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Displacement of the Bandedges of GaInP2 in Aqueous Electrolytes Induced by Surface Modification

Shyam S. Kocha、John A. Turner1995-08-01Journal of The Electrochemical Society

The surface of epi layer p ‐ GaInP 2 electrodes was treated using 8‐quinolinol, cupferron, and ferrocyanide, producing a modified surface directed at varying the Helmholtz layer charge. Mott‐Schottky and photocurrent‐voltage measurements were carried out to determine if there was any shift in the flatband potential or…

Quantum Dots Synthesis And PropertiesSemiconductor materials and devicesSemiconductor materials and interfaces

Hot Isostatic Pressing and Characterization of Sol‐Gel‐Derived Chromium(III) Oxide

Akio Kawabata、Masaru Yoshinaka、Ken Hirota 等 4 位作者1995-08-01Journal of the American Ceramic Society

Chromium (III) oxide (Cr 2 O 3 ) crystallizes at low temperatures from an amorphous material prepared by adding hydrazine monohydrate to an aqueous solution of Cr(NO 3 ) 3 ‐9H 2 O. Individual particles of Cr 2 O 3 tend toward a hexagonal morphology above 800°C. Well‐densified Cr 2 O 3 pellets (98.8% of theoretical den…

Advanced ceramic materials synthesisAdvanced materials and compositesInorganic Chemistry and Materials

Perfluorocyclobutane aromatic ether polymers. II. Thermal/ oxidative stability and decomposition of a thermoset polymer

Alvin P. Kennedy、David A. Babb、Jeffrey N. Bremmer 等 4 位作者1995-08-01Journal of Polymer Science Part A Polymer Chemistry

Abstract The results of thermal and oxidative stability studies are reported for one perfluorocyclo‐butane aromatic ether thermoset polymer. The polymer was prepared from 1,1,1‐tris (4‐trifluorovinyloxyphenyl)ethane by the thermal cyclodimerization of the trifluorovinyl either functionality, resulting in a network pol…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersChemical Thermodynamics and Molecular Structure

Investigation of flexoelectric properties of a palladium-containing nematic liquid crystal, Azpac, and its mixtures with MBBA

А. Г. Петров、Andreea Ionescu、C. Versacé 等 4 位作者1995-08-01Liquid Crystals

Flexoelectricity of pure Azpac (an HOAB-palladium complex) was studied using planar nematic layers under an in-plane electric field. Longitudinal domains were observed with a period inversely proportional to the applied d.c. electric field. These domains were considered as a first experiment manifestation of the theor…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationNonlinear Photonic Systems

Surface properties of EPDM, silicone rubber, and their blend during aging

Anil K. Bhowmick、J. Konar、Swapan Kole 等 4 位作者1995-08-01Journal of Applied Polymer Science

Abstract Surface energy of EPDM, silicone rubber, and their 50 : 50 (by weight) blend during aging was determined by contact angle measurement using water and formamide as the probe liquids. The surface energy increases initially with aging time. The results are explained on the basis of the polar component of the sur…

Surface Modification and SuperhydrophobicityHigh voltage insulation and dielectric phenomenaSurface Roughness and Optical Measurements

A 29 Si MAS NMR and IR spectroscopic investigation of synthetic pyrope-grossular garnet solid solutions

Anne Bosenick、Charles A. Geiger、Torsten Schaller 等 4 位作者1995-08-01American Mineralogist

Other| August 01, 1995 A 29Si MAS NMR and IR spectroscopic investigation of synthetic pyrope-grossular garnet solid solutions Anne Bosenick; Anne Bosenick Christian-Albrechts-Universitaet zu Kiel, Mineralogisch-Petrographisches Institut, Kiel, Federal Republic of Germany Search for other works by this author on: GSW G…

High-pressure geophysics and materialsCrystal Structures and PropertiesMineralogy and Gemology Studies

Docking of congo red to the surface of crystalline cellulose using molecular mechanics

Steve Woodcock、Bernard Henrissat、Junji Sugiyama1995-08-01Biopolymers

A method for the docking of ligands to crystalline surfaces using molecular mechanics was developed and applied to study the molecular features of the adsorption of Congo Red to cellulose crystals. The docking procedure was based on a grid search exploring the surface repeat unit of the cellulose crystals using severa…

Advanced Cellulose Research StudiesLignin and Wood ChemistryNanomaterials for catalytic reactions

