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Thiolase from Clostridium acetobutylicum ATCC 824 and Its Role in the Synthesis of Acids and Solvents

Dennis P. Wiesenborn、Frederick B. Rudolph、Eleftherios T. Papoutsakis1988-11-01Applied and Environmental Microbiology

Thiolase (acetyl-coenzyme A [CoA] acetyltransferase, E.C. 2.3.1.19) from Clostridium acetobutylicum ATCC 824 has been purified 70-fold to homogeneity. Unlike the thiolase in Clostridium pasteurianum, this thiolase has high relative activity throughout the physiological range of internal pH of 5.5 to 7.0, indicating th…

Enzyme Structure and FunctionMetabolism and Genetic DisordersAmino Acid Enzymes and Metabolism

Scattering matrix method for propagation of radiation in stratified media: attenuated total reflection studies of liquid crystals

D. Y. K. Ko、J. R. Sambles1988-11-01Journal of the Optical Society of America A

We present a new scattering matrix formalism for the modeling of electromagnetic wave propagation in stratified media. It is computationally efficient and stable and is well suited to the layer geometry that is characteristic of stratified materials. It is applied successfully to the modeling of total attenuated refle…

Plant Reproductive BiologyLiquid Crystal Research AdvancementsPhotonic Crystals and Applications

An x‐ray photoelectron spectroscopic study of some chromium–oxygen systems

Elio Desimoni、Cosimino Malitesta、P. G. Zambonin 等 4 位作者1988-11-01Surface and Interface Analysis

Abstract A series of pure and mixed chromium standards has been analysed by x‐ray photoelectron spectroscopy in order to obtain a sufficiently homogeneous and self‐consistent set of spectral parameters to be used in the resolution of complex spectra. Additional information was obtained about the stability of the vario…

Corrosion Behavior and InhibitionElectron and X-Ray Spectroscopy TechniquesX-ray Spectroscopy and Fluorescence Analysis

Dihexadecyl phosphate, vesicle-stabilized and in situ generated mixed cadmium sulfide and zinc sulfide semiconductor particles: preparation and utilization for photosensitized charge separation and hydrogen generation

Hyeong Chan Youn、Subhash Baral、János H. Fendler1988-11-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDihexadecyl phosphate, vesicle-stabilized and in situ generated mixed cadmium sulfide and zinc sulfide semiconductor particles: preparation and utilization for photosensitized charge separation and hydrogen generationHyeong Chan Youn, Subhash Baral, and Janos H. FendlerCite…

Quantum Dots Synthesis And PropertiesPorphyrin and Phthalocyanine ChemistryChalcogenide Semiconductor Thin Films

Phthalonitrile‐based high temperature resin

Teddy M. Keller1988-11-01Journal of Polymer Science Part A Polymer Chemistry

Abstract An aromatic, diether‐linked phthalonitrile resin, prepared from 4,4′‐bis(3,4‐dicyanophenoxy)biphenyl, exhibits excellent thermo‐oxidative properties. The resin is easily processed from the melt of the monomer in a controlled manner as a function of the amine curing agent and processing temperatures. Polymeriz…

Epoxy Resin Curing ProcessesSynthesis of Tetrazole DerivativesSynthesis and properties of polymers

Solubility and decomposition kinetics of nitrous acid in aqueous solution

Jong-Yoon Park、Yin Nan Lee1988-11-01OpenAlex

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSolubility and decomposition kinetics of nitrous acid in aqueous solutionJong Yoon Park and Yin Nan LeeCite this: J. Phys. Chem. 1988, 92, 22, 6294–6302Publication Date (Print):November 1, 1988Publication History Published online1 May 2002Published inissue 1 November 1988htt…

nanoparticles nucleation surface interactionsChemical Thermodynamics and Molecular StructureCrystallization and Solubility Studies

Selectivity of Neutrophil 5-Lipoxygenase and Cyclo-oxygenase Inhibition by an Anti-inflammatory Flavonoid Glycoside and Related Aglycone Flavonoids

