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High‐Thermal‐Conductivity Aluminum Nitride Ceramics: The Effect of Thermodynamic, Kinetic, and Microstructural Factors

T. Barrett Jackson、Anil V. Virkar、Karren L. More 等 5 位作者1997-06-01OpenAlex

Improvement in the thermal conductivity of aluminum nitride (AlN) can be realized by additives that have a high thermodynamic affinity toward alumina (Al 2 O 3 ), as is clearly demonstrated in the aluminum nitride‐yttria (AlN‐Y 2 O 3 ) system. A wide variety of lanthanide dopants are compared at equimolar lanthanide o…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisThermal properties of materials

Dissolved organic matter sorption on sub soils and minerals studied by 13 C‐NMR and DRIFT spectroscopy

Klaus Kaiser、Georg Guggenberger、Ludwig Haumaier 等 4 位作者1997-06-01OpenAlex

Summary Sorption on the mineral matrix is an important process restricting the movement of dissolved organic matter (DOM) in soils. In this study, we aimed to identify the chemical structures responsible for the retention of DOM by sorption experiments with total DOM and acidic humic substances (AHS), containing humic…

Geochemistry and Elemental AnalysisClay minerals and soil interactionsIron oxide chemistry and applications

XRD Measurement of Mean Crystallite Thickness of Illite and Illite/Smectite: Reappraisal of the Kubler Index and the Scherrer Equation

Victor A. Drits、Jan Środoń、D. D. Eberl1997-06-01OpenAlex

Abstract The standard form of the Scherrer equation, which has been used to calculate the mean thickness of the coherent scattering domain (CSD) of illite crystals from X-ray diffraction (XRD) full width data at half maximum (FWHM) intensity, employs a constant, K sh , of 0.89. Use of this constant is unjustified, eve…

Clay minerals and soil interactionsSoil and Unsaturated FlowIron oxide chemistry and applications

2. Assembly of Alternating Polyelectrolyte and Protein Multilayer Films for Immunosensing

Frank Caruso、Kenichi Niikura、D. Neil Furlong 等 4 位作者1997-06-01OpenAlex

Alternating polyelectrolyte films constructed by the sequential adsorption of poly(allylamine hydrochloride) (PAH) and poly(styrenesulfonate) (PSS) have been used as substrates for the immobilization of immunoglobulin G (IgG) and anti-IgG. Anti-IgG has also been immobilized in multilayer films by the alternate deposit…

Acoustic Wave Resonator TechnologiesNanofabrication and Lithography TechniquesPolymer Surface Interaction Studies

Relaxor based ferroelectric single crystals for electro-mechanical actuators

Seung-Eek Park、Thomas R. Shrout1997-06-01OpenAlex

The piezoelectric properties of relaxor based ferroelectric single crystals, such as Pb(Zn1/3Nb2/3)O3- PbTiO3 (PZN-PT) and Pb(Mg1/3Nb2/3)O3-PbTiO3 (PMN-PT) were investigated for electromechanical actuators. In contrast to polycrystalline materials such as Pb(Zr, Ti)O3 (PZTs), morphotropic phase boundary (MPB) composit…

Acoustic Wave Resonator TechnologiesFerroelectric and Piezoelectric MaterialsDielectric materials and actuators

Size-Dependent Spectroscopy of InP Quantum Dots

O. I. Mićić、Hyeonsik Cheong、Huaxiang Fu 等 7 位作者1997-06-01OpenAlex

The spectroscopic behavior of colloidal InP quantum dots (QDs) has been investigated as a function of the mean QD diameter (which ranged from 26 to 60 Å). Absorption spectra show up to three peaks or shoulders which reflect excited state transitions in the QDs. Global photoluminescence (PL) spectra (excitation well to…

Semiconductor Quantum Structures and DevicesChalcogenide Semiconductor Thin FilmsQuantum Dots Synthesis And Properties

Improvement of 13 C and 15 N CPMAS NMR spectra of bulk soils, particle size fractions and organic material by treatment with 10% hydrofluoric acid

