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Strong Kleinman-Forbidden Second Harmonic Generation in Chiral Sulfide: La 4 InSbS 9

Hua‐Jun Zhao、Yongfan Zhang、Ling Chen2012-01-10Journal of the American Chemical Society

A new chiral sulfide family, Ln(4)InSbS(9) (Ln = La, Pr, Nd), with its own structure type in space group P4(1)2(1)2 or its enantiomorph P4(3)2(1)2 has been synthesized by solid-state reaction. Remarkably, the La member shows the strongest Kleinman-forbidden second harmonic generation to date, with an intensity 1.5 tim…

High-pressure geophysics and materialsCrystal Structures and PropertiesIron-based superconductors research

Crucial Ignored Parameters on Nanotoxicology: The Importance of Toxicity Assay Modifications and “Cell Vision”

Sophie Laurent、Carmen Burtéa、Coralie Thirifays 等 5 位作者2012-01-10PLoS ONE

Until now, the results of nanotoxicology research have shown that the interactions between nanoparticles (NPs) and cells are remarkably complex. In order to get a deep understanding of the NP-cell interactions, scientists have focused on the physicochemical effects. However, there are still considerable debates about…

Nanoparticle-Based Drug DeliveryNanoparticles: synthesis and applications3D Printing in Biomedical Research

Silk protein fibroin from Antheraea mylitta for cardiac tissue engineering

Chinmoy Patra、Sarmistha Talukdar、Tatyana Novoyatleva 等 8 位作者2012-01-10Biomaterials

The human heart cannot regenerate after an injury. Lost cardiomyocytes are replaced by scar tissue resulting in reduced cardiac function causing high morbidity and mortality. One possible solution to this problem is cardiac tissue engineering. Here, we have investigated the suitability of non-mulberry silk protein fib…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applications

Light-Emitting Two-Dimensional Ultrathin Silicon Carbide

Shisheng Lin2012-01-10OpenAlex

Two-dimensional (2D) atomic crystals, especially graphene, have received much attention. However, the main shortcoming of graphene is its zero band gap. Silicon carbide, composed of silicon and carbon, is a typical wurtzite compound semiconductor, with more than 250 alloy types. Herein, we give some evidence of the so…

Graphene research and applicationsBoron and Carbon Nanomaterials ResearchGraphene and Nanomaterials Applications

Experimental demonstration of terahertz metamaterial absorbers with a broad and flat high absorption band

Li Huang、Dibakar Roy Chowdhury、Suchitra Ramani 等 7 位作者2012-01-10arXiv

We present the design, numerical simulations and experimental measurements of terahertz metamaterial absorbers with a broad and flat absorption top over a wide incidence angle range for either transverse electric or transverse magnetic polarization depending on the incident direction. The metamaterial absorber unit ce…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Magnetic exchange interactions and supertransferred hyperfine fields at119Sn probe atoms in CaCu3Mn4O12

Igor A. Presniakov、V. S. Rusakov、G. Demazeau 等 9 位作者2012-01-09Physical Review B

The double manganite CaCu${}_{3}$Mn${}_{4}$O${}_{12}$ doped with ${}^{119}$Sn atoms (\ensuremath{\sim}1 at.$%$ with respect to manganese atoms) was studied by use of M\"ossbauer spectroscopy. Formally tetravalent Sn${}^{4+}$ ions substitute for isovalent manganese ions in the octahedral (Mn${}^{4+}$O${}_{6}$) polyhedr…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Solubility of Sodium 4-Nitrobenzenesulfonate in Binary Sodium Chloride + Water, Sodium Sulfate + Water, and Ethanol + Water Solvent Mixtures at Elevated Temperatures

Rongrong Li、Ji Lin、Anguo Ying 等 5 位作者2012-01-09Journal of Chemical & Engineering Data

The solubilities of sodium 4-nitrobenzenesulfonate in binary sodium chloride + water, sodium sulfate + water, and ethanol + water solvent mixtures were measured with temperatures ranging from (273.15 to 323.15) K by a steady-state method. Results of these measurements were correlated by a modified Apelblat equation. S…

