Materials Literature
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The interaction of surface plasmons with surface-optical-phonon modes in the presence of an external dc magnetic field, neglecting the retardation effect, has been studied to investigate the factors which may influence the coupling between the two waves in III-V polar semiconductors. It has been found that the couplin…
The time and temperature dependence of the specific heat of glasses is considered in light of an analytic form for the density-of-states function of two-level systems, N(E), which has recently been calculated. It is shown that experimentally observed time and temperature dependences are explainable with this function…
A structural investigation by x-ray diffraction is presented on ionic conducting glasses of composition (AgI)x (AgPO3)1−x, with x=0.0, x=0.45, and x=0.55. The radial distribution functions of the AgI-doped glasses, calculated from the experimental diffracted intensities, are dominated by a peak centered at about 2.80–…
Refinement and thin film synthesis methods were used by members of six different institutions to design antireflection coatings for germanium substrates. The solutions are based on the use of zinc sulfide and germanium layers only. Several systems were found with an average reflectance that is less than 1% in the 7.7…
The origin and characteristics of the field-off state optical properties of the general twisted nematic liquid-crystal displays (LCD) are discussed. The optical field propagating normally in a uniformly twisted nematic structure can be represented by two mutually orthogonal elliptically polarized normal modes, one wit…
The dynamic structure factor S(q,\ensuremath{\omega}) of electrons in highly oriented pyrolytic graphite for q\ensuremath{\parallel}c and q\ensuremath{\perp}c with 0.37<q<2.06 a.u. was measured at 0.8 eV resolution by inelastic scattering of synchrotron x radiation. The energy-transfer regions both of interband…
We present a Landau theory of the martensitic structural phase transformation undergone by bcc Li into the 9R phase. We propose that the transition occurs via incomplete softening of the ((1/3 1) /3 0) ${\ensuremath{\Sigma}}_{4}$ phonon. Even though this branch does not soften to zero frequency (or even close to zero…
We generalize the Fibonacci Penrose tiling to three classes of one-dimensional, two-tile Penrose tilings which can be obtained geometrically as well as recursively. From a numerical study of their spectral properties, we conclude that the Fibonacci case has the generic features of all three classes. As a model of epit…
We present a valence effective Hamiltonian (VEH) nonempirical investigation of the electronic properties of metal-free phthalocyanine. The valence one-electron energy levels are related to those of the phthalocyanine components: benzene, pyrrole, and isoindole. From the electronic structure standpoint, phthalocyanine…
Mean electronic resonant wavelength of some single substance liquid crystals obtained by ultraviolet transmission spectrum and by wavelength dependent birefringence agrees very well. Both ground and higher state π→π* electronic transitions are found to make a major contribution to the observed birefringence of those l…
Phase transitions of the linear-chain semiconductor (${\mathrm{NbSe}}_{4}$${)}_{3}$I, which occur successively at ${T}_{c1}$=271 K and ${T}_{c2}$\ensuremath{\simeq}100 K, were studied by Raman scattering and electrical resistivity. The resistivity data showed that the band gap increases below ${T}_{c1}$. It was found…
Constraints for quasi-crystals arising from the energetical stability assumption are obtained. For grid models the constraints are expressed in a simple algebraic form (SI-conditions) and applied to planar tilings. SI-conditions allow only for quadratic irrationalities a + b √D ( a, b and D are rational numbers). n -f…
Optical and electro-optic properties of some highly conjugated nematic liquid crystals (LCs): 4-cyano-4′-n-alkyltolanes (n-CDP) and 4-cyano-4′-n-alkylstilbene (n-CS) were studied at elevated temperature. Results are compared with 4-cyano-4′-n-pentylbiphenyl (5CB). These LCs exhibit large birefringence, small viscoelas…
A monomeric arsinogallane containing a covalent gallium-arsenic bond has been prepared, and its molecular structure has been determined by x-ray crystallography. The compound reacted with tert-butanol at ambient temperature to yield the III-V semiconductor gallium arsenide as a finely divided amorphous solid. During t…
A theoretical model is developed to describe the polarization and depinning of charge-density waves (CDW's) in the inorganic linear-chain compounds which exhibit Fr\"ohlich sliding conduction. Each individual impurity within the crystal is assumed to pin the CDW phase very strongly at the impurity site, and dc CDW mot…
We study the short-time collective and self-diffusion coefficients, the rotational self-diffusion coefficient, and the high frequency effective viscosity of a suspension of spherical Brownian particles. At low volume fraction these transport coefficients are given by integrals of hydrodynamic pair interactions. Using…
A remarkable nonlinearity and a switching effect have been observed for electric transport in a tetrathiafulvalene (TTF)-$p$-chloranil crystal. Experimental evidence indicates that these features are of an intrinsic origin associated with the neutral-ionic transition. A possible mechanism is discussed in terms of fiel…
Infinitely degenerate states at an energy E=0 on a two-dimensional Penrose lattice are investigated in a tight-binding model where atomic orbitals are located at vertices of rhombuses. The states with E=0 are all strictly localized and have amplitudes only on some specific vertices, which are three-edge vertices and s…
The large third-order nonlinear optical properties ${\ensuremath{\gamma}}_{\mathrm{ijkl}}(\ensuremath{-}{\ensuremath{\omega}}_{4};{\ensuremath{\omega}}_{1},{\ensuremath{\omega}}_{2},{\ensuremath{\omega}}_{3})$ observed for conjugated organic linear chains, such as polyenes, are explained by strong electron-correlation…
We have derived a nonlocal theory of thermal conductivity for the case in which the heat is carried by phonons. There is a nonlocal relation between the heat current J(r) and the temperature gradient \ensuremath{\nabla}T(r'). The nonlocal theory is needed whenever the phonon mean free path is long compared to the dist…