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Solvent-Dependent Swelling of Poly(amido amine) Starburst Dendrimers

Stefan Stechemesser、Wolfgang Eimer1997-04-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTSolvent-Dependent Swelling of Poly(amido amine) Starburst DendrimersStefan Stechemesser and Wolfgang EimerView Author Information Department of Chemistry, University of Bielefeld, P.O. Box 10 01 31, D-33 501 Bielefeld, GermanyCite t…

Polymer Surface Interaction StudiesLuminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

Crystal structure of monoclinic hydrous wadsleyite [beta -(Mg,Fe) 2 SiO 4 ]

Joseph R. Smyth、Tatsuhiko Kawamoto、Stephen D. Jacobsen 等 6 位作者1997-04-01American Mineralogist

Other| April 01, 1997 Crystal structure of monoclinic hydrous wadsleyite [β-(Mg,Fe)2 SiO4 ] Joseph R. Smyth; Joseph R. Smyth University of Colorado, Department of Geological Sciences, Boulder, CO, United States Search for other works by this author on: GSW Google Scholar Tatsuhiko Kawamoto; Tatsuhiko Kawamoto Search f…

Geological and Geochemical AnalysisCrystal Structures and PropertiesClay minerals and soil interactions

The use of the split Hopkinson pressure bar techniques in high strain rate materials testing

M.M. Al-Mousawi、S.R. Reid、W.F. Deans1997-04-01Proceedings of the Institution of Mechanical Engineers Part C Journal of Mechanical Engineering Science

The use of the split Hopkinson pressure bar (SHPB) techniques for materials testing under a high rate of loading is described, including various modifications of the original compression testing set-up for tension testing, torsion testing and dynamic fracture testing. Details of measurement techniques and instrumentat…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorElectromagnetic Launch and Propulsion Technology

Surface effects in ferroelectrics: Periodic slab computations for BaTiO3

R. E. Cohen1997-04-01Ferroelectrics

Total energies, electronic structure, surface energies, polarization, potentials and charge densities were studied for slabs of BaTiO3 using the Linearized Augmented Plane Wave (LAPW) method. The depolarization field inhibits ferroelectricity in the slabs, and the macroscopic field set up across a ferroelectric slab i…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Enhanced Adhesion between Polypropylene and Polyamide-6: Role of Interfacial Nucleation of the β-Crystalline Form of Polypropylene

E. Boucher、John P. Folkers、Costantino Creton 等 5 位作者1997-04-01Macromolecules

We present an investigation of the mechanisms of mechanical reinforcement at interfaces between polypropylene (PP) and polyamide-6 (PA6), associated with the incorporation of a small amount of maleic anhydride functionalized PP (PP- g -MA) which reacts with the NH 2 groups of the PA6 to form a copolymer in situ. In a…

Mechanical Behavior of CompositesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Pressure Dependence of the 100 K Spin-State Transition in LaCoO3

Kichizo Asai、Osamu Yokokura、Masaru Suzuki 等 8 位作者1997-04-01Journal of the Physical Society of Japan

The pressure dependence of the 100 K spin-state transition in LaCoO 3 is investigated through magnetization measurement under pressures of up to 18.2 kbar. The energy gap, Δ, between the low-spin ground state and the excited magnetic state (intermediate spin) increases remarkably with increasing pressure. The linear p…

Advanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materialsRare-earth and actinide compounds

Observation and investigation of the ferrielectric subphase with highqTparameter

Yu. P. Panarin、O. E. Kalinovskaya、J. K. Vij 等 4 位作者1997-04-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Dielectric relaxation processes in an antiferroelectric liquid crystal (AFLC) have been investigated over a wide range of frequencies from 1 Hz to 1 GHz. The AFLC under investigation possesses a variety of different ferrielectric, ferroelectric, and antiferroelectric phases. Dielectric and polarization measurements un…

Liquid Crystal Research AdvancementsPhase-change materials and chalcogenidesMolecular spectroscopy and chirality