Ionic liquids properties and applicationsCrystallization and Solubility StudiesChemical and Physical Properties in Aqueous Solutions

Iridium complex probes for monitoring of cellular oxygen levels and imaging of hypoxic tissues

Toshitada Yoshihara、Atsushi Kobayashi、Shinpei Oda 等 6 位作者2012-01-09Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

We have recently reported that a red-emitting iridium complex (btp)<sub>2</sub> Ir (acac) (BTP) serves as a hypoxia-sensing probe for tumor imaging in living mice. BTP exhibits oxygen-sensitive phosphorescence that can be utilized to monitor oxygen levels in living cells and to visualize hypoxic tissues. To improve th…

Nanoplatforms for cancer theranosticsLuminescence and Fluorescent MaterialsAnalytical Chemistry and Sensors

Kinetic study of the RTM6/TiO2 by DSC/TGA for improved hardness of resin

L. Merad、P. Bourson、Y. Guedra 等 5 位作者2012-01-09Journal of the Association of Arab Universities for Basic and Applied Sciences

The aim of this paper is to obtain an epoxy resin with best properties such as good cure of polymer (by using DSC and TGA). The thermal stability and kinetic parameters of epoxy resin RTM6 using non-isothermal thermogravimetry/derivative thermogravimetry (TG/DTG) analysis with a series of different ratios of TiO2-PC50…

Polymer Nanocomposites and PropertiesEpoxy Resin Curing ProcessesThermal and Kinetic Analysis

Capacitor bushing optimization via electrostatic finite element analysis

Amin Mahmoudi2012-01-09International Journal of the Physical Sciences

In high-voltage capacitor bushings, there is maximum field intensity at the edge of the aluminum foil and where foils overlap. Any technique decreasing much field intensity in those regions will significantly optimize the bushings’ electrostatic characteristics. This paper presents the study of the effect of edge dive…

High voltage insulation and dielectric phenomenaVacuum and Plasma ArcsElectromagnetic Launch and Propulsion Technology

Correlation and comparison for solubility of pimelic acid in different solvents

Hua Li、Juan Liu、Jiang Zhu 等 6 位作者2012-01-09Russian Journal of Physical Chemistry A

Based on the solubilities of pimelic acid in ether or tetrahydrofuran or ethanol or methanol, the experimental data were correlated and compared with Apelblat equation, simplified Apelblat equation and λ h equation, respectively. The results showed that the simplified Apelblat equation had better agreement with experi…

Crystallization and Solubility StudiesChemical and Physical Properties in Aqueous SolutionsPharmacological Effects of Natural Compounds

Signatures of the ATP‐binding pocket as a basis for structural classification of the serine/threonine protein kinases of gram‐positive bacteria

Natalia V. Zakharevich、Dmitry I. Osolodkin、Irena I. Artamonova 等 6 位作者2012-01-09Proteins Structure Function and Bioinformatics

Eukaryotic-like serine/threonine protein kinases (ESTPKs) are widely spread throughout the bacterial genomes. These enzymes can be potential targets of new antibacterial drugs useful for the treatment of socially important diseases such as tuberculosis. In this study, ESTPKs of pathogenic, probiotic, and antibiotic-pr…

RNA and protein synthesis mechanismsEnzyme Structure and FunctionBiochemical and Molecular Research

Accurate calculation of the intensity dependence of the refractive index using polarized basis sets

Angelika Baranowska‐Ła̧czkowska、Krzysztof Z. Łączkowski、Berta Fernández2012-01-09The Journal of Chemical Physics

Using the single and double excitation coupled cluster level of theory (CCSD) and the density functional theory/Becke 3-parameter Lee-Yang and Parr (DFT/B3LYP) methods, we test the performance of the Pol, ZPol, and LPol-n (n = ds, dl, fs, fl) basis sets in the accurate description of the intensity dependence of the re…

Advanced Chemical Physics StudiesNonlinear Optical Materials ResearchMolecular spectroscopy and chirality

Super strong nanoindentors for biomedical applications based on the bamboo-like nanotubes

Olga E. Glukhova、А. С. Колесникова、Е. Л. Коссович 等 4 位作者2012-01-09Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