The AC Impedance Response of the Physical Interface Between Yttria‐Stabilized Zirconia and YBa2Cu3 O 7 − x

James G. Fletcher、Anthony R. West、John T. S. Irvine1995-08-01Journal of The Electrochemical Society

Composite electrochemical cells incorporating press‐contact pellets of yttria‐stabilized zirconia (YSZ), electronically blocking electrodes, and YBa 2 Cu 3 O 7 − x ( YBCO ) were investigated by ac impedance spectroscopy. An additional element, not attributable to either of the individual components, was observed in th…

Advancements in Solid Oxide Fuel CellsIonic liquids properties and applicationsAdvanced Condensed Matter Physics

Tetragonal—Monoclinic Phase Transition Enthalpy and Temperature of ZrO 2 ‐CeO 2 Solid Solutions

Masatomo Yashima、T. Mitsuhashi、Hiroyuki Takashina 等 6 位作者1995-08-01Journal of the American Ceramic Society

DSC (differential scanning calorimeter) measurements were performed to investigate the tetragonal‐monoclinic ( t‐m ) transition enthalpy of the compositionally homogeneous ZrO 2 ‐ X mol% CeO 2 solid solution of X = 0, 4, 8, and 12. The transition enthalpy decreases linearly with an increase of CeO 2 content. The m → t…

Nuclear Materials and PropertiesThermal and Kinetic AnalysisThermal Expansion and Ionic Conductivity

Mechanically Activated MoO3. 2. Characterization of Defect Structures

Gerhard Mestl、Nathalie Verbruggen、H. Knoezinger1995-08-01Langmuir

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMechanically Activated MoO3. 2. Characterization of Defect StructuresG. Mestl, N. F. D. Verbruggen, and H. KnoezingerCite this: Langmuir 1995, 11, 8, 3035–3041Publication Date (Print):August 1, 1995Publication History Published online1 May 2002Published inissue 1 August 1995…

Transition Metal Oxide Nanomaterials

High yield synthesis of mixed-metal keggin polyoxoanions in non-aqueous solvents: Preparation of (n-Bu4N)4[PMW11O40] (M = V, Nb, Ta)

E. Radkov、Robert Beer1995-08-01Polyhedron

The synthesis of (n-Bu4N)4[PMW11O40] (M = V, Nb, Ta) in non-aqueous solvents is described using the lacunary compound (n-Bu4N)4H3[PW11O39] and commercially available VOCl3, NbCl5 and TaCl5. The yield and purity of the product vary depending on the solvent and the presence of base. 183W NMR spectroscopy of the title co…

biodegradable polymer synthesis and propertiesPolyoxometalates: Synthesis and ApplicationsSulfur-Based Synthesis Techniques

Thermodynamic Parameters for Cobalt-Quinone Electron Transfer and Spin Transition Steps of the CoIII(bpy)(3,5-DBSQ)(3,5-DBCat)/CoII(bpy)(3,5-DBSQ)2 Valence Tautomeric Equilibrium

Cortlandt G. Pierpont、Ok‐Sang Jung1995-08-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThermodynamic Parameters for Cobalt-Quinone Electron Transfer and Spin Transition Steps of the CoIII(bpy)(3,5-DBSQ)(3,5-DBCat)/CoII(bpy)(3,5-DBSQ)2 Valence Tautomeric EquilibriumCortlandt G. Pierpont and Ok-Sang JungCite this: Inorg. Chem. 1995, 34, 16, 4281–4283Publication…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer Studies

The [Co4O4]4+ Cubane as a Quadruply-Bridging Unit: The Mixed-Valence Cluster [Co8O4(O2CPh)12(solv)4] (solv = DMF, MeCN, H2O)

Katerina Dimitrou、Jui-Sui Sun、Kirsten Folting 等 4 位作者1995-08-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe [Co4O4]4+ Cubane as a Quadruply-Bridging Unit: The Mixed-Valence Cluster [Co8O4(O2CPh)12(solv)4] (solv = DMF, MeCN, H2O)Katerina Dimitrou, Jui-Sui Sun, Kirsten Folting, and George ChristouCite this: Inorg. Chem. 1995, 34, 16, 4160–4166Publication Date (Print):August 1, 1…

Metal complexes synthesis and propertiesPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications

The Effect of Turbulence on Solidification of a Binary Metal Alloy With Electromagnetic Stirring

