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Carbon Black Distribution in NR/Polybutadiene Blends

Jean Marie Massie、Robert C. Hirst、Adel F. Halasa1993-05-01Rubber Chemistry and Technology

Abstract The distribution of carbon black between the phases of a NR/ cis -1,4-polybutatdiene (BR) blend was studied. An N550 carbon black was added to the blend using different mixing techniques. The carbon-black distribution was determined using a variety of analytical techniques. The crystallization temperature of…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites

Clothing Heated with Textile Heating Elements

Wlodzimierz Wie ̧źlak、J. Zieliński1993-05-01International Journal of Clothing Science and Technology

Presents the possibility of utilization of the textile heating element for designing protective clothing. Investigation of the textile heating element has been carried out and it has been found that a conductive woven fabric of specific resistance should not be higher than 4*10−2 (Ω*m). Physical behaviour of the heati…

Thermoregulation and physiological responsesTextile materials and evaluations

Surface Magnetostriction

H. Szymczak、R. Żuberek1993-05-01Acta Physica Polonica A

Experimental and theoretical research on magnetostriction of nanoscale magnetic multilayers is reviewed. The importance of interfaces and the occurrence of the surface magnetostriction is emphasized. It is shown that the dependence of magnetostriction on the magnetic layer thickness is due to the magnetostrictive stra…

Magnetic properties of thin filmsMagnetic Properties and Applications

Comments on the thermoelectric properties of pressure-sintered Si0.8Ge0.2 thermoelectric alloys

D.M. Rowe、Liangwei Fu、S.G.K. Williams1993-05-01Journal of Applied Physics

The recent results of C. B. Vining, W. Laskow, J. O. Hanson, R. R. Van der Beck, and P. D. Gorsuch [J. Appl. Phys. 69, 4333 (1991)] regarding the effect of grain size on the thermoelectric figure of merit of heavily doped p-type silicon germanium alloys are compared to earlier results on similar materials. The data co…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsSemiconductor materials and interfaces

X-ray photoelectron spectroscopy study of CaS:Eu and SrS:Eu phosphors

Moonsup Han、S.-J. Oh、Jong Hee Park 等 4 位作者1993-05-01Journal of Applied Physics

The phosphors of alkali-earth sulfides SrS:Eux (x=0.05 and 0.10 mole per mole of SrS), SrSO:Eux (x=0.05), and CaS:Eux (x=0.0005, 0.05, and 0.10) were studied by x-ray photoelectron spectroscopy. The CaS:Eu phosphors were found to be stabilized against atmospheric water vapor and carbon dioxide by annealing at high tem…

Advanced Chemical Physics StudiesLuminescence Properties of Advanced MaterialsSolid-state spectroscopy and crystallography

Crystal structure and magnetic susceptibility of a hydrocarbon free radical: tris(3,5-di-tert-butylphenyl)methyl

Bart Kahr、Donna Van Engen、Prakash Gopalan1993-05-01Chemistry of Materials

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCrystal structure and magnetic susceptibility of a hydrocarbon free radical: tris(3,5-di-tert-butylphenyl)methylBart Kahr, Donna Van Engen, and Prakash GopalanCite this: Chem. Mater. 1993, 5, 5, 729–732Publication Date (Print):May 1, 1993Publication History Published online1…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Effect of Environmental Humidity on the Transformation Pathway of Nitrofurantoin Modifications During Grinding and the Physicochemical Properties of Ground Products

Makoto Otsuka、Yoshihisa Matsuda1993-05-01Journal of Pharmacy and Pharmacology

The effect of humidity on the physicochemical properties of nitrofurantoin anhydrate and monohydrate during grinding in a humidity-controlled system was investigated using X-ray diffraction analysis, IR spectroscopy, thermal analysis and scanning electron microscopy. Anhydrate and monohydrate were transformed into a n…

Drug Solubulity and Delivery SystemsAnalytical Methods in PharmaceuticalsCrystallization and Solubility Studies

