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Reversible Switch between Bulk MgCO3·3H2O and Mg(OH)2 Micro/Nanorods Induces Continuous Selective Preconcentration of Anionic Dyes

Yongjing Wang、Jingping Chen、Lili Lü 等 4 位作者2013-07-30ACS Applied Materials & Interfaces

It is still a big challenge to treat large amount of water with low concentration of pollutant. In this study, a hierarchical (micro/nano) structured Mg(OH)2 adsorbent was introduced by the in situ hydration of porous MgO in the dye solution. The adsorbent showed high selective adsorption capacity (Q0 ≈ 155 mg/g for a…

Adsorption and biosorption for pollutant removalLayered Double Hydroxides Synthesis and ApplicationsMagnesium Oxide Properties and Applications

Transition-Metal-Substituted Phosphomolybdates: Catalytic and Kinetic Study for Liquid-Phase Oxidation of Styrene

Soyeb Pathan、Anjali Patel2013-07-30Industrial & Engineering Chemistry Research

Mono-transition-metal-substituted phosphomolybdates, PMo 11 M (M = Co, Mn, Ni), were synthesized and characterized by various physicochemical techniques. They were efficiently used for liquid-phase nonsolvent oxidation of styrene under mild reaction conditions. It was found that all of the catalysts are efficient in a…

Polyoxometalates: Synthesis and ApplicationsCatalysis and Oxidation ReactionsChemical Synthesis and Reactions

Zeta Potential, Contact Angles, and AFM Imaging of Protein Conformation Adsorbed on Hybrid Nanocomposite Surfaces

Ana C. Pinho、Ana P. Piedade2013-07-30ACS Applied Materials & Interfaces

The sputtering deposition of gold (Au) and poly(tetrafluoroethylene) (PTFE) was used to prepare a nanocomposite hybrid thin film suitable for protein adsorption while maintaining the native conformation of the biological material. The monolithic PTFE and the nanocomposite PTFE/Au thin films, with Au content up to 1 at…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsNanofabrication and Lithography Techniques

Mesoporous silica with fibrous morphology: a multifunctional core–shell platform for biomedical applications

Timur Sh. Atabaev、Jong-Ho Lee、Jun-Jae Lee 等 7 位作者2013-07-30Nanotechnology

Multifunctional mesoporous silica nanocomposites are attractive carriers for targeted drug delivery in nanomedicine. Although promising developments have been made in the fabrication of multifunctional mesoporous silica nanocomposites, the design and mass production of novel multifunctional carriers are still challeng…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisNanomaterials for catalytic reactions

Effect of Pretreatment of Raw Material on Properties of Particleboard Panels Made from Wheat Straw

Pavlo Bekhta、Süleyman Korkut、Salim Hızıroǧlu2013-07-30BioResources

The objective of this study was to evaluate properties of experimental particleboard panels manufactured from wheat straw that had been pretreated with acetic anhydride, soapy solution, hot water, or steam. Wheat straw particles were mixed with commercially manufactured wood particles at a ratio of 60%. Control straw…

Wood Treatment and PropertiesNatural Fiber Reinforced Composites

Electrolysis and Co‐Electrolysis Performance of SOE Short Stacks

Stefan Diethelm、Jan Van herle、Dario Montinaro 等 4 位作者2013-07-30Fuel Cells

Abstract In this study, two short SOE stacks (6‐cells) were characterized in steam‐electrolysis mode. The first was based on Ni‐YSZ supported cells with LSCF‐based air electrodes. The second included LSC‐based air electrodes specifically developed within the SOFC600 project. The stacks were fed with a 90% steam, 10% h…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsCO2 Reduction Techniques and Catalysts

Highly Uniform α-NaYF4:Yb/Er Hollow Microspheres and Their Application as Drug Carrier

Yunhua Han、Shili Gai、Ping’an Ma 等 7 位作者2013-07-30Inorganic Chemistry

Highly uniform α-NaYF4:Yb/Er hollow microspheres have been successfully prepared via a simple two-step route. First, the core-shell structured MF@Y(OH)CO3:Yb/Er precursor was fabricated by a urea-based homogeneous precipitation method using colloidal melamine formaldehyde (MF) microspheres as template. Then the Y(OH)C…