M.A. Moroney、M. José Alcaraz、Robert A. Forder 等 5 位作者1988-11-01OpenAlex

A newly described plant-derived flavonoid, hypolaetin-8-glucoside, which has anti-inflammatory and gastroprotective actions in-vivo, and its corresponding aglycone, hypolaetin, have been compared with 14 other flavonoids for inhibition of eicosanoid generation via the 5-lipoxygenase and cyclo-oxygenase pathways in eli…

Phytochemistry and Bioactive CompoundsInflammatory mediators and NSAID effectsBioactive Compounds and Antitumor Agents

Internal bias in ferroelectric ceramics: Origin and time dependence

G. Arlt、H. Neumann1988-11-01OpenAlex

The internal bias field which is observed in many ferroelectric materials is explained semiquantita-tively. Dipolar defects in the ferroelectric cause div P # O at the defect sites. The electric fields diverging at these sites tend to orient the dipoles to energetically favourable orientations. The free energy is modi…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsAcoustic Wave Resonator Technologies

Empirical three-body potential for vitreous silica

Bradley P. Feuston、Stephen H. Garofalini1988-11-01OpenAlex

A three-body potential suitable for molecular dynamics (MD) simulations has been developed for vitreous silica by adding three-body interactions to the Born–Mayer–Huggins (BMH) pair potential. Previous MD simulations with the BMH potential have formed glassy SiO2 through the melt-quench method with some success. Thoug…

Material Dynamics and PropertiesGlass properties and applicationsLuminescence Properties of Advanced Materials

Fourier transform ir spectroscopy of collagen and gelatin solutions: Deconvolution of the amide I band for conformational studies

K. J. Payne、Arthur Veis1988-11-01OpenAlex

Abstract The ir spectra of lathyritic rat skin collagen and calf skin gelatin solutions at a variety of temperatures were obtained using Fourier transform ir spectroscopy and a 9‐reflection, 2‐pass ZnSe prism sample cell. The spectra were then deconvolved (based on Kauppinnen's method) and the behavior of the amide I…

Meat and Animal Product QualityCollagen: Extraction and Characterization

Three-dimensional structure of the tryptophan synthase alpha 2 beta 2 multienzyme complex from Salmonella typhimurium.

C. Craig Hyde、Salman Ahmed、Eduardo A. Padlan 等 5 位作者1988-11-01OpenAlex

The three-dimensional structure of the alpha 2 beta 2 complex of tryptophan synthase from Salmonella typhimurium has been determined by x-ray crystallography at 2.5 A resolution. The four polypeptide chains are arranged nearly linearly in an alpha beta beta alpha order forming a complex 150 A long. The overall polypep…

Enzyme Structure and FunctionMicrobial Metabolic Engineering and BioproductionProtein Structure and Dynamics

A discretized population balance for nucleation, growth, and aggregation

Michael J. Hounslow、Rosemary L. Ryall、V. R. Marshall1988-11-01OpenAlex

Abstract The population balance for batch aggregation of particulate suspensions is recast in a form that may be solved simply and accurately. The transformed equation is deduced with the introduction of only one additional parameter, which is found to be a constant for all cases. The transformed equation is tested by…

Minerals Flotation and Separation TechniquesCrystallization and Solubility StudiesCoagulation and Flocculation Studies

Extremely sharp erbium-related intra-4f-shell photoluminescence of erbium-doped GaAs grown by metalorganic chemical vapor deposition

H. Nakagome、Kunihiko Uwai、Kenichiro Takahei1988-10-31Applied Physics Letters

A drastic change is observed in the 1.5 μm Er-related photoluminescence spectra for GaAs:Er grown by metalorganic chemical vapor deposition, when the growth temperature and arsine partial pressure are reduced. An optically efficient Er-emitting center which shows a photoluminescence spectrum with narrow linewidth (les…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceGaN-based semiconductor devices and materials