P. J. Prescott、F. P. Incropera1995-08-01ASME Journal of Heat and Mass Transfer

Electromagnetic induction is considered as a means of altering convection during the solidification of a Pb–19 wt pct Sn alloy. Application of a time-varying magnetic field induces Lorentz forces, which augment thermal buoyancy forces in the melt and oppose solutal buoyancy forces in the mushy zone. A continuum model…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaMetallurgical Processes and Thermodynamics

Phonon modes and vibrational entropy of mixing in Fe-Cr

Brent Fultz、Laurence Anthony、J. L. Robertson 等 6 位作者1995-08-01Physical review. B, Condensed matter

Results from neutron inelastic-scattering experiments on Fe, Cr, and three bcc Fe-Cr alloys were analyzed with a Born--von K\'arm\'an model to obtain phonon density-of-states (DOS) curves. We compared the phonon DOS of the bcc Fe-Cr alloys to the composite phonon DOS from appropriate fractions of the phonon DOS of the…

High-pressure geophysics and materialsNuclear Materials and PropertiesNuclear Physics and Applications

Selective quinone formation by oxidation of aromatics with heteroaromatic N-oxides catalyzed by ruthenium porphyrins.

Tsunehiko Higuchi、Chika Satake、Masaaki Hirobe1995-08-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSelective quinone formation by oxidation of aromatics with heteroaromatic N-oxides catalyzed by ruthenium porphyrins.Tsunehiko Higuchi, Chika Satake, and Masaaki HirobeCite this: J. Am. Chem. Soc. 1995, 117, 34, 8879–8880Publication Date (Print):August 1, 1995Publication His…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsOxidative Organic Chemistry Reactions

Effects of Iron and Aluminium Oxides on the Colloidal and Surface Properties of Kaolin

Manuel Arias‐Estévez、María Teresa Barral、Francisco Dı́az-Fierros Viqueira1995-08-01Clays and Clay Minerals

Abstract The association between clay silicates, and iron and aluminium oxides has a major influence on the chemical and physical properties of soils. In this work the interaction of a kaolin substrate with iron and aluminium oxides and/or hydroxides obtained by basification of solutions of the metal ions was compared…

Soil and Unsaturated FlowClay minerals and soil interactionsIron oxide chemistry and applications

Kinetics and Mechanism of the Oxidation of HSO3- by O2. 1. The Uncatalyzed Reaction

Robert E. Connick、Yixue Zhang、Shaoyung Lee 等 5 位作者1995-08-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTKinetics and Mechanism of the Oxidation of HSO3- by O2. 1. The Uncatalyzed ReactionRobert E. Connick, Yi-Xue Zhang, Shaoyung Lee, Raymond Adamic, and Paul ChiengCite this: Inorg. Chem. 1995, 34, 18, 4543–4553Publication Date (Print):August 1, 1995Publication History Publishe…

Advanced oxidation water treatmentThermal and Kinetic AnalysisIndustrial Gas Emission Control

Thermodynamic and magnetic properties of theS=1 Heisenberg chain Ni(C2H8N2)2Ni(CN)4: Experiments and theory

M. Orendáč、A. Orendáčová、Juraj Černák 等 8 位作者1995-08-01Physical review. B, Condensed matter

Specific-heat and susceptibility studies of powdered Ni(${\mathrm{C}}_{2}$${\mathrm{H}}_{8}$${\mathrm{N}}_{2}$${)}_{2}$Ni(CN${)}_{4}$ have been performed from 50 mK to 20 K, and magnetization measurements have been conducted at 4.3 K in magnetic fields up to 6 T. The results show that Ni(${\mathrm{C}}_{2}$${\mathrm{H}…

Physics of Superconductivity and MagnetismMagnetism in coordination complexesOrganic and Molecular Conductors Research

Surface-Plasmon-Polariton-Enhanced Raman Scattering from Self-Assembled Monolayers of p-Nitrothiophenol and p-Aminothiophenol on Silver

Masayuki Futamata1995-08-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSurface-Plasmon-Polariton-Enhanced Raman Scattering from Self-Assembled Monolayers of p-Nitrothiophenol and p-Aminothiophenol on SilverMasayuki FutamataCite this: J. Phys. Chem. 1995, 99, 31, 11901–11908Publication Date (Print):August 1, 1995Publication History Published onl…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon Research