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Novel Electron Acceptors Bearing a Heteroquinonoid System III: 2,5-Bis(dicyanomethylene)-2,5-dihydrofuran and Its Conjugated Homologues as Novel Oxygen-Containing Electron Acceptors

Hideki Ishida、Koji Yui、Yoshio Aso 等 5 位作者1990-10-01Bulletin of the Chemical Society of Japan

Abstract 2,5-Bis(dicyanomethylene)-2,5-dihydrofuran with a 2,5-furanoquinonoid skeleton and its extensive conjugated homologues, 5,5′-bis(dicyanomethylene)-5,5′-dihydro-Δ2,2′-bifuran (8a), and 5,5″-bis(dicyanomethylene)-5,5″-dihydro-Δ2,2′:5′,2″-terfuran (12a), have been prepared as a new type of oxygen-containing elec…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryOrganic and Molecular Conductors Research

Physical and Chemical Properties of a Typical Automatic Transmission Fluid

Steven P. Kemp、James L. Linden1990-10-01SAE technical papers on CD-ROM/SAE technical paper series

<div class="htmlview paragraph">Twenty-two physical and chemical properties of a typical automatic transmission fluid were determined. In most cases the properties were determined over a range of temperatures. In general, air solubility, volumetric thermal expansion, and specific heat increase with increasing te…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationAerosol Filtration and Electrostatic Precipitation

Effective thermal conductivity of binary dispersed composites over wide ranges of volume fraction, temperature, and pressure

Björn Håkansson、Russell G. Ross1990-10-01Journal of Applied Physics

The effective thermal conductivity of binary dispersed composites prepared from mixed and compacted powders of AgCl and low-density polyethylene was measured over the entire range of volume fraction at temperatures in the range 100–330 K together with pressures up to 1.75 GPa. Measurements were made using the transien…

High voltage insulation and dielectric phenomenaThermal properties of materialsComposite Material Mechanics

Consolidation of cushion curves

Gary Burgess1990-10-01Packaging Technology and Science

Abstract A simple method for the consolidation of all of the conventional cushion curves for a particular material into a single relationship is discussed. The method requires only one of the usual cushion curves for an arbitrary drop height and cushion thickness to deduce the dynamic stress‐strain curve for the mater…

High-Velocity Impact and Material BehaviorEngineering and Material Science ResearchTransportation Safety and Impact Analysis

Point Defects and the Pre-Dose Effect in Quartz

Xing Yang、S.W.S. McKeever1990-10-01Radiation Protection Dosimetry

Abstract The thermal annealing properties of (H3O4)0 centres in single crystal SiO2 were studies by means of electron spin resonance (ESR). The data indicate that these centres take part in the TL process at 110 oC in this material. The mechanism suggested for this TL signal is the thermal release of electrons from (G…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid-state spectroscopy and crystallography

Vibrational Spectroscopy and XPS for Atmospheric Corrosion Studies on Copper

Dan Persson、C. Leygraf1990-10-01Journal of The Electrochemical Society

The possible use of Fourier transform infrared reflection‐absorption spectroscopy (FT‐IRAS) and Raman spectroscopy for surface studies of thin (<10 nm) corrosion products on Cu has been explored. Cu samples were exposed to 75% relative humidity and 25°C in flowing air, with additions of 0.25 ppm of SO 2 and NO 2 . X‐r…

Corrosion Behavior and InhibitionMetal and Thin Film MechanicsElectron and X-Ray Spectroscopy Techniques

Thermalized and Hot Interstitial Halogen Ions in Alkali Halides

A. Lushchik、A. Frorip1990-10-01physica status solidi (b)

Abstract The efficiency of α, I pair creation at exciton decay is high at 4.2 K for KCl, KBr, and RbBr crystals for which H centers are oriented along 〈110〉. The efficiency of α, I pair creation by VUV‐irradiation at 4.2 K is extremely low for NaCl crystals for which H centers are oriented along 〈111〉. The process of…

Perovskite Materials and ApplicationsSpectroscopy and Quantum Chemical StudiesSolid-state spectroscopy and crystallography

The use of an electrogenerated cobalt(I) porphyrin for the homogeneous catalytic reduction of dioxygen in dimethylformamide. Reactions of [(TMpyP)CoII]4+ and [(TMpyP)CoI]3+ where TMpyP = meso-tetrakis(1-methylpyridinium-4-yl)porphyrin

Dimitra Sazou、C. Araullo-McAdams、Baocheng Han 等 5 位作者1990-10-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe use of an electrogenerated cobalt(I) porphyrin for the homogeneous catalytic reduction of dioxygen in dimethylformamide. Reactions of [(TMpyP)CoII]4+ and [(TMpyP)CoI]3+ where TMpyP = meso-tetrakis(1-methylpyridinium-4-yl)porphyrinD. Sazou, C. Araullo-McAdams, B. C. Han,…

