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Direct Solvothermal Synthesis of B/N‐Doped Graphene

Sun‐Min Jung、Eun Kwang Lee、Min Choi 等 10 位作者2014-02-20Angewandte Chemie

Abstract Heteroatom‐doping into graphitic networks has been utilized for opening the band gap of graphene. However, boron‐doping into the graphitic framework is extremely limited, whereas nitrogen‐doping is relatively feasible. Herein, boron/nitrogen co‐doped graphene (BCN‐graphene) is directly synthesized from the re…

Graphene research and applicationsSupercapacitor Materials and Fabrication2D Materials and Applications

Rapid Microwave Synthesis of Graphene Directly on h-BN with Excellent Heat Dissipation Performance

Tianquan Lin、Zhanqiang Liu、Mi Zhou 等 8 位作者2014-02-20ACS Applied Materials & Interfaces

We report a new rapid household microwave method to successfully grow graphene on h-BN flakes without using any catalysts. We obtained a novel uniform multilevel matrix of vertical graphene sheets on h-BN flakes. The unique structure possessed outstanding electron conductivity and thermal properties (29.1 W m(-1) K(-1…

Graphene research and applications2D Materials and ApplicationsBoron and Carbon Nanomaterials Research

Purification of NaYF4-Based Upconversion Phosphors

Alexander Stepuk、Gioele Casola、Christoph M. Schumacher 等 5 位作者2014-02-20Chemistry of Materials

Applications of upconversion phosphors have grown extensively in number during the past decade. Hexagonal sodium yttrium fluoride (β-NaYF 4 ) is known to be one of the best host lattices for upconversion materials. We developed a novel technique for transforming cubic sodium yttrium fluoride (α-NaYF 4 ) phosphors into…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesInorganic Fluorides and Related Compounds

The comparison of differences in flammability and thermal degradation between cotton fabrics treated with phosphoramidate derivatives

Thach‐Mien Nguyen、SeChin Chang、Brian Condon2014-02-20Polymers for Advanced Technologies

The effectiveness of a phosphoramidate tetraethyl piperazine‐1,4‐diyldiphosphoramidate (TEPP) as a flame retardant on cotton twill fabrics was compared with that of a previously studied diethyl 4‐methylpiperazin‐1‐ylphosphoramidate (DEPP). TEPP was formed in a reaction between two phosphonates and a piperazine then co…

Fire dynamics and safety researchFlame retardant materials and properties

Determination of Antimony by Surface-Enhanced Raman Spectroscopy

A. Yu. Panarin、И. А. Ходасевич、O. L. Gladkova 等 4 位作者2014-02-20Applied Spectroscopy

A highly sensitive method for the detection and quantitative evaluation of antimony(III) using the surface-enhanced Raman scattering (SERS) technique is demonstrated. The method is based on the analysis of SERS spectra intensity of antimony bound to phenylfluorone (Sb-PhF). Phenylfluorone is widely used as an organic…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesElectrochemical Analysis and Applications

Optical absorption, induced bleaching, and photoluminescence of CdSe nanoplatelets grown in cadmium octanoate matrix

A. Lyashchova、Andriy Dmytruk、Igor Dmitruk 等 6 位作者2014-02-20Nanoscale Research Letters

CdSe nanoparticles (NPs) are chemically synthesized in thermotropic ionic liquid crystalline (LC) phase of cadmium octanoate that was used as a nanoreactor. The nanocomposite samples are obtained by the rapid cooling of the LC phase to room temperature. Observed doublet structure in absorption spectra of the nanocompo…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNonlinear Optical Materials Studies

A Novel Transparent Cross-Linked Poly(methyl methacrylate)-Based Copolymer with Enhanced Mechanical, Thermal, and Flame-Retardant Properties

Saihua Jiang、Hongyu Yang、Xiaodong Qian 等 10 位作者2014-02-20Industrial & Engineering Chemistry Research