Luminescence Properties of Advanced MaterialsLuminescence and Fluorescent MaterialsInorganic Fluorides and Related Compounds

Controlled Mesoporosity in SiOC via Chemically Bonded Polymeric “Spacers”

Yigal D. Blum、Gian Domenico Sorarù、Aravind Parakkulam Ramaswamy 等 5 位作者2013-07-30Journal of the American Ceramic Society

Silicon oxycarbides with controlled porosity in the mesopore range have been obtained through high‐temperature pyrolysis of newly developed reactive siloxane formulations. The starting gels have been synthesized via Pt catalyzed hydrosilylation reaction between polyhydromethylsiloxane ( PHMS ) and vinyl‐terminated pol…

Advanced ceramic materials synthesisMesoporous Materials and CatalysisAerogels and thermal insulation

Raman comparison of skin dermis of different ages: focus on spectral markers of collagen hydration

The Thuong Nguyen、Teddy Happillon、Jezabel Feru 等 7 位作者2013-07-30Journal of Raman Spectroscopy

Skin aging is the most visible sign of aging of the body. This complex process involves molecular and structural alterations of the main skin constituents. The major cutaneous constituent is type I collagen that gives strength and resilience to the skin. This macromolecule possesses a particular triple helix structure…

Skin Protection and AgingTextile materials and evaluationsCollagen: Extraction and Characterization

Enhancement of the antibacterial activity of natural rubber latex foam by the incorporation of zinc oxide nanoparticles

W.G.I.U. Rathnayake、H. Ismail、A. Baharin 等 5 位作者2013-07-30Journal of Applied Polymer Science

ABSTRACT The synthesis and characterization of ZnO‐nanoparticle‐incorporated natural rubber latex foam (NRLF) are described in this article. ZnO nanoparticles were added as the primary gelling agent by the replacement of the microsized ZnO particles, whereas the control sample of the NRLF was made without the addition…

Nanoparticles: synthesis and applicationsPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Nitrogen-Doped Porous Carbon Spheres Derived from Polyacrylamide

Xiangying Chen、Chong Chen、Zhong Jie Zhang 等 4 位作者2013-07-30Industrial & Engineering Chemistry Research

Spherical nitrogen-doped porous carbons have been prepared through a template carbonization method, in which polyacrylamide (PAM) serves as carbon and nitrogen sources, and calcium acetate as hard template. It reveals that the mass ratio of polyacrylamide and calcium acetate and the carbonization temperature have cruc…

Supercapacitor Materials and FabricationConducting polymers and applicationsMesoporous Materials and Catalysis

Raman Spectroscopy of Solid Oxide Fuel Cells: Technique Overview and Application to Carbon Deposition Analysis

Robert C. Maher、V. Duboviks、Gregory J. Offer 等 6 位作者2013-07-30Fuel Cells

Abstract Raman spectroscopy is a powerful characterization tool for improving the understanding of solid oxide fuel cells (SOFCs), capable of providing direct, molecularly specific information regarding the physical and chemical processes occurring within functional SOFCs in real time. In this paper we give a summary…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Electronic states in a graphene flake strained by a Gaussian bump

D Moldovan、M. Ramezani Masir、F. M. Peeters2013-07-30Physical Review B

The effect of strain in graphene is usually modeled by a pseudomagnetic vector potential which is, however, derived in the limit of small strain. In realistic cases deviations are expected in view of graphene's very high strain tolerance, which can be up to $25%$. Here we investigate the pseudomagnetic field generated…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Elastic Repulsion from Polymer Brush Layers Exhibiting High Protein Repellency

Yuuki Inoue、Tomoaki Nakanishi、Kazuhíko Ishihara2013-07-30Langmuir

Hydrophilic poly(2-methacryloyloxyethyl phosphorylcholine) (PMPC) and poly(2-hydroxyethyl methacrylate) (PHEMA) brush layers with different thicknesses and graft densities were prepared to construct a model surface to elucidate protein-surface interactions. In particular, we focused on the steric repulsion of hydrophi…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsAdhesion, Friction, and Surface Interactions