Michael W. Schmidt、Heike Knicker、Patrick G. Hatcher 等 4 位作者1997-06-01OpenAlex

Summary The small organic matter content of mineral soils makes it difficult to obtain 13 C and 15 N nuclear magnetic resonance (NMR) spectra with acceptable signal‐to‐noise ratios. Subjecting such samples to hydrofluoric acid removes mineral matter and leads to a relative increase in organic material. The effect of t…

NMR spectroscopy and applicationsSoil Carbon and Nitrogen DynamicsClay minerals and soil interactions

Monocyte Chemotactic Protein-1 Increases Collateral and Peripheral Conductance After Femoral Artery Occlusion

Wulf Ito、Margarete Arras、Bernd Winkler 等 6 位作者1997-06-01OpenAlex

Monocytes are activated during collateral artery growth in vivo, and monocyte chemotactic protein-1 (MCP-1) has been shown to be upregulated by shear stress in vitro. In order to investigate whether MCP-1 enhances collateral growth after femoral artery occlusion, 12 rabbits were randomly assigned to receive either MCP…

Polymer Surface Interaction StudiesCardiac Ischemia and ReperfusionCell Adhesion Molecules Research

Polyhaloporphyrins: Unusual Ligands for Metals and Metal-Catalyzed Oxidations

David Dolphin、Teddy G. Traylor、Lily Y. Xie1997-06-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolyhaloporphyrins: Unusual Ligands for Metals and Metal-Catalyzed OxidationsDavid Dolphin, Teddy G. Traylor, and Lily Y. XieView Author Information Department of Chemistry, University of British Columbia, Vancouver, Canada V6T 1Z1, and Department of Chemistry, University of…

Surface Chemistry and CatalysisMetal-Catalyzed Oxygenation MechanismsPorphyrin and Phthalocyanine Chemistry

Elastic Scattering Corrections in AES and XPS. II. Estimating Attenuation Lengths and Conditions Required for their Valid Use in Overlayer/Substrate Experiments

Peter J. Cumpson、M. P. Seah1997-06-01OpenAlex

We examine substrate/overlayer experiments and the equations commonly used to quantify overlayer thicknesses. Comparisons with accurate Monte-Carlo simulations show that using attenuation lengths (rather than inelastic mean free paths) eliminates most of the error due to elastic scattering without increasing the compl…

Semiconductor materials and devicesAdvancements in Photolithography TechniquesElectron and X-Ray Spectroscopy Techniques

Structural Studies of Rutile-Type Metal Dioxides

Adrian A. Bolzan、Celesta Fong、Brendan J. Kennedy 等 4 位作者1997-06-01OpenAlex

The structures of the four metal dioxides GeO 2 , SnO 2 , RuO 2 and IrO 2 (germanium, tin, ruthenium and iridium dioxides, respectively) have been redetermined by Rietveld refinement from neutron diffraction powder data. The four dioxides all adopt the rutile-type structure, space group P 42/ mnm (no. 136), with a = 4…

Metallurgical and Alloy ProcessesTransition Metal Oxide NanomaterialsChemical and Physical Properties of Materials

Access in mesoporous materials: Advantages of a uniform pore structure in the design of a heavy metal ion adsorbent for environmental remediation

Louis Mercier、Thomas J. Pinnavaia1997-06-01OpenAlex

The access of guest species to the binding sites of adsorbent determines the metal‐binding capacity of materials, which is important for example in environmental remediation efforts. It is shown that MP‐HMS, the mercaptopropylsilane‐functionalized derivative of the molecualr sieve HMS, with its regular pore structure…

Metal-Organic Frameworks: Synthesis and ApplicationsMesoporous Materials and CatalysisChemical Synthesis and Characterization

MultiCoil: A program for predicting two‐and three‐stranded coiled coils

Ethan Wolf、Peter S. Kim、Bonnie Berger1997-06-01OpenAlex

A new multidimensional scoring approach for identifying and distinguishing trimeric and dimeric coiled coils is implemented in the MultiCoil program. The program extends the two-stranded coiled-coil prediction program PairCoil to the identification of three-stranded coiled coils. The computations are based upon data g…

RNA and protein synthesis mechanismsProtein Structure and DynamicsEnzyme Structure and Function

