Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTConcentration Profiles in Ternary Gaseous DiffusionR. Carty and T. SchrodtCite this: Ind. Eng. Chem. Fundamen. 1975, 14, 3, 276–278Publication Date (Print):August 1, 1975Publication History Published online1 May 2002Published inissue 1 August 1975https://pubs.acs.org/doi/10.…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNovel synthesis of longifoleneRobert A. Volkmann, Glenn C. Andrews, and William S. JohnsonCite this: J. Am. Chem. Soc. 1975, 97, 16, 4777–4779Publication Date (Print):August 1, 1975Publication History Published online1 May 2002Published inissue 1 August 1975https://doi.org/1…
The dissociation energy of gaseous ZrO, D0° (ZrO), and the heat of atomization of gaseous ZrO2 have been measured using a high temperature mass spectrometer. A number of equilibria were studied and the following results were derived: ΔfH (ZrO,g,298.15 K) =83±12 kJ/mol, D0° (ZrO) =761±15 kJ/mol) (or 7.89±0.15 eV), ΔfH…
Abstract not Available.
An empirical model has been developed to relate molecular weight distribution to the shear dependence of the steady shear viscosity in high-density polyethylene melts. It uses a molecular weight, Mc, which partitions molecular weights into two classes; those below Mc contribute to the viscosity as they do at zero shea…
Sputter-deposited high-purity copper specimens with grain sizes from 8.4 to 0.056 μm were tested in tension to investigate the influence of grain size on yield strength for small grain sizes. The smallest grain size in the sputter-deposited copper was a factor of 40 smaller than the smallest grain size previously avai…
Abstract The Raman scattering is investigated from five phases of AgI that can be reached with moderate pressure and temperature. Particularly noteworthy is the strong negative pressure coefficient of the 17 cm −1 E 2 mode in the wurtzite phase. Its mode gamma is −7.5. The intensity of this mode decreases above 1 kbar…
Values of crystalline-solid Debye temperatures depend both on the method and temperature of measurement. Simple relationships between Debye temperatures and such cohesive properties as compressibility and melting point were derived over 60 years ago by Madelung, by Einstein, and by Lindemann. Debye temperatures ΘXR of…
The crystal structure of YbFe 2 O 4 was determined and refined by the x-ray method. This compound crystallizes trigonal in the space group R [unk] m with the unit-cell dimensions a = 3.455 ± 0.001, c = 25.054 ± 0.010 Å. The unit cell contains three formula units. The structure consists of the alternating layers of YbO…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAdsorption of hydrogen peroxide on the surface of titanium dioxideA. H. Boonstra and C. A. H. A. MutsaersCite this: J. Phys. Chem. 1975, 79, 18, 1940–1943Publication Date (Print):August 1, 1975Publication History Published online1 May 2002Published inissue 1 August 1975https…
Abstract The mineral in monomineralic glauconite pellets is an iron-rich mixed-layer illite-smectite (here called glauconite), often composed almost entirely of illite layers. The nature of the interlayering is closely analagous to that of aluminous illite-smectite and varies with the proportions of the layer types: &…
Abstract Thermal cis‐trans isomerization and decomposition of polyacetylene film prepared with a Ti(OC 4 H 9 ) 4 –Al(C 2 H 5 ) 3 (Al/Ti = 4) system were investigated under inert gas or in vacuum by means of thermal analysis and infrared spectroscopy. Thermograms of differential thermal analysis of cis ‐polyacetylene r…
Abstract LaNiO 3 loses oxygen in well-defined equilibrium stages. Electron diffraction studies show the presence of super-structure due to vacancy ordering in an anion-deficient sample.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal structures and dehydrated divalent-copper-exchanged faujasiteI. E. Maxwell and J. J. De BoerCite this: J. Phys. Chem. 1975, 79, 17, 1874–1879Publication Date (Print):August 1, 1975Publication History Published online1 May 2002Published inissue 1 August 1975https://do…
A lattice-imaging technique is applied in a study of the intimate structure of non-graphitizing PVDC C atoms heat treated in the range 803 K to 2973 K. Fine detail in the resulting electron micrographs indicates that the bulk material consists of a high proportion of intertwined crystallites comprising turbostraticall…
Abstract Rigid plastic foams find application in construction mainly as core materials for loaded sandwich structures—in buildings, ground vehicles, and airplanes. This work provides an equation for the mechanical behavior of polyurethane foams as a function of foam density. Starting from a model conception and the qu…
From an analysis of the one-dimensional constant-loss theory of secondary electron emission, maximum yield (δm), primary electron energy at maximum yield (Eom), and both crossover energies EIoc and EIIoc are shown to depend on the surface and bulk properties of the emitting material through simple relations. In partic…
The electrical, optical, and magnetic properties of layered compounds of dichalcogenides of transition metals and intercalated crystals are considered. Particular attention is paid to the anisotropy of these properties and to the analysis of the changes produced by intercalation. Experimental data are presented on the…
A model for anomalous diffusion in the bcc phase of group-$\mathrm{IV}B$ transition metals is proposed, based on the identity of structure of the activated complex for diffusion and the basal plane of the low-temperature metastable $\ensuremath{\omega}$ phase. An expression for the diffusion coefficient is derived fro…
The growth of W grains in sputtered W-${\mathrm{Al}}_{2}$${\mathrm{O}}_{3}$ films as a consequence of annealing results in a narrowing of the transition region from metallic to nonmetallic conductivity. The conductivity, $\ensuremath{\sigma}$, as a function of the volume fraction of the metal, $x$, exhibits a critical…