Analysis of Fatigue Crack Propagation in NR/BR Rubber Blend

M.-P. Lee、A. Moet1993-05-01Rubber Chemistry and Technology

Abstract Fatigue behavior in a blend of natural rubber (NR) and polybutadiene rubber (BR) has been investigated. The energy release rates measured from load-displacement curves recorded during the fatigue test could be used to characterize the fatigue crack propagation (FCP) history of NR/BR blend. Crack propagation k…

Polymer crystallization and propertiesStructural Behavior of Reinforced ConcretePolymer Nanocomposites and Properties

Theoretical Description of the Crowdion in an Anisotropic Crystal Based on the Frenkel‐Kontorova Model Including and Elastic Three‐Dimensional Medium

A. S. Kovalev、A. D. Kondratyuk、A. M. Kosevich 等 4 位作者1993-05-01physica status solidi (b)

Abstract The well‐known Frenkel‐Kontorova theoretical model is generalized by including the elastic properties of the three‐dimensional medium surrounding the discrete atomic chain considered. The generalized sinuse‐Gordon equation (SGE) and the integro‐differential equation describing the crowdion in a highly anisotr…

Structural mechanics and materialsMaterial Properties and Failure Mechanisms

High‐Temperature Failure Mechanisms of Hot‐Pressed Si 3 N 4 and Si 3 N 4 /Si 3 N 4 ‐Whisker‐Reinforced Composites

Cha‐Yang Chu、J. P. Singh、J.L. Routbort1993-05-01Journal of the American Ceramic Society

The high‐temperature flexural strength of hot‐pressed silicon nitride (Si 3 N 4 ) and Si 3 N 4 ‐whisker‐reinforced Si 3 N 4 ‐matrix composites has been measured at a crosshead speed of 1.27 mm/min and temperatures up to 1400°C in a nitrogen atmosphere. Load–displacement curves for whisker‐reinforced composites showed…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesHigh-Velocity Impact and Material Behavior

Heterocyclic azole nonlinear optical chromophores. 1. Donor-acceptor substituted pyrazole derivatives

Robert D. Miller、Christopher R. Moylan、Oliver Reiser 等 4 位作者1993-05-01Chemistry of Materials

We have described the synthesis of a variety of 1,3,1,4, and 1,5 donor-acceptor conjugation extended substituted pyrazole derivatives and have studied their spectr6scopic and nonlinear optical properties. These materials are thermally stable and absorb strongly in the UV-visible\nregion, albeit at much shorter wavelen…

Synthesis and biological activityNonlinear Optical Materials ResearchPhotochemistry and Electron Transfer Studies

Raman-scattering study of high-pressure phase transition and amorphization of resorcinol

S. K. Deb、M. A. Rekha、A. P. Roy 等 6 位作者1993-05-01Physical review. B, Condensed matter

Crystalline resorcinol [${\mathrm{C}}_{6}$${\mathrm{H}}_{4}$(OH${)}_{2}$] has been shown to amorphize at 40 kbars, solely using Raman scattering. The external modes vanish resulting in a spectrum similar to the density of states spectrum, but the internal modes persist indicating a breakdown of translational and orien…

Material Dynamics and PropertiesCrystallography and molecular interactionsSolid-state spectroscopy and crystallography

Electron-paramagnetic-resonance spectroscopy of manganese-dopedBa3(VO4)2: Identification of tetrahedralMn5+andMn4+centers

Michael H. Whitmore、Horacio R. Verdún、David J. Singel1993-05-01Physical review. B, Condensed matter

Electron-paramagnetic-resonance (EPR) spectra of single crystals of a solid-state-laser material, manganese-doped ${\mathrm{Ba}}_{3}$(${\mathrm{VO}}_{4}$${)}_{2}$, are reported. The spectra reveal the incorporation of the putative active ion ${\mathrm{Mn}}^{5+}$ substituting for the tetrahedral coordinate ${\mathrm{V}…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCatalysis and Oxidation Reactions

X-ray Couette shear cell for nonequilibrium structural studies of complex fluids under flow