Fluorescence Spectroscopy on Single CdS Nanocrystals

J. Tittel、W. Göhde、Felix Koberling 等 7 位作者1997-04-01The Journal of Physical Chemistry B

By use of low-temperature (20 K) confocal microscopy, fluorescence spectra of isolated single CdS nanocrystals have been recorded. The narrowest measured line width of the main fluorescence band has been determined to be about 5 meV at the lowest excitation intensities. At higher intensities at least three additional…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Protein engineering reveals ancient adaptive replacements in isocitrate dehydrogenase

Antony M. Dean、G. Brian Golding1997-04-01Proceedings of the National Academy of Sciences

Evolutionary analysis indicates that eubacterial NADP-dependent isocitrate dehydrogenases (EC 1.1.1.42) first evolved from an NAD-dependent precursor about 3.5 billion years ago. Selection in favor of utilizing NADP was probably a result of niche expansion during growth on acetate, where isocitrate dehydrogenase provi…

Genomics and Phylogenetic StudiesEnzyme Structure and FunctionBiochemical and Molecular Research

Nanometer-Scale Patterning of Surfaces Using Self-Assembly Chemistry. 2. Preparation, Characterization, and Electrochemical Behavior of Two-Component Organothiol Monolayers on Gold Surfaces

William Hayes、Hyun Kim、Xiaohui Yue 等 5 位作者1997-04-01Langmuir

We report a study of the physical and electrochemical properties of two-component self-assembled monolayers (SAMs) composed of both electroactive (4-aminothiophenol, 4-ATP) and electroinactive ( n -octadecanethiol, ODT) species. In all of the experiments reported here, relatively short (3 h) assembly times were used t…

Conducting polymers and applicationsMolecular Junctions and NanostructuresElectrochemical Analysis and Applications

Synthesis of Pyrochlore‐Free 0.9Pb(Mg 1/3 Nb 2/3 )O 3 ‐0.1PbTiO 3 Ceramics via a Soft Mechanochemical Route

Jong‐Gab Baek、Tetsuhiko Isobe、Mamoru Senna1997-04-01Journal of the American Ceramic Society

Single‐phase perovskite 0.9Pb(Mg 1/3 Nb 2/3 )O 3 ‐0.1PbTiO 3 (0.9PMN–0.1 PT) from a stoichiometric mixture of starting materials was synthesized by applying a mechanochemical technique to the stage of a precursor. A stoichiometric mixture of PbO, TiO 2 , Mg(OH) 2 , and Nb 2 O 5 was milled for 60 min and heated at temp…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisDielectric properties of ceramics

Xanthine metabolism in Bacillus subtilis: characterization of the xpt-pbuX operon and evidence for purine- and nitrogen-controlled expression of genes involved in xanthine salvage and catabolism

Line Christiansen、Sverre Juul Schou、Per Nygaard 等 4 位作者1997-04-01Journal of Bacteriology

The xpt and pbuX genes from Bacillus subtilis were cloned, and their nucleotide sequences were determined. The xpt gene encodes a specific xanthine phosphoribosyltransferase, and the pbuX gene encodes a xanthine-specific purine permease. The genes have overlapping coding regions, and Northern (RNA) blot analysis indic…

Bacterial Genetics and BiotechnologyEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Fabrication and Sintering of Fine Yttria‐Doped Ceria Powder

Jan Van herle、Teruhisa Horita、‪Tatsuya Kawada 等 6 位作者1997-04-01Journal of the American Ceramic Society

Yttria–doped ceria powder was prepared from oxalate precursors. The oxalate coprecipitation bath parameters were closely monitored and found to influence the sintering behavior of the subsequently obtained oxide powders strongly. The use of concentrated (Ce,Y) metal nitrate solutions and dilute neutralized oxalic acid…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisThermal and Kinetic Analysis

Amphiphilic N-benzoyl-1-amino-1-deoxy-D-glucitol derivatives forming thermotropic lamellar, columnar and different types of cubic mesophases