Nanosized Particles Made in Colloidal Assemblies

M. P. Pileni1997-06-01OpenAlex

In this feature article, syntheses of nanosized particles by using colloidal assemblies as a template are described. We asked ourselves the following question: What parameters play a role in the control of the size, shape, and polydispersity? We know that parameters such as the shape of colloidal assemblies, the hydra…

Surfactants and Colloidal SystemsIron oxide chemistry and applicationsPickering emulsions and particle stabilization

Novel poly(aryl ether ketone)s containing various pendant groups. II. Gas-transport properties

Zhonggang Wang、Tianlu Chen、Jiping Xu1997-05-31Journal of Applied Polymer Science

The gas transport of hydrogen, oxygen, nitrogen, carbon dioxide, and methane gases in a series of poly(aryl ether ketone)s was examined. The polymer membranes have a wide range of permeability coefficients and permselectivity coefficients, showing excellent gas-transport properties. The enhanced interchain interaction…

Fuel Cells and Related MaterialsSynthesis and properties of polymersMembrane Separation and Gas Transport

Mechanical properties of pineapple leaf fiber‐reinforced polyester composites

L. Uma Devi、S. S. Bhagawan、Sabu Thomas1997-05-31Journal of Applied Polymer Science

Pineapple leaf fiber (PALF) which is rich in cellulose, relatively inexpensive, and abundantly available has the potential for polymer reinforcement. The present study investigated the tensile, flexural, and impact behavior of PALF-reinforced polyester composites as a function of fiber loading, fiber length, and fiber…

Advanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical ApplicationsNatural Fiber Reinforced Composites

Survey on transport properties of liquids, vapors, and gases in biodegradable poly(3-hydroxybutyrate) (PHB)

Óscar Miguel、M. J. Fernández‐Berridi、J. J. Iruin1997-05-31Journal of Applied Polymer Science

The transport properties of carbon dioxide, water, and different organic solvents in bacterial poly(3-hydroxybutyrate) (PHB) at 30°C were investigated. CO2 sorption was measured by the gravimetric method using a recording microbalance at subatmospheric pressures. Results were adequately interpreted in terms of Henry's…

Membrane Separation and Gas TransportCarbon dioxide utilization in catalysisbiodegradable polymer synthesis and properties

Crystallization of poly(hydroxybutrate-co-hydroxyvalerate) in wood fiber-reinforced composites

Veronika E. Reinsch、Stephen S. Kelley1997-05-31Journal of Applied Polymer Science

Wood fiber-reinforced composites were prepared from poly(hydroxybutyrate) (PHB) and poly(hydroxybutyrate-co-hydroxyvalerate) (PHB/HV) copolymers containing 9 and 24% valerate. The effects of fibers on crystallization were investigated. Thermomechanical pulp, bleached Kraft fibers, and microcrystalline cellulose filler…

Advanced Cellulose Research Studiesbiodegradable polymer synthesis and propertiesPolymer crystallization and properties

Mechanical properties of pineapple leaf fiber-reinforced polyester composites

L. Uma Devi、S. S. Bhagawan、Sabu Thomas1997-05-31OpenAlex

Pineapple leaf fiber (PALF) which is rich in cellulose, relatively inexpensive, and abundantly available has the potential for polymer reinforcement. The present study investigated the tensile, flexural, and impact behavior of PALF-reinforced polyester composites as a function of fiber loading, fiber length, and fiber…

Advanced Cellulose Research StudiesNatural Fiber Reinforced CompositesElectrospun Nanofibers in Biomedical Applications

Polypyrrole: a conducting polymer; its synthesis, properties and applications

T.V. Vernitskaya、О. Н. Ефимов1997-05-31OpenAlex

The synthesis, properties and applications of polypyrrole (PPy), a representative of conducting polymers, are reviewed. Chemical and electrochemical methods for the preparation of PPy and PPy films and the effect of the reaction conditions on the properties of the polymer produced are discussed. The mechanisms of elec…

Conducting polymers and applicationsOrganic Electronics and PhotovoltaicsAnalytical Chemistry and Sensors