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Photoreactions of the triruthenium cluster Ru3(CO)12 and substituted analogs

Marc F. Desrosiers、David A. Wink、Ray. Trautman 等 5 位作者1986-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotoreactions of the triruthenium cluster Ru3(CO)12 and substituted analogsMarc F. Desrosiers, David A. Wink, Ray. Trautman, Alan E. Friedman, and Peter C. FordCite this: J. Am. Chem. Soc. 1986, 108, 8, 1917–1927Publication Date (Print):April 1, 1986Publication History Publ…

Catalytic Processes in Materials ScienceAsymmetric Hydrogenation and CatalysisNanocluster Synthesis and Applications

Ordered structure in aqueous polysaccharide. 5. Cooperative order-disorder transition in aqueous schizophyllan

Takashi Itou、Akio Teŕamoto、Takasuke Matsuo 等 4 位作者1986-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOrdered structure in aqueous polysaccharide. 5. Cooperative order-disorder transition in aqueous schizophyllanTakashi Itou, Akio Teramoto, Takasuke Matsuo, and Hiroshi SugaCite this: Macromolecules 1986, 19, 4, 1234–1240Publication Date (Print):April 1, 1986Publication Histo…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsFlowering Plant Growth and Cultivation

Proton and carbon-13 NMR analysis of poly(β-hydroxybutyrate) isolated from Bacillus megaterium

Yoshiharu Doi、Masao Kunioka、Yoshiyuki Nakamura 等 4 位作者1986-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProton and carbon-13 NMR analysis of poly(β-hydroxybutyrate) isolated from Bacillus megateriumYoshiharu Doi, Masao Kunioka, Yoshiyuki Nakamura, and Kazuo SogaCite this: Macromolecules 1986, 19, 4, 1274–1276Publication Date (Print):April 1, 1986Publication History Published o…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionBiopolymer Synthesis and Applications

Interactions Between Acidic Macromolecules and Structured Crystal Surfaces. Stereochemistry and Biomineralization

Lia Addadi、Steve Weiner1986-04-01Molecular crystals and liquid crystals

Some organisms are capable of exerting exquisite control ower the crystals they form. Key components in this process are unusually acidic proteins (aspartic acid-rich). In this study we use a series of calciun dicarboxylic acid salts to investigate in vitro how these proeins are capable of interacting specifically wit…

Calcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation TechniquesGeomagnetism and Paleomagnetism Studies

Physical and electrochemichromic properties of rf sputtered tungsten oxide films

Hirohiko Kaneko、S. Nishimoto、K. Miyake 等 4 位作者1986-04-01Journal of Applied Physics

The physical and electrochemical coloration characteristics of tungsten oxide films rf sputtered from a compressed powder WO3 target have been investigated. Oxide films with 3600–9800 Å thickness were deposited on substrates maintained at 200 °C at a total pressure of 0.5–8×10−2 Torr in Ar gas or an Ar-0.5-50% O2 gas…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Kinetics of phase separation in polymer blends for deep quenches

I. G. Voigt‐Martin、Karl‐Heinz Leister、R. C. Rosenau 等 4 位作者1986-04-01Journal of Polymer Science Part B Polymer Physics

Abstract Electro microscopy was used to study the phase separation kinetics of a polystyrene/polyvinylmethylether system subjected to a critical deep quench. The size of the phase‐separated domains was found to increase linearly with time, implying that hydrodynamic effects control the rate of growth of the domains in…

Corrosion Behavior and InhibitionPolymer crystallization and propertiesBlock Copolymer Self-Assembly

Quantitative electron probe microanalysis of carbon in binary carbides. I—principles and procedures

G. F. Bastin、H. J. M. Heijligers1986-04-01X-Ray Spectrometry

Abstract Introductory investigations performed in order to make quantitative electron‐probe microanalysis of very light elements such as boron, carbon, nitrogen or oxygen possible are described. The practical problems encountered in this kind of work are discussed in detail and, where possible, solutions are proposed.…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesAdvanced Materials Characterization Techniques

Pathways of Smectite Illitization

Craig M. Bethke、Norma Vergo、Stephen P. Altaner1986-04-01Clays and Clay Minerals

Abstract Junction probability diagrams show variation in both composition and layer arrangement in mixed-layer clay minerals. These diagrams can represent short-range and long-range ordered, random, and segregated interstratifications. Mineralogical analyses of illite/smectite from shale cuttings, bentonites, and hydr…

Arsenic contamination and mitigationClay minerals and soil interactionsIron oxide chemistry and applications

Microstructure in Mixed-Layer Illite/Smectite and Its Relationship to the Reaction of Smectite to Illite

Tom Bell1986-04-01Clays and Clay Minerals

Abstract The reaction of smectite to illite in shale from the COST 1 well in the south Texas Gulf Coast and from altered ash-fall tuffs from the Morrison Formation in New Mexico was investigated using X-ray powder diffraction in conjunction with transmission electron microscopy. In the COST 1 well, the bulk of the det…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Transition-metal hydride bond energies: first and second row

J. L. Elkind、P. B. Armentrout1986-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTransition-metal hydride bond energies: first and second rowJ. L. Elkind and P. B. ArmentroutCite this: Inorg. Chem. 1986, 25, 8, 1078–1080Publication Date (Print):April 1, 1986Publication History Published online1 May 2002Published inissue 1 April 1986https://pubs.acs.org/d…

Catalytic Processes in Materials ScienceHydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen Reduction

The n‐Silicon/Thallium(III) Oxide Heterojunction Photoelectrochemical Solar Cell

Jay A. Switzer1986-04-01Journal of The Electrochemical Society

Thallium(III) oxide is a degenerate n‐type semiconductor which can be electrochemically or photoelectrochemically deposited on conducting or semiconducting substrates. The material is highly conductive, transparent, and electrocatalytic. A photoelectrochemical cell consisting of the n‐silicon/thallium(III) oxide photo…