Robert J. Plano、Cyrus R. Safinya、E. B. Sirota 等 4 位作者1993-05-01Review of Scientific Instruments

We have designed and constructed a sealed, temperature-controlled Couette-type shear cell which allows us to carry out in situ synchrotron x-ray scattering studies of the nonequilibrium structures of complex fluids under flow, probing lengths ranging from the nanometer to the semimacroscopic micron scale. The sealed d…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Cellulose acetate propionate and poly(tetramethylene glutarate) blends

Charles M. Buchanan、Steve C. Gedon、Alan W. White 等 4 位作者1993-05-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCellulose acetate propionate and poly(tetramethylene glutarate) blendsCharles M. Buchanan, Steve C. Gedon, Alan W. White, and Matthew D. WoodCite this: Macromolecules 1993, 26, 11, 2963–2967Publication Date (Print):May 1, 1993Publication History Published online1 May 2002Pub…

Advanced Cellulose Research Studies

Investigation of S/sub 2/F/sub 10/ production and mitigation in compressed SF/sub 6/-insulated power systems

D. R. James、I. Sauers、Guy D. Griffin 等 9 位作者1993-05-01IEEE Electrical Insulation Magazine

The Cooperative Research and Development Agreement (CRADA), established to study the production and mitigation of S/sub 2/F/sub 10/ (disulfur decafluoride), one of a number of toxic by-products formed in electric discharges in the insulating gas SF/sub 6/, is described. The particular concern about S/sub 2/F/sub 10/ i…

High voltage insulation and dielectric phenomenaVacuum and Plasma ArcsElectrostatic Discharge in Electronics

Bis(dimethylviolurato)(phenanthroline)cobalt(II), a low-spin octahedral cobalt(II) complex. Crystal structure of [Co(dmvi)2phen].2CHCl3

Juan Faus、Miguel Julve、Francisco Lloret 等 4 位作者1993-05-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBis(dimethylviolurato)(phenanthroline)cobalt(II), a low-spin octahedral cobalt(II) complex. Crystal structure of [Co(dmvi)2phen].2CHCl3Juan Faus, Miguel Julve, Francisco Lloret, and M. Carmen MunozCite this: Inorg. Chem. 1993, 32, 10, 2013–2017Publication Date (Print):May 1,…

Organometallic Complex Synthesis and CatalysisMetal complexes synthesis and propertiesMagnetism in coordination complexes

Calibration of an electron back‐scattering pattern set‐up

Niels Christian Krieger Lassen、Jørgen Bilde-Sørensen1993-05-01Journal of Microscopy

Summary The determination of lattice orientations from electron back‐scattering patterns (EBSPs) in a scanning electron microscope (SEM) requires accurate knowledge of the position of the pattern centre and the source point to screen distance. This paper outlines a new procedure that enables the determination of these…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesSurface and Thin Film Phenomena

Anisotropic Chemical Etching of Copper Foil: I . Electrochemical Studies in Acidic Solutions

Maria Georgiadou、Richard C. Alkire1993-05-01Journal of The Electrochemical Society

Etching of thick copper foil masked except for a single rectangular opening having an aspect ratio (width:depth) of 5:1 or 1:1 was investigated in the presence of controlled laminar flow across the width of the pattern opening. In a solution of , copper was found to form a surface film spontaneously at the "corrosion…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsCopper Interconnects and Reliability

Transient and Load-Following Characteristics of a Fully Integrated Single-Cell Thermionic Fuel Element

Mohamed S. El‐Genk、Huimin Xue、Christopher S. Murray1993-05-01Nuclear Technology

A thermionic transient analysis model is developed to simulate transient and steady-state operations of a fully integrated, single-cell thermionic fuel element (TFE). The responses of the TFE to a step input in reactivity and changes in the cesium pressure or in the size of the interelectrode gap, the coolant temperat…

Advanced Battery Materials and TechnologiesAdvanced Thermoelectric Materials and DevicesHydrogen Storage and Materials