The results of quantum-chemical analysis of elastic and strength properties of the bamboo-like tube are presented in this paper. For the first time the configuration of the thinnest stable bamboo-like tube was established. The bamboo-like nanotube breaking point is established to be under compression of 11GPa. Configu…

Carbon Nanotubes in CompositesAdvanced Theoretical and Applied Studies in Material Sciences and GeometryNanotechnology research and applications

Air Permeability and Acoustic Absorbing Behavior of Nonwovens

Shu Yang & Weidong Yu2012-01-09Journal of Fiber Bioengineering and Informatics

Several nonwovens were studied to explore the relationship between their structural characteristics, permeability and acoustic absorbing behavior. Fundamental structural parameters including thickness, gram square meter and porosity were considered. Results show that the permeability is not just linear to porosity, bu…

Textile materials and evaluationsAerosol Filtration and Electrostatic PrecipitationMaterial Properties and Processing

Mathematical Model of Electric Field Distribution at a Critical State in Bubble Electrospinning

Liang Dong, Yong Liu, Rui Wang, Wei-Min Kang & Bo-Wen Cheng2012-01-09Journal of Fiber Bioengineering and Informatics

Bubble electrospinning is a novel method to produce ultrafine nanofibers. In this work, a mathematical model of the electric field distribution in a critical state was established for bubble electrospinning process and was numerically simulated using finite element method. The results indicated that the maximum electr…

Membrane Separation TechnologiesAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Molecular and Electronic Structure, Magnetotropicity and Absorption Spectra of Benzene–Trinuclear Copper(I) and Silver(I) Trihalide Columnar Binary Stacks

Athanassios C. Tsipis、Alexandros V. Stalikas2012-01-09Inorganic Chemistry

The molecular and electronic structures, stabilities, bonding features, magnetotropicity and absorption spectra of benzene-trinuclear Cu(I) and Ag(I) trihalide columnar binary stacks with the general formula [c-M(3)(μ(2)-X)(3)](n)(C(6)H(6))(m) (M = Cu, Ag; X = halide; n, m ≤ 2) have been investigated by means of elect…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesNanocluster Synthesis and Applications

Aragonitic dendritic prismatic shell microstructure in Thracia (Bivalvia, Anomalodesmata)

António Checa、Elizabeth M. Harper、Marc‐Georg Willinger2012-01-09Invertebrate Biology

Abstract The shells of most anomalodesmatan bivalves are composed of an outer aragonitic layer of either granular or columnar prismatic microstructure, and an inner layer of nacre. The T hraciidae is one of the few anomalodesmatan families whose members lack nacreous layers. In particular, shells of members of the gen…

Paleontology and Stratigraphy of FossilsCalcium Carbonate Crystallization and InhibitionCephalopods and Marine Biology

Ferroelectric phase transition in strained multiferroic (Bi0.9La0.1)2NiMnO6 thin films

Eric Langenberg、Ignasi Fina、P. Gemeiner 等 7 位作者2012-01-09Applied Physics Letters

We report here temperature-dependent x-ray structural and Raman spectroscopy data, on the ferromagnetic double-perovskite (Bi0.9La0.1)2NiMnO6 epitaxial thin films. Results indicate a ferroelectric transition occurring at about 450 °C. Low-temperature polarization loops allow to clearly observing polarization switching…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Surface Photochemistry: 3,3'-Dialkylthia and Selenocarbocyanine Dyes Adsorbed onto Microcrystalline Cellulose

L.F. Vieira Ferreira、Diana P. Ferreira、Paulo Duarte 等 9 位作者2012-01-09International Journal of Molecular Sciences

In this work, thia and selenocarbocyanines with n-alkyl chains of different length, namely with methyl, ethyl, propyl, hexyl and decyl substituents, were studied in homogeneous and heterogeneous media for comparison purposes. For both carbocyanine dyes adsorbed onto microcrystalline cellulose, a remarkable increase in…

Gold and Silver Nanoparticles Synthesis and ApplicationsPhotochemistry and Electron Transfer StudiesLuminescence and Fluorescent Materials