Silicon Nanostructures and PhotoluminescenceSemiconductor materials and interfacesElectron and X-Ray Spectroscopy Techniques

Demixing and gelation behavior of ternary cellulose acetate solutions

A.J. Reuvers、F. W. Altena、C.A. Smolders1986-04-01Journal of Polymer Science Part B Polymer Physics

Abstract The demixing behavior on cooling of ternary systems of cellulose acetate/solvent/water has been examined for CA concentrations up to 40 wt% CA in several solvents. Cloud points have been measured as a function of cooling rate. The rapid process of liquid—liquid demixing can be discriminated from the slow proc…

Advanced Cellulose Research StudiesSurfactants and Colloidal SystemsLignin and Wood Chemistry

Surface Reconstruction on a Clean Si(110) Surface Observed by RHEED

Youiti Yamamoto、Shozo Ino、Toshihiro Ichikawa1986-04-01Japanese Journal of Applied Physics

A “16-structure" was found from careful surface cleaning manners and RHEED observations to be only a superstructure appearing on a clean Si(110) surface. The present work also confirmed clearly that almost all surface structures reported previously were superstructures characteristic of Ni-contaminated Si(110) surface…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

The epoxidation of unsaturated macrolides. Stereocontrolled routes to ionophore subunits

Stuart L. Schreiber、Tarek Sammakia、Bernard Hulin 等 4 位作者1986-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe epoxidation of unsaturated macrolides. Stereocontrolled routes to ionophore subunitsStuart L. Schreiber, Tarek. Sammakia, Bernard. Hulin, and Gayle. SchulteCite this: J. Am. Chem. Soc. 1986, 108, 8, 2106–2108Publication Date (Print):April 1, 1986Publication History Publi…

Polyoxometalates: Synthesis and ApplicationsSynthetic Organic Chemistry MethodsChemical Synthesis and Reactions

Stimulation of Wound Healing by Epidermal Growth Factor

J Niinikoski、Lena Lebel、Bengt Gerdin1986-04-01Annals of Surgery

This work was undertaken to study the effects of various doses of locally applied epidermal growth factor (EGF) on developing granulation tissue in rats. Cylindrical hollow sponge implants were used as an inductive matrix for the growth of granulation tissue. In the test groups, the implants were injected daily with a…

Wound Healing and Treatments3D Printing in Biomedical ResearchSilk-based biomaterials and applications

Magnetic field dependence of solvent proton relaxation rates induced by Gd3+ and Mn2+ complexes of various polyaza macrocyclic ligands: Implications for NMR imaging

Carlos F. G. C. Geraldes、A. Dean Sherry、R. D. Brown 等 4 位作者1986-04-01Magnetic Resonance in Medicine

The magnetic field dependence of the solvent water proton longitudinal relaxation rate 1/T1 (the NMRD profile) has been measured for solutions of chelates of Gd3+ and Mn2+ ions with two different polyaza macrocyclic ligands: 1,4,7-triazacyclononane-N,N',N",-triacetic acid (NOTA) and 1,4,7,10-tetraazacyclododecane-N,N'…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

An AC‐Impedance Study of Electrochemical Processes at Nafion‐Coated Electrodes

Israel Rubinstein、Judith Rishpon、S. Gottesfeld1986-04-01Journal of The Electrochemical Society

The system was investigated by the ac‐impedance method, covering both the semi‐infinite and the finite (very low frequency) diffusion regimes. Upon decreasing the modulation frequency, a transition from semi‐infinite diffusion to finite diffusion is observed, with different apparent diffusion coefficients calculated f…

Fuel Cells and Related MaterialsConducting polymers and applicationsElectrochemical Analysis and Applications

Strain broadening of the dangling-bond resonance at the (111)Si-SiO2interface

K. L. Brower1986-04-01Physical review. B, Condensed matter

It is observed that the linewidth and line shape of the Zeeman resonance associated with dangling bonds at the (111)Si-${\mathrm{SiO}}_{2}$ interface (${P}_{b}$ centers) vary with the direction of the applied magnetic field. An analysis of the line shape of this resonance indicates that it can be represented analytica…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceMagneto-Optical Properties and Applications

Bolaamphiphiles and monolayer lipid membranes made from 1,6,19,24-tetraoxa-3,21-cyclohexatriacontadiene-2,5,20,23-tetrone

J.‐H. FUHRHOP、Hans Hermann David、Joachim Mathieu 等 6 位作者1986-04-01Journal of the American Chemical Society

The title macrotetrolide contains two maleic diester units that add hydrophilic sulfur nucleophiles, e.g., bisulfite, thioacetic acid, and various thioglycosides, in high yield. Two-headed amphiphiles (“bolaamphiphiles” or “bolytes”) are thus formed. They produce extremely thin (hydrophobic part ~20 Å) monolayer lipid…

Porphyrin and Phthalocyanine ChemistrySynthesis and Properties of Aromatic Compounds

Surface structure of segmented poly(ether urethanes) and poly(ether urethane ureas) with various perfluoro chain extenders. An x-ray photoelectron spectroscopic investigation

Sung Chul Yoon、Buddy D. Ratner1986-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSurface structure of segmented poly(ether urethanes) and poly(ether urethane ureas) with various perfluoro chain extenders. An x-ray photoelectron spectroscopic investigationSung Chul Yoon and Buddy D. RatnerCite this: Macromolecules 1986, 19, 4, 1068–1079Publication Date (P…

Synthesis and properties of polymersSilicone and Siloxane ChemistryPhotopolymerization techniques and applications