Materials Literature
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The red luminescence of bismuth-doped alkaline-earth-metal sulfates is ascribed to the presence of divalent bismuth The optical transitions are due to transitions within the 6p shell.
Five new trisiloxane quaternary ammonium compounds were synthesized from hydrotrisiloxane with allyl glycidyl ether to yield the epoxy function. Various amines were then reacted to yield trisiloxane amines which were further reacted to methyl substitute or oxidize the beta-carbons in order to provide thermal stability…
Colony groups that form large amounts of slime externally were obtained from activated sludge among phthalate-assimilating microbes. That slime, which R-3 mixed microbes produced externally, had a high level of flocculation activity. R-3 mixed strains, one of such colony groups, efficiently produced a bioflocculant (A…
The magnetoelectric effect of Cr2O3 single crystals has been studied in magnetic fields up to 20 T in the range of liquid helium to room temperature In the antiferromagnetic phase for low magnetic fields the well known results for the magnetoelectric effect below the Néel temperature were reproduced. In the spin-flop…
This paper considers the major design factors which constrain the maximum acceleration capability of surface-mounted neodymium-iron-boron permanent magnet motors as used in servo drives. Expressions are derived for typical achievable values of the air-gap flux density and the linear current density around the stator p…
The effect of a two-component dry bonding system consisting of resorcinol and hexamethylene tetramine on the mechanical and viscoelastic properties of short sisal fiber reinforced natural rubber composites has been studied. The studies were conducted with chemically treated and untreated short sisal fibers. Treated fi…
Abstract The dielectric constant of ferroelectric ceramics shows strong Debye‐like relaxation at GHz frequencies. This relaxation is caused by sound generation inside the crystallites. The ferroelastic domain walls which vibrate in the electric ac field are very effective shear wave transducers. The shear wave emissio…
Multilamellar liposomes consisting of dipalmitoyl phosphatidylcholine (DPPC) and dicetyl phosphate (DCP) in a molar ratio of 8:2 (DPPC:DCP = 8:2) were coated with three different types of polymers: chitosan, polyvinyl alcohol having a long alkyl chain, and poly(acrylic acid) bearing cholesterols. The existence of poly…
Sommaire : 1.Fibrous reinforcements for composite materials. 2.Matrices. 3.Fabrication of polymer composites. 4.Mechanical properties of composites - micromechanics. 5.Mechanical properties - macromechanics. 6.Environmental aspects
This paper discusses the results of a basic study for the development of 500 kV XLPE power cables. The authors have established that the factors that decide the performance of today's XLPE cables are impurities in the insulator and protrusions on the semiconductive layer, and that the insulation performance of XLPE po…
Sn3S7·(NMe4)2·H2O has been shown to consist of the framework of composition [Sn3S7]2– with the two exchangeable [NMe4]+ ions occupying cavities in the structure; these molecules can be exchanged with a variety of alkali, alkali earth and transition metal cations.
In order to obtain the diffusion coefficient of hydrogen in iron free from trapping by dislocations and impurities, electrochemical permeation measurements have been done using high purity iron (99.99 mass% Fe), pure iron (99.99 mass% Fe, high substitutional and low interstitial impurity contents), pure iron (99.94 ma…
The sol-gel process opens the possibility of combining inorganic and organic units on a molecular or nanosized level. The flexible chemical approach of tailoring inorganic structures as well as organic polymeric structures in combination with the new concept of incorporation of nanoscaled metal oxide particles opens t…
The mechanical alloying (MA) process was developed in the mid-1960s and has evolved to commercial status with the production of oxide dispersion strengthened INCONEL® and INCOLOY® 1 MA alloys. These Ni- and Fe-based alloys possess exceptional high temperature strength, high temperature stability, and hot corrosion res…
The number and strength of the acid centres of tungstic heteropolyacids have been determined by absorption calorimetry of ammonia. The initial heats are in the order H3PW12O40>H4SiW12O40>H6P2W21O71(H2O)3>H6P2W18O62, varying from 200 to 155kJ mol–1. An increase in the number of protons in Keggin heteropolyanions decrea…
In-reactor and long-term autoclave corrosion data have been obtained on ZIRLO and three variants of Zircaloy-4: conventional (1.5% tin), low-tin, and beta-treated. In-reactor data from demonstration assemblies irradiated in the Virginia Power Company's North Anna Unit 1 reactor demonstrate the superiority of ZIRLO and…
Open lamellar systems such as layered double hydroxides (LDHs) can be used to generate new intercalation compounds. We report the synthesis of nanocomposite materials consisting of organopolymer molecules encapsulated between ultra-thin mixed-metal hydroxide sheets which are propped apart by spacers [terephthalate or…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTEffect of hard-segment flexibility on phase separation of segmented polyurethanesYingjie Li, Wanxuan Kang, James O. Stoffer, and Benjamin ChuCite this: Macromolecules 1994, 27, 2, 612–614Publication Date (Print):January 1, 1994Publication History Published online1 May 2002Pu…
We have measured simultaneously both the normal forces F⊥(D) and the shear forces F∥(D) that act between compressed polymer-bearing mica surfaces, a distance D apart, as they slide past each other. We find that for surface-attached polystyrene (PS) brushes in the good solvent toluene the shear forces are extremely wea…
We have determined the segregation of diblock copolymers of deuterated polystyrene (dPS) and poly(2-vinylpyridine) (PVP) to a planar interface between the homopolymers using forward recoil spectrometry. The segregation isotherms, namely the interfacial excess versus its volume fraction in the homopolymer phase far fro…