Minimal chaos, stochastic webs, and structures of quasicrystal symmetry

G. M. Zaslavskiĭ、R. Z. Sagdeev、D. A. Usikov 等 4 位作者1988-10-31Soviet Physics Uspekhi

The relationship between the problem of the symmetry of a plane tiling and the properties of nonintegrable dynamic systems is reviewed. The formation of stochastic layers and a stochastic web in the motion of linear and nonlinear oscillators subjected to a perturbation is discussed in detail. Emphasis is placed on res…

Liquid Crystal Research AdvancementsQuasicrystal Structures and PropertiesAdvanced Mathematical Theories and Applications

Metalorganic chemical vapor deposition of PbTiO3 thin films

B. S. Kwak、E. P. Boyd、A. Erbil1988-10-31Applied Physics Letters

PbTiO3 thin films have been grown successfully for the first time by using purely metalorganic precursors, namely, titanium isopropoxide and tetraethyllead. A scanning electron micrograph showed dense and noncolumnar growth with good surface morphology. Temperature-dependent x-ray diffraction studies provide evidences…

Electronic and Structural Properties of OxidesFerroelectric and Piezoelectric MaterialsSemiconductor materials and devices

Localization by a Potential with Slowly Varying Period

D. J. Thouless1988-10-31Physical Review Letters

In order to understand some discrepancies in the recent Letter of Griniasty and Fishman, a study has been made of localization by a one-dimensional potential with slowly varying period. Away from the band center, localization is produced by local regions in which the Bragg condition allows backward scattering, and the…

Quasicrystal Structures and PropertiesTerahertz technology and applicationsQuantum chaos and dynamical systems

Comportamiento mecánico de yeso reforzado con polímeros sintéticos

Alfonso García Santos1988-10-30Informes de la Construcción

Se presenta un estudio de la resistencia mecánica del yeso, basado en su refuerzo mediante la adición de polímeros sintéticos, en forma de fibras y dispersiones acuosas. Se pretende mejorar las características mecánicas del yeso, entre cuyas cualidades se pueden enumerar las siguientes: abundancia en España, bajo cost…

Textile materials and evaluationsbiodegradable polymer synthesis and propertiesNatural Fiber Reinforced Composites

Electronic band structures and magnetism of the cubic perovskite-type manganese compounds Mn3MC (M=Zn,Ga,In,Sn)

Kazuko Motizuki、Hiroyuki Nagai1988-10-30Journal of Physics C Solid State Physics

Electronic band structures of manganese compounds having cubic perovskite-type structure are calculated by a self-consistent augmented-plane-wave method. The energy dispersion, density of states and Fermi surface calculated for the nonmagnetic state of Mn 3 MC (M=Zn,Ga,In,Sn) are shown. The ferromagnetic band is also…

Advanced Battery Materials and TechnologiesHeusler alloys: electronic and magnetic propertiesThermal Expansion and Ionic Conductivity

Water as a plasticizer: physico-chemical aspects of low-moisture polymeric systems

Harry Levine、Louise Slade1988-10-27OpenAlex

Introduction ‘Water is the most ubiquitous plasticizer in our world.’ It has become well established that plasticization by water affects the glass-to-rubber transition temperatures ( T g ) of many synthetic and natural amorphous polymers (particularly at low moisture contents), and that T g depression can be advantag…

biodegradable polymer synthesis and propertiesPolymer Science and PVCPolymer crystallization and properties

Raman scattering by optical phonons in In1−y−zAlyGazAs lattice matched to InP

R. Borroff、R. Merlín、Albert Chin 等 4 位作者1988-10-24Applied Physics Letters

We report on Raman scattering by longitudinal optical phonons in In1−y−zAlyGazAs (1−y−z=0.53) lattice matched to InP. The quaternary alloys were grown on (001) InP by molecular beam epitaxy. The phonon spectra exhibit three-mode behavior. The frequencies of AlAs- and GaAs-like modes vary linearly with the concentratio…

Nanowire Synthesis and ApplicationsSemiconductor Quantum Structures and DevicesSilicon Nanostructures and Photoluminescence