Materials Literature
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ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTrans-cis photoisomerization of the stilbenes and a reexamination of the positional dependence of the heavy-atom effectJack Saltiel, A. Marinari, David W. L. Chang, James C. Mitchener, and E. Dennis MegarityCite this: J. Am. Chem. Soc. 1979, 101, 11, 2982–2996Publication Dat…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMetamagnetic properties of one-dimensional decamethylferrocenium 7,7,8,8-tetracyano-p-quinodimethanide (1:1):[Fe(.eta.5-C5Me5)2]+.cntdot.(TCNQ)-.cntdot.G. A. Candela, L. J. Swartzendruber, Joel S. Miller, and M. J. RiceCite this: J. Am. Chem. Soc. 1979, 101, 10, 2755–2756Pub…
It is shown that microchannel plates (MCPs) tend to act as if they were discrete stage electron multipliers with a fixed number of stages or dynodes if a plausible assumption is made regarding the behavior of the secondary electrons emitted from the semiconducting sidewalls of tubular channel electron multipliers unde…
γ irradiation of vitreous silica normally leads to the formation of a large number of optical defects and to an increase in density. Irradiation of hydrogen-impregnated vitreous silica suppresses the formation of these optical defects, but does result in the formation of large quantities of bound hydroxyl and hydride.…
Abstract The variation of solution Al 3+ activity with pH, the effect of suspending salt solution cation on Al 3+ activity, and the buffering intensity were determined for salt solution suspensions of three soil samples and an Al substituted peat that contained one equivalent of Al 3+ for each equivalent of carboxyl g…
A new high pressure volumetric technique, which employs a fine glass capillary as joint sample chamber and pressure vessel is described. Because of the small samples used, it is suitable for supercooled liquid studies. The compressibilities κT of water and of D2O have been determined over the applied pressure range 0.…
The oxidation state of iridium ions in an oxide film, grown electrochemically on an Ir metal reflector electrode, can be rapidly and reversibly modulated according to the electrochromic redox reaction Ir OH n transparent ⇄ IrO x OH n − x blue ‐ black + x H + + xe By suitable choice of electrolyte composition and poten…
In this paper we reinterpret the magnetic-susceptibility data and present and discuss specificheat data on MEM-${(\mathrm{TCNQ})}_{2}$ in terms of a spin-Peierls transition theory. We find that the data can be described reasonably well by a mean-field spin-Peierls transition theory which suggests that at low temperatu…
Abstract Fourier‐transform infrared (FTIR) studies of the poly(ϵ‐caprolactone) (PCL)–poly(vinyl chloride) (PVC) blend system are presented. The results indicate that there are specific interactions between the PCL and PVC in both the molten and solid states which could be responsible for the apparent compatibility of…
Calcium ion plays an essential role in many biological processes. The environment about Ca 2+ may be probed by substitution of tripositive lanthanide ions, Ln 3+ . Ca 2+ proteins fall into two broad classes: those that are inhibited by Ln 3+ substitution and those that are not. It is suggested that although Ca 2+ unde…
Microstructural development during aging of supersaturated solid solutions of cubic ZrO, stabilized with MgO was studied, principally using transmission electron microscopy. The starting materials were commercial Mg‐PSZ, solution‐annealed at 1850°C for 4 h. Optimum mechanical properties are obtained at aging temperatu…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRaman and ultraviolet spectroscopic characterization of molybdena on alumina catalystsHelge. Jeziorowski and Helmut. KnoezingerCite this: J. Phys. Chem. 1979, 83, 9, 1166–1173Publication Date (Print):May 1, 1979Publication History Published online1 May 2002Published inissue…
A rigorous theoretical formalism describing the diffraction of a P polarised plane wave by a perfectly conducting double grating is presented. The use of such structures as long wavelength Fabry-Perot interferometers is investigated and the individual effects of the design parameters are determined. In particular, it…
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The single-crystal elastic moduli C ij and their pressure derivatives dC ij /dP have been measured ultrasonically at 25 degrees C for six Ti-V-Cr, eight Nb-Mo and seven Ta-W solid solutions. The rigid-band model for the alloy electronic structure is known to work fairly well for these BCC metals in predicting the dens…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA molecular orbital study of strong metal-support interaction between platinum and titanium dioxideJ. A. HorsleyCite this: J. Am. Chem. Soc. 1979, 101, 11, 2870–2874Publication Date (Print):May 1, 1979Publication History Published online1 May 2002Published inissue 1 May 1979…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDeconvolution of fluorescence decay curves. A critical comparison of techniquesD. V. O'Connor, W. R. Ware, and J. C. AndreCite this: J. Phys. Chem. 1979, 83, 10, 1333–1343Publication Date (Print):May 1, 1979Publication History Published online1 May 2002Published inissue 1 Ma…
Abstract not Available.
The changes in the properties of copolymers as a function of the introduction of units with carboxy- and salt groups into the macrochain are examined. Attention is concentrated on the analysis of the results of the study of copolymers in the acid and ionomeric forms in solutions. The decisive influence of ionic intera…
The quenching by an electric field of molecular-orientation fluctuations in freely suspended ferroelectric smectic-$C$ films has been studied by light scattering, allowing absolute measurements of polarization, elastic constants, and viscosities. Evidence is presented to demonstrate surface contributions to Frank elas…