A novel cross-linked poly(methyl methacrylate) (PMMA)-based copolymer was first synthesized by bulk copolymerization of methyl methacrylate (MMA) and 1-oxo-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane-4-acrylate (PEPAA) at low temperature (80 °C), which is a facile and green method. The structure of PEPAA was confirmed…

Polymer Nanocomposites and PropertiesFlame retardant materials and propertiesSynthesis and properties of polymers

Thermodynamic Analysis of an Integrated Gasification Solid Oxide Fuel Cell Plant with a Kalina Cycle

Leonardo Pierobon、Masoud Rokni2014-02-20International Journal of Green Energy

A hybrid plant that consists of a gasification system, solid oxide fuel cells (SOFC) and a simple Kalina cycle (SKC) is investigated. Woodchips are introduced into a fixed bed gasification plant to produce syngas, which is then fed into an integrated SOFC-SKC plant to produce electricity. The pre-treated fuel then ent…

Advancements in Solid Oxide Fuel CellsAdsorption and Cooling SystemsChemical Looping and Thermochemical Processes

Electromagnetic Simulation and Measurement of Carbon Nanotube Thread Dipole Antennas

Steven D. Keller、Amir I. Zaghloul、Vesselin Shanov 等 6 位作者2014-02-20IEEE Transactions on Nanotechnology

The conductivity, current distribution, and radiation efficiency for a variety of dipole antennas constructed from carbon nanotube thread/rope are simulated using Hallén's integral equation for a thin wire applied to the method of moments and are compared to a standard copper wire dipole antenna. Next, the conductivit…

Antenna Design and AnalysisCarbon Nanotubes in CompositesEnergy Harvesting in Wireless Networks

Nanostructured Guidance for Peripheral Nerve Injuries: A Review with a Perspective in the Oral and Maxillofacial Area

Stefano Sivolella、Giulia Brunello、Nadia Ferrarese 等 7 位作者2014-02-20International Journal of Molecular Sciences

Injury to peripheral nerves can occur as a result of various surgical procedures, including oral and maxillofacial surgery. In the case of nerve transaction, the gold standard treatment is the end-to-end reconnection of the two nerve stumps. When it cannot be performed, the actual strategies consist of the positioning…

Nerve injury and regenerationElectrospun Nanofibers in Biomedical ApplicationsSupramolecular Self-Assembly in Materials

Modulating the Electronic Properties of Multimeric Thiophene Oligomers by Utilizing Carbon Nanotube Confinement

Takashi Yumura、Hiroki Yamashita2014-02-20The Journal of Physical Chemistry C

We investigated the arrangement of methyl-terminated terthiophenes inside a nanotube by using density functional theory (DFT) including dispersion corrections. After DFT calculations were conducted, a variety of arrangements of the inner terthiophene chains was found, depending on host-tube diameters and the number of…

Carbon Nanotubes in CompositesMolecular Junctions and NanostructuresFullerene Chemistry and Applications

Negative differential resistance behavior in phosphorus-doped armchair graphene nanoribbon junctions

Yuhong Zhou、Daoli Zhang、Jianbing Zhang 等 5 位作者2014-02-20Journal of Applied Physics

In this present work, we investigate the electronic transport properties of phosphorus-doped armchair graphene nanoribbon (AGNR) junctions by employing nonequilibrium Green's functions in combination with the density-function theory. Two phosphorus (P) atoms are considered to substitute the central carbon atom with th…

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

Extrusion foaming of PHBV

Damian Szegda、Sitthi Duangphet、Jinhua Song 等 4 位作者2014-02-20Journal of Cellular Plastics

This paper reports work on extrusion foaming of poly(3-hydroxybutyrate- co-3-hydroxyvalerate) with a chemical blowing agent based on sodium bicarbonate and citric acid and calcium carbonate nucleation agent. It includes investigations in the effects of rheological behaviour of the polymer, blowing agent, nucleation ag…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysisPolymer Foaming and Composites

ZnS nanoparticles well dispersed in ethylene glycol: coordination control synthesis and application as nanocomposite optical coatings

