Materials Literature
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${\mathrm{G}\mathrm{d}}_{5}{\mathrm{S}\mathrm{n}}_{4}$ exhibits a giant magnetocaloric effect comparable to that reported in the ${\mathrm{G}\mathrm{d}}_{5}(\mathrm{S}\mathrm{i},\mathrm{G}\mathrm{e}{)}_{4}$ system. The giant magnetocaloric effect is associated with a first-order change that occurs at $\ensuremath{\sim…
Powder and single-crystal X-ray diffraction, combined with MAS NMR measurements, has been used to study the thermal expansion of siliceous zeolite ferrierite as it approaches a second-order displacive phase transition from a low-symmetry (Pnnm) to a high-symmetry (Immm) structure. Below the transition temperature, fer…
Information about the partial structure factors of densified GeO2 glass has been obtained from neutron and x-ray diffraction measurements. Densification causes a reduction in the length scale of the intermediate range order (IRO). The difference structure factors obtained by combining the x-ray and neutron data so as…
We report the optical properties of three dioxythiophene-based conjugated polymers: poly(3,4-ethylenedioxythiophene) poly(3,4-propylenedioxythiophene), and poly(3,4-(2,2-dimethylpropylenedioxy)thiophene). Films of ca. 200 nm thickness of these polymers were prepared on indium-tin-oxide coated glass substrates using a…
The adsorption of ammonia, dimethylamine, and ethylamine on stoichiometric and slightly defective TiO 2 (110) surfaces was studied by means of TPRS and XPS. The slightly defective surfaces were prepared by exposing a clean stoichiometric surface to electron irradiation, resulting in the creation of point defects (oxyg…
The 2-aminopyrimidin-5-yl ligand is revealed to be a promising candidate for the construction of supramolecular porphyrin arrays with broad absorption bands for efficient light-harvesting. 10-Mono- and 10,20-di(2-aminopyrimidin-5-yl) derivatives of 5,15-bis(3,5-di-tert-butylphenyl)porphyrin have been synthesized in hi…
[reaction: see text] N-Confused porphyrin (NCP) bearing pentafluorophenyl groups at meso-positions, which were obtained from N-confused dipyrromethane in ca. 20% yield, can form Cu(II) complex as well as Ag(III), Ni(II), and Pd(II) complexes. The square-planar structures of all these metal complexes were elucidated by…
Self assembly produced high yields of the lanthanide ring complex Dy10(OC2H4OCH3)30, the largest lanthanide ring known, characterized by X-ray diffraction methods and by magnetic susceptibility as a function of temperature.
In solution phase synthesis of nanoparticles, processes such as coarsening and aggregation can compete with nucleation and growth in modifying the particle size distribution in the system. We report on the synthesis of ZnO nanoparticles from Zn(CH 3 CO 2 ) 2, ZnBr 2, and Zn(ClO 4 ) 2 in 2-propanol. For synthesis from…
Time-resolved fluorescence spectroscopy has been employed to probe the ultrafast emission observed in gold nanospheres and nanorods. The decay of the emission was found to be ≤50 fs. The ultrafast emission from nanorods has been directly compared to that for nanospheres and the dispersion of the relative local field e…
Plate-like particles of Ca3Co4O9 have been prepared in which Bi and Na were partially substituted for Ca to improve the thermoelectric performance. Successfully fabricated dense and highly textured ceramics have been obtained by combining the templated grain growth technique (TGG) with hot-pressing (HP). Ca3Co4O9 sing…
Herein we report results from quantum chemical calculations on a large series of pyrone-like model compounds which are relevant for carbon basicity. In consonance with previous work ( Carbon 1999, 37, 1002), pyrone-like functionalities at the edge of graphene layers are predicted to exhibit a broad range of p K a valu…
We have studied magnetic properties of heavily Mn-doped [(In0.44Ga0.56)0.79Mn0.21]As thin films grown by low-temperature molecular-beam epitaxy (LT-MBE) on InP substrates. The (InGaMn)As with high Mn content (21%) was obtained by decreasing the growth temperature to 190 degC. When the thickness of the [(In0.44Ga0.56)0…
The adsorption of oxygen on the Ag(001) is investigated by means of density functional techniques. Starting from a characterization of the clean silver surfaces oxygen adsorption in several modifications (molecularly, on-surface, sub-surface, Ag$_2$O) for varying coverage was studied. Besides structural parameters and…
Spatially and spectrally resolved microscopic images of spontaneous and stimulated emissions are imaged at the mirror facets of a GaAs T-shaped quantum wire laser with high uniformity. Laser emission from the one-dimensional ground state reveals a circular image located at the core of a T-shaped optical waveguide but…
The quasiparticle band structures of 3d transition metals, ferromagnetic Fe, Ni and paramagnetic Cu, are calculated by the GW approximation. The width of occupied 3d valence band, which is overestimated in the LSDA, is in good agreement with experimental observation. However the exchange splitting and satellite in spe…
The mean-square relative displacements (MSRD) of atomic pair motions in crystals are studied as a function of pair distance and temperature using the atomic pair distribution function (PDF). The effects of the lattice vibrations on the PDF peak widths are modelled using both a multi-parameter Born--von Karman (BvK) fo…
Anionic iron oxide nanoparticles are efficiently internalized into macrophages where they concentrate within micrometric endosomes, conferring on them a high magnetic susceptibility. The uptake of anionic maghemite nanoparticles by macrophages was quantified by an electron spin resonance (ESR) experiment. MR spin-echo…
Plasma fluorination followed by cross-linking of polybutadiene films gives rise to the formation of hard super-hydrophobic surfaces. The combined effect of low surface energy and substrate roughness is found to underpin the observed liquid repellency behavior.
Abstract Poly(oxybenzoate‐ co ‐oxynaphthoate) (POCO) film surfaces were modified with remote oxygen plasma, and the effects of the modification on the adhesion between the copper layer and POCO were investigated. The remote‐oxygen‐plasma treatment led to a noticeable decrease in the contact angle, which was mainly due…