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The elastic constants of nematic liquid crystalline terminally substituted azoxybenzenes

Wim H. de Jeu、W. A. P. Claassen1977-10-15The Journal of Chemical Physics

The elastic constants K11, K22, and K33 of some members of two homologous series of nematic liquid crystals, the p,p′-di-n-alkyl and p,p′-di-n-alkoxy azoxybenzenes, are reported. Both K11 and K33 become greater with increasing alkyl chain length, while the ratio K33/K11 decreases along the series. For small alkyl chai…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Disorder effects in angle-resolved photoelectron spectroscopy

N. J. Shevchik1977-10-15Physical review. B, Solid state

The effects of compositional, vibrational, long-range positional, and topographical disorders upon the angle-resolved photoemission spectra of tightly bound valence electrons are investigated. In order to take into account the strong potential sensed by the electron in the vicinity of the atomic core, an augmented-pla…

Advanced Chemical Physics StudiesX-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy Techniques

Raman and infrared studies of superlattice formation in Ti Se 2

John A. Holy、K. C. Woo、M. V. Klein 等 4 位作者1977-10-15Physical review. B, Solid state

Raman and far-infrared reflectivity spectra have been obtained for both stoichiometric and nonstoichiometric Ti${\mathrm{Se}}_{2}$ above and below the transition temperatures corresponding to formation of the $2{a}_{0}\ifmmode\times\else\texttimes\fi{}2{c}_{0}$ superlattice. In the normal phase above ${T}_{c}$ Raman-a…

Chalcogenide Semiconductor Thin FilmsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Electronic structure and lattice instability of metallic V O 2

Michèle Gupta、A. J. Freeman、D. E. Ellis1977-10-15Physical review. B, Solid state

A first-principles energy-band study of the metallic rutile phase of V${\mathrm{O}}_{2}$ using a general crystal potential and an expansion of the Bloch functions in a linear combination of atomic orbitals is reported. The results are compared with previous work and experimental optical, x-ray absorption and emission,…

Transition Metal Oxide NanomaterialsAdvanced Condensed Matter PhysicsCatalysis and Oxidation Reactions

Anomalous transport properties of a linear-chain metal: NbSe3

N. P. Ong、P. Monçeau1977-10-15Physical review. B, Solid state

The transport properties of the linear-chain metal Nb${\mathrm{Se}}_{3}$ are anomalous. Giant increases in the dc resistivity appear at 145 and 59 K, suggestive of charge-density-wave (CDW) formation. These anomalies show breakdown effects with applied electric fields as low as 0.1 V ${\mathrm{cm}}^{\ensuremath{-}1}$.…

Molecular Junctions and NanostructuresOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

Infrared studies of the energy gap and electron-phonon interaction in potassium-tetracyanoquinodimethane (K-TCNQ)

D. B. Tanner、Christian S. Jacobsen、A. A. Bright 等 4 位作者1977-10-15Physical review. B, Solid state

The polarized reflectance at room temperature of potassium-tetracyanoquinodimethane (K-TCNQ) has been measured. Analysis using the Kramers-Kronig transforms gives the response functions (dielectric function and conductivity) between 300 and 23 000 ${\mathrm{cm}}^{\ensuremath{-}1}$. Attempts have been made to fit these…

Magnetism in coordination complexesMechanical and Optical ResonatorsOrganic and Molecular Conductors Research

Resonant Raman scattering in ZnO

J. M. Calleja、M. Cardona1977-10-15OpenAlex

The resonance of the Raman scattering by ${E}_{2}, {A}_{1T}, {E}_{1L}$, and ${E}_{1T}$ phonons, and several second-order features, has been studied for ZnO for photon energies between 1.6 and 3 eV. The results are interpreted with a dielectric theory based on the first and second derivatives of the dielectric constant…

ZnO doping and propertiesHigh-pressure geophysics and materialsSolid-state spectroscopy and crystallography

Hair Element Content in Learning Disabled Children

R. O. Pihl、M. Parkes1977-10-14Science

Hair samples from 31 learning disabled and 22 normal children were analyzed for content of 14 elements. Significant group differences were determined and a discriminant function was completed which separated the groups with 98 per cent accuracy. Elevated lead and cadmium content in the learning disabled group is viewe…

Hair Growth and DisordersTextile materials and evaluations

Vacancy Double Jumps and Atomic Diffusion in Aluminum and Sodium

A. Da Fano、Gianni Jacucci1977-10-10Physical Review Letters

The relevance of a high-temperature mechanism for vacancy migration, the double jump, has been established by molecular dynamics in Al and Na. Migration energies for single jumps are 0.42 \ifmmode\pm\else\textpm\fi{} 0.1 eV and 0.12 \ifmmode\pm\else\textpm\fi{} 0.02 eV, respectively, while for double jumps they are ab…

Ion-surface interactions and analysisX-ray Diffraction in CrystallographyThermodynamic and Structural Properties of Metals and Alloys

Electron-beam and photolithographic fabrication of guided-wave optical components

R. L. Aagard、L. T. Shepherd、R. P. Ulmer1977-10-01Journal of Applied Physics

Thin-film lenses, mirrors, and diffraction gratings have been fabricated from electon-beam-generated masks. These masks were used to make iron oxide working masks for photolithographic fabrication of these passive components in Nb2O5 optical waveguides. The optical-waveguide characteristics of these components are dis…

Photonic and Optical DevicesAdvanced Surface Polishing TechniquesOptical Coatings and Gratings

Observations of oblique magnetic domain walls in nickel single crystals by X-ray topography

W. J. Boettinger、Harold E. Burdette、M. Kuriyama1977-10-01Philosophical magazine

Unusual band images observed by dynamical diffraction X-ray topography in nickel single crystals are elucidated by a model of very thin magnetic domains which extend obliquely through the thickness of the crystal. These thin domains have a magnetization direction which would cause free-pole formation on the crystal su…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsMagnetic Properties of Alloys

New bands attributed to scandium hydride

A. Bernard、C. Effantin、R. Bacis1977-10-01Canadian Journal of Physics

New bands assigned to scandium hydride have been observed in emission in the green (5580 Å) and near infrared (8603 Å) regions. The identity of the carrier as ScH is established on the basis of the observed deuteride spectrum.