Konstanze Borisch、Siegmar Diele、Petra Göring 等 5 位作者1997-04-01Liquid Crystals

Novel amphiphilic glucamine derivatives have been synthesized. These are N-benzoyl-1-deoxy1-methylamino-D-glucitols and N-benzoyl-1-amino-1-deoxy-D-glucitols carrying one, two or three aliphatic chains (CnH2n 1O- with n 3, 6 and 12) grafted to the benzamido group. The thermotropic mesophases of these compounds were st…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsCarbohydrate Chemistry and Synthesis

Low-temperature specific heat of κ-(BEDT-TTF)2Cu[N(CN)2]Br in the superconducting state

Yasuhiro Nakazawa、Kazushi Kanoda1997-04-01Physical review. B, Condensed matter

The low-temperature specific heat of single crystals of \ensuremath{\kappa}-(BEDT-TTF${)}_{2}$ Cu[N(CN${)}_{2}$ ]Br was studied in the temperature range between 0.11 and 4.5 K. The electronic specific heat, ${\mathrm{C}}_{\mathrm{el}}$, in the superconducting state shows a quadratic temperature dependence that is most…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesOrganic and Molecular Conductors Research

In situ Spectroscopy of Polymers Subjected to Supercritical CO 2 : Plasticization and Dye Impregnation

Sergei G. Kazarian、Noel H. Brantley、Barry L. West 等 5 位作者1997-04-01Applied Spectroscopy

In situ FT-IR spectroscopy has been used to study poly(methyl methacrylate) films subjected to high-pressure and supercritical CO 2 . Spectral changes indicate increased molecular mobility of ester groups due to the plasticization effect of CO 2 on PMMA. This increase in PMMA segmental mobility has been used to impreg…

Phase Equilibria and ThermodynamicsInjection Molding Process and PropertiesPolymer Foaming and Composites

Recent Advances in Flame Retardancy of Polymeric Materials

Г. Е. Заиков1997-04-01International Journal of Polymeric Materials

The Seventh Annual Conference on Flame Retardancy was held in International Plaza Hotel in Stamford, Connecticut, USA on May 20-22, 1996, As before it was organized and sponsored by Business Communications Company (BCC). Scientists from 15 countries (USA, Canada, Germany, Israel, Russia, Belorussia, Italy, UK, China,…

Flame retardant materials and properties

A review of high dielectric materials for DRAM capacitors

David E. Kotecki1997-04-01Integrated ferroelectrics

There has been growing interest in the use of materials with the perovskite structure as a dielectric for capacitors in dynamic random access memory chips. The heightened activity in this field is exemplified by the nearly exponential increase in the number of patents issued during the past 5 years. At the present tim…

Ferroelectric and Piezoelectric MaterialsSemiconductor materials and devicesDielectric materials and actuators

Effective Hamiltonian in manganites:mStudy of the orbital and spin structures

Sumio Ishihara、Jun-ichiro Inoue、Sadamichi Maekawa1997-04-01Physical review. B, Condensed matter

In order to study nature of the electronic structures in manganites, the effective Hamiltonian is derived by taking the degeneracy of the ${\mathrm{e}}_{\mathrm{g}}$ orbitals and the strong electron correlation into account. The spin and orbital ordered phases in the insulating states are studied in the mean-field app…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

The Use and Application of Red‐Phosphorous Pyrotechnic Composition for camouflage in the infrared region of radiation

Ladislav Klusáček、Philip R. Navratil1997-04-01Propellants Explosives Pyrotechnics

Abstract Under laboratory conditions, there were detected burning products of pyrotechnic compositions based on red phosphorus with epoxy resin being especially trihydrogenphosphoric acid, tetrahydrogendiphosphoric acid and mixture of cyclo ‐triphosphoric acid, cyclo ‐tetraphosphoric acid and cyclo ‐hexaphosphoric aci…

Flame retardant materials and propertiesMaterial Properties and ApplicationsEnvironmental and Industrial Safety