Yuanrong Cheng、Zhe Lin、Hao Lü 等 5 位作者2014-02-20Nanotechnology

The study of the preparation and application of ZnS nanoparticles (NPs) has been one of the most prominent hotspots in the domain of semiconductor NPs. The ZnS NPs usually exist in two crystallographic forms: zinc blende (cubic) and wurtzite (hexagonal). However, controlled preparation of ZnS NPs with specified crysta…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Osteoconductive Potential of Mesoporous Titania Implant Surfaces Loaded with Magnesium: An Experimental Study in the Rabbit

Silvia Galli、Yoshihito Naito、Johan Karlsson 等 7 位作者2014-02-20Clinical Implant Dentistry and Related Research

BACKGROUND: Mesoporous coatings enable incorporation of functional substances and sustainedly release them at the implant site. One bioactive substance that can be incorporated in mesoporous is magnesium, which is strongly involved in bone metabolism and in osteoblast interaction. PURPOSE: The aim of this experimental…

Bone Tissue Engineering MaterialsMagnesium Alloys: Properties and ApplicationsMagnesium Oxide Properties and Applications

Development and validation of an intrinsic dissolution method for nimodipine polymorphs

Manoela Klüppel Riekes、Gislaine Kuminek、Gabriela Schneider Rauber 等 5 位作者2014-02-20Open Chemistry

Abstract The polymorphs of nimodipine, Modification I (Mod I), the metastable racemate, and Modification II (Mod II), the stable conglomerate, were evaluated by means of the intrinsic dissolution procedure. For this purpose, a hydro alcoholic solution (ethanol:water, 50:50, v/v) was selected as the dissolution medium,…

Drug Solubulity and Delivery SystemsCrystallography and molecular interactionsCrystallization and Solubility Studies

Polyamorphism and Pressure-Induced Metallization at the Rigidity Percolation Threshold in Densified GeSe4 Glass

Bora Kalkan、Ranga Dias、Choong-Shik Yoo 等 5 位作者2014-02-20The Journal of Physical Chemistry C

Chalcogenide glasses with tetrahedral networks can undergo significant densification under pressure owing to their open structures. The structural mechanisms of pressure-induced densification and the corresponding evolution of physical properties of glassy GeSe 4 alloy are studied over pressures ranging between ambien…

Material Dynamics and PropertiesGlass properties and applicationsPhase-change materials and chalcogenides

Porogen Templating Processes: An Overview

Yifeng Hong、Jack G. Zhou、Donggang Yao2014-02-20Journal of Manufacturing Science and Engineering

Porous materials with well-defined pore shapes, sizes and distributions are highly desired in many emerging applications, particularly for biomedical materials and devices. However, conventional methods for processing porous materials only demonstrated limited capability in morphological control. One promising solutio…

Cellular and Composite StructuresElectrospun Nanofibers in Biomedical ApplicationsAdditive Manufacturing and 3D Printing Technologies

Effect of different amounts of modified talc on the mechanical, thermal, and crystallization properties of poly(butylene succinate)

Bingxin Sun、Chengzhi Chuai、Si Luo 等 5 位作者2014-02-20Journal of Polymer Engineering

Abstract Poly(butylene succinate) (PBS) with different ratios of modified talc was prepared by twin-screw extruding. The effect of different loading amounts of talc on the mechanical, thermal, and crystallization properties of PBS was investigated. The mechanical test results indicate that the stiffness of the composi…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Photoluminescence Imaging of SiO2@ Y2O3:Eu(III) and SiO2@ Y2O3:Tb(III) Core-Shell Nanostructures

Insu Cho、Jun‐Gill Kang、Youngku Sohn2014-02-20Bulletin of the Korean Chemical Society

We uniformly coated Eu(III)- and Tb(III)-doped yttrium oxide onto the surface of <TEX>$SiO_2$</TEX> spheres and then characterized them by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction crystallography and UV-Visible absorption. 2D and 3D photoluminescence image map profi…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsLanthanide and Transition Metal Complexes