Eddy Current Loss Estimation of Edge Burr-Affected Magnetic Laminations Based on Equivalent Electrical Network—Part I: Fundamental Concepts and FEM Modeling

Hamed Hamzehbahmani、Philip Anderson、Jeremy Hall 等 4 位作者2013-07-30IEEE Transactions on Power Delivery

Cutting and punching of the electrical steel can cause edge burrs which lead to interlaminar short circuits between the laminations. In this paper, based on an equivalent electric circuit of the eddy current path, an analytical method has been developed to estimate the eddy current power loss of the magnetic cores, ca…

Magnetic Properties and ApplicationsPower Transformer Diagnostics and InsulationNon-Destructive Testing Techniques

Effect of surface modification of nanofibres with glutamic acid peptide on calcium phosphate nucleation and osteogenic differentiation of marrow stromal cells

Ozan Karaman、Ankur Kumar、Seyedsina Moeinzadeh 等 6 位作者2013-07-30Journal of Tissue Engineering and Regenerative Medicine

Biomineralization is mediated by extracellular matrix (ECM) proteins with amino acid sequences rich in glutamic acid. The objective of this study was to investigate the effect of calcium phosphate deposition on aligned nanofibres surface-modified with a glutamic acid peptide on osteogenic differentiation of rat marrow…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Hierarchically Ordered Nanoporous Pd/SBA-15 Catalyst for the Aerobic Selective Oxidation of Sterically Challenging Allylic Alcohols

Christopher M. A. Parlett、Pooja Keshwalla、Stephen G. Wainwright 等 7 位作者2013-07-30ACS Catalysis

The utility of a hierarchically ordered nanoporous SBA-15 architecture, comprising 270 nm macropores and 5 nm mesopores (MM-SBA-15), for the catalytic aerobic selective oxidation of sterically challenging allylic alcohols is shown. Detailed bulk and surface characterization reveals that incorporation of complementary…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisOxidative Organic Chemistry Reactions

Plasmonic Mesoporous Composites as Molecular Sieves for SERS Detection

Vanesa López‐Puente、Sara Abalde‐Cela、Paula C. Angelomé 等 5 位作者2013-07-30The Journal of Physical Chemistry Letters

Application of surface-enhanced Raman scattering (SERS) spectroscopy to the ultrasensitive analysis of small molecules in biological samples is complicated by signal contamination by ubiquitous macromolecules such as proteins, nucleic acids, or lipids. We present a proof-of-concept study of the application of composit…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesAdvanced Nanomaterials in Catalysis

Multicolor Microscopy and Spectroscopy Reveals the Physics of the One-Photon Luminescence in Gold Nanorods

Frank Wackenhut、Antonio Virgilio Failla、Alfred J. Meixner2013-07-30The Journal of Physical Chemistry C

This work demonstrates for the first time that one-photon luminescence in gold nanorods is an entirely plasmon-induced process. To achieve this goal, we used confocal microscopy in combination with higher order laser modes as well as light spectroscopy. We show that gold nanorod luminescence can be produced in three d…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchNanocluster Synthesis and Applications

Mesostructured Nanomagnetic Polyhedral Oligomeric Silsesquioxanes (POSS) Incorporated with Dithiol Organic Anchors for Multiple Pollutants Capturing in Wastewater

Haibo He、Bin Li、Junping Dong 等 8 位作者2013-07-30ACS Applied Materials & Interfaces

A functionalizable organosiliceous hybrid magnetic material was facilely constructed by surface polymerization of octavinyl polyhedral oligomeric silsesquioxane (POSS) on the Fe3O4 nanoparticles. The resultant Fe3O4@POSS was identified as a mesoporous architecture with an average particle diameter of 20 nm and high sp…

Lanthanide and Transition Metal ComplexesSilicone and Siloxane ChemistryInorganic Fluorides and Related Compounds