copper(II) yttrium tris-(arsenate) hexa-hydroxide trihydrate], belongs to the mixite mineral group which is characterized by the general formula Cu(2+) 6 A(TO4)3(OH)6·3H2O, where nine-…
The evolution of the local Jahn-Teller distortion across the LaMnO3+Δ phase diagram was obtained using the perturbed angular correlation local probe technique. We found that upon doping, the local distortion decreases continuously with increasing doping and that no fully Jahn-Teller distorted Mn(3+)O6 octahedra are ob…
Anionic complex Cs+[EuL4]− (I) is synthesized by the reaction of Eu(NO3)3 · 6H2O with 1-(1,5-dimethyl-1H-pyrazol-4-yl)-4,4,4-trifluorobutane-1,3-dione (HL) and CsOH in an aqueous-alcohol medium. Unstable adduct Cs+[EuL4]− · 2CH2Cl2 (Ia) is obtained from a solution in CH2Cl2. The structure of complex Ia is determined b…