Luminescence Properties of Advanced MaterialsAtomic and Molecular PhysicsInorganic Fluorides and Related Compounds

Spectra of centrosymmetric rare-earth complexes:Nd3+-hexakis-antipyrine tri-iodide single crystals

A.K. Mukhopadhyay、Mihir Chowdhury1977-10-01Physical review. B, Solid state

Polarized absorption spectra of centrosymmetric neodymium hexakis-antipyrine tri-iodide single crystals at 77 and 20\ifmmode^\circ\else\textdegree\fi{}K have been discussed. The spectrum is complicated by the appearance of a large number of vibronic lines. A phase transition destroying the inversion symmetry occurs be…

Magnetism in coordination complexesPhotochemistry and Electron Transfer StudiesLanthanide and Transition Metal Complexes

Lactose‐ derived surfactants(III): Fatty esters of oxyalkylated lactito

F. Scholnick、W. M. Linfield1977-10-01Journal of the American Oil Chemists Society

Abstract and Summary Lactitol was oxyalkylated with propylene or ethylene oxide. The resulting ether‐alcohols were transesterified with a series of fatty acid esters in order to produce long chain ether‐esters of lactitol. These compounds were found to be more water soluble than related lactitol derivatives prepared b…

biodegradable polymer synthesis and propertiesSurfactants and Colloidal SystemsEnvironmental Chemistry and Analysis

Laser-induced breakdown in organic liquids

H. Fujii、K. Yoshino、Yoshio Inuishi1977-10-01Journal of Physics D Applied Physics

The threshold fields of laser-induced breakdown in dielectric liquids (dimethyl silicon oil and linear hydrocarbon liquids) were experimentally studied as the functions of increasing molecular weight and decreasing temperature and found to decrease. By comparison, slightly increase. From these results, laser-induced b…

Ultrasound and Cavitation PhenomenaLaser-induced spectroscopy and plasmaElectrohydrodynamics and Fluid Dynamics

Magnetostriction of SmFeO3and YFe1-xCox/2Tix/2O3in the Spin Reorientation Region

Masanori Abe、Kumiko Kaneta、Manabu Gomi 等 5 位作者1977-10-01Japanese Journal of Applied Physics

Longitudinal and transverse magnetostrictions along the a , b and c axes of SmFeO 3 and YFe 1- x Co x /2 Ti x /2 O 3 (0.004≦ x ≦0.012) were measured. In both of the orthoferrites, the magnetostriction increases in magnitude near the spin reorientation temperature region, reaching maximum value of Δ l / l ∼15×10 -6 und…

Magnetic properties of thin filmsMultiferroics and related materialsMagnetic Properties and Applications

Measurement of tribo-emission from oxide-covered metals

B -Z Rosenblum、J. P. Carrico、P. Bräunlich 等 4 位作者1977-10-01Journal of Physics E Scientific Instruments

An apparatus is described for the investigation of chemically stimulated, photostimulated and tribostimulated exoelectron emission. Emphasis was placed on tribostimulated emission from uniaxially deformed oxide-covered metals (aluminium, titanium and nickel). Experiments were performed in either ultra-high vacuum or a…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy TechniquesAnodic Oxide Films and Nanostructures

Calendering of PVC: Defects in calendered PVC films and sheets

J. L. Bourgeois、J. F. Agassant1977-10-01Journal of Macromolecular Science Part B

Major types of defects appearing in calendered films and sheets are described. The conditions for the appearance of air bubbles and mattness were studied for the particular case of calendering crystal-clear, rigid, toughened PVC. A correlation was found between the presence of air bubbles in the film and a distributio…

Rheology and Fluid Dynamics StudiesMaterial Properties and ProcessingPolymer Science and PVC

Climb model of extended dislocations in f.c.c. metals

J. Grilhé、Matthieu Boisson、K. Seshan 等 4 位作者1977-10-01Philosophical magazine

A climb model of extended dislocations based on jog pair nucleation is proposed. The energy of an extended jog pair is computed for different stacking fault energies. The results show a critical jog size from which the extended jog pair may develop by glide. This critical size is related to the stacking fault energy.…

Microstructure and mechanical propertiesHigh Temperature Alloys and CreepSurface and Thin Film Phenomena

Calendering of PVC: Prediction of stress and torque

J. F. Agassant、Pierre Avenas1977-10-01Journal of Macromolecular Science Part B

Using a power-law viscosity, then connecting power-law fluid and thermo-dependence of the viscosity, we compute the applied stresses between the rollers during calendering (pressure curve-maximum pressure and shear stress-roll separating force and the applied opposing torque) as well as the temperature evolution of th…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Science and PVC