Materials Literature
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Abstract Experiments on zeolitization were conducted on four synthetic monocationic glasses (Na, K, Ca, or Mg-rich glass) with Si/Al molar ratios of 2.67, similar in acidity to many volcanic glasses of partially zeolitized Italian tuffs. The products of the hydrothermal treatment at 100, 150, and 200°C of single glass…
The objectives of the present research are to understand better the degradation of crosslinked polyethylene tubing subjected to pressurised, hot chlorinated water in flow through systems (e.g. home plumbing) and to estimate its service lifetime. Crosslinked polyethylene tubing was subjected to pressure testing with fl…
Abstract The adsorption of the silane coupling agents N -(2-amino-ethyl)-3-aminopropyl- trimethoxysilane (Z-6020), N -(2-(vinylbenzyl-amino)-ethyl)-3-amino-propyl-trimethoxysilane (Z-6032) and 3-glycidoxy-propyl-trimethoxysilane (Z-6040) onto the surface of kaolinite has been studied using the solvents water and ethan…
Electronic charge transport in insulating polymers is briefly discussed, particularly the measurement of charge carrier mobility. The more frequently used techniques of space charge profile measurent in dielectrics are then described, and data for polyethylene published during the last 5-6 years are reviewed.
Recipes are given to assist in setting up rigid bodies for common molecules and coordination polyhedra, to define satellite groups, to perform rotations around arbitrary axes through the origin of the rigid body, and to refine intramolecular degrees of freedom under consideration of the special needs of powder diffrac…
Indium tin oxide thin films have been deposited on glass substrates using rf magnetron sputtering at different power densities (0.27–0.80 W/cm 2 ) and at different substrate temperatures (RT-250) °C. Film structure, crystallite size and orientation, optical absorption and bandgap have been studied to characterize the…
The anisotropy ratios (parallel to the c axis versus perpendicular to the c axis) for the electrical resistivity, Seebeck coefficient, and thermal conductivity of horizontal Bridgman-grown n-type (Bi2Te3)90 (Sb2Te3)5 (Sb2Se3)5 and p-type (Sb2Te3)72 (Bi2Te3)25 (Sb2Se3)3 were measured at 300 K. The orientation having th…
We have developed a new high sensitive magnetic method for non-destructive testing (NDT) of small ferrous inclusions in aircraft engine discs. The measuring method is based on a second order gradiometer using three thin film Superconducting Quantum Interferometer Devices (SQUIDs) as magnetic sensors. The high balance…
Abstract Recent research on fouling in desalination systems, cooling towers, ocean thermal energy conversion (OTEC) heat exchangers, salinity power plants (SPP), etc. where composite inorganic and biological fouling may be present is reviewed. Crystallization or precipitation fouling is the most studied type of foulin…
The Pt/PbZrxTi1−xO3 (PZT) interfacial reaction caused by low-temperature (320 °C) annealing and resulting change in the surface Fermi level position (Schottky barrier height) has been studied by using in vacuo x-ray photoelectron spectroscopy (XPS). A thin (2 nm) Pt layer was deposited on a polycrystalline PZT film an…
The purpose of this paper is to show how voltage distortion may cause accelerated aging of insulation systems, particularly of self-healing capacitors. Distortion is due to the presence, in the supply voltage waveform, of harmonics which are typically detected in distribution ac networks. These harmonics sum up to the…
ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTSynthesis of a New Side-Chain Type Liquid Crystal Polymer Poly[dicyclohexyl vinylterephthalate]Dong Zhang, Yuxiang Liu, Xinhua Wan, and Qi-Feng ZhouView Author Information Department of Polymer Science & Engineering, College of Chem…
Using broad band dielectric spectroscopy (10(-5)-10(9) Hz), combining time domain and frequency domain techniques, we study the temperature dependence of the non-Debye character of the alpha relaxation of polymer melts in the glass transition temperature T(g) range. The alpha relaxation process is described in terms o…
Abstract Formation of authigenic trioctahedral Mg-rich smectite is common in evaporative lake sediments, but was not described previously in modern marine evaporative environments. This study documents formation of authigenic K-rich, Mg-smectite during very early diagenesis in the dominantly siliciclastic Salina Omete…
The effects of rare earth metals on the morphology of γ-M2 C, γ-M6 C, and γ-MC eutectics of as cast M2 high speed steel were investigated. The solidification of the specimens was monitored by conventional and differential thermal analysis and the characterisation of the microstructures was performed through optical an…
Abstract Zinc and metal-free amphiphilic phthalocyanines (pcs) substituted by four or eight tri(ethylene oxide) chains (3,6,9-trioxadecyloxy groups) {(H2(4EGpc), [Zn(4EGpc)], H2(8EGpc), and [Zn(8EGpc)] in Fig. 1)} have been prepared in order to study their aggregation in water, dioxane, and dioxane/water mixtures, the…
This study reports the synthesis of polyurethane–imide (PU–imide) copolymers using 4,4′-diphenylmethane diisocyanate (MDI) polytetramethylene glycols (PTMGs) and different aromatic dianhydrides. Differential scanning calorimetry (DSC) results indicate that PU–imide copolymers had two phase structures containing four t…
The depolymerization of PET, nylon 66, and nylon 46 at high temperatures in an autoclave is well known in the patent literature. We sought to invent processes for the depolymerization of PET, nylon 66, and nylon 46 in alkaline solutions at low temperatures and atmospheric pressure. A method was developed for the depol…
The recycling of nylon 6 carpet via depolymerization provides the potential for an environmentally benign new process to produce world-class caprolactam. This article describes the depolymerization of nylon 6 carpet in the presence of steam under medium pressure (800-1500 kPa, 100-200 psig). A small laboratory apparat…
Abstract The tensile properties of three types of injection molded glass bead (GB) filled polypropylene (PP)/ethylene‐propylene‐diene monomer (EPDM) ternary composites have been determined at room temperature by using an Instron materials testing machine. The effects of the filler surface treatment, the glass bead (GB…