Electrochemical sensors and biosensorsPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Effect of a coalescing aid on polymer diffusion in latex films

Yongcai Wang、Mitchell A. Winnik1990-10-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleEffect of a coalescing aid on polymer diffusion in latex filmsYongcai Wang and Mitchell A. WinnikCite this: Macromolecules 1990, 23, 21, 4731–4732Publication Date (Print):October 1, 1990Publication History Published online1 May 2002Published inissue 1 October 1990https://pubs.ac…

Surfactants and Colloidal SystemsPolymer Surface Interaction Studies

In situ FTIR and XPS studies of the hexacyanoferrate redox system

Monika Datta、Arunabha Datta1990-10-01The Journal of Physical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTIn situ FTIR and XPS studies of the hexacyanoferrate redox systemMonika. Datta and Arunabha. DattaCite this: J. Phys. Chem. 1990, 94, 21, 8203–8207Publication Date (Print):October 1, 1990Publication History Published online1 May 2002Published inissue 1 October 1990https://pu…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Unified thermodynamic analysis of sorption in rubbery and glassy materials

G. Glenn Lipscomb1990-10-01AIChE Journal

Abstract A thermodynamic framework for the analysis of gas sorption in glassy polymers is established in the limit of low sorption levels. The results represent an extension of the Flory‐Huggins theory to materials with nonzero internal energy changes due to deformation; the Flory‐Huggins theory is recovered in the li…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Foaming and Composites

Mie scattering used to determine spherical bubble oscillations

R. Glynn Holt、Lawrence A. Crum1990-10-01Applied Optics

Linearly polarized laser light is scattered from an oscillating, acoustically levitated bubble, and the scattered intensity is measured with a suitable photodetector. The output photodetector current is converted into a voltage and digitized. For spherical bubbles, the scattered intensity I(rel)(R,theta,t) as a functi…

Ultrasound and Cavitation PhenomenaNuclear Physics and ApplicationsPhotoacoustic and Ultrasonic Imaging

Solid Redox Polymerization Electrodes and Their Use in All-Solid-State Batteries

S.J. Visco、Meilin Liu、Michel Armand 等 4 位作者1990-10-01Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics

The dramatic proliferation of products based on semiconductor technology is a strong testament to the predictability and reliability of solid-state technology. In a similar vein, advances in materials exhibiting high levels of ionic conduction in the solid state has led to worldwide efforts in the development of all-s…

Supercapacitor Materials and FabricationAdvanced Battery Materials and TechnologiesConducting polymers and applications

The tertiary structure of a bacterial cellulase determined by small-angle X-ray-scattering analysis

Ingrid Pilz、Erika Schwarz、Douglas G. Kilburn 等 6 位作者1990-10-01Biochemical Journal

CenA from Cellulomonas fimi is a beta-1,4-endoglucanase that binds tightly to cellulose. X-ray-scattering analyses show that the enzyme is tadpole-shaped: the previously identified catalytic and cellulose-binding domains comprise the head and tail respectively. It appears that this structural and functional organizati…

Protein Structure and DynamicsEnzyme Structure and FunctionAdvanced NMR Techniques and Applications

Simple design of monolith reactor for selective catalytic reduction of nitric oxide for power plant emission control

Marek A. Buzanowski、Ralph T. Yang1990-10-01Industrial & Engineering Chemistry Research

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSimple design of monolith reactor for selective catalytic reduction of nitric oxide for power plant emission controlMarek A. Buzanowski and Ralph T. YangCite this: Ind. Eng. Chem. Res. 1990, 29, 10, 2074–2078Publication Date (Print):October 1, 1990Publication History Publish…

Catalytic Processes in Materials ScienceFuel Cells and Related Materials

Raman heterodyne detected electron-nuclear-double-resonance measurements of the nitrogen-vacancy center in diamond

Neil B. Manson、Xing-Fei He、Peter Fisk1990-10-01Optics Letters

We report two new applications of the Raman heterodyne detection technique. Raman heterodyne detected electron-nuclear double resonance and a double rf resonance technique are used to obtain the hyperfine structure of the nitrogen-vacancy center in diamond.

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchQuantum optics and atomic interactions

Dense simple plasmas as high-temperature liquid simple metals

F. Perrot1990-10-01Physical Review A

In this paper, we study the thermodynamic properties of dense plasmas considered as high-temperature liquid metals. The problems that have to be solved are the following: (1) calculation of the ``average'' electron-density profile around an ion in the plasma, (2) determination of a self-consistent average ionization o…

High-pressure geophysics and materialsMaterial Dynamics and Propertiesnanoparticles nucleation surface interactions

Characterization of a thermally imidized soluble polyimide film

Philip R. Young、Judith R. Davis、Alice C. Chang 等 4 位作者1990-10-01Journal of Polymer Science Part A Polymer Chemistry

Abstract A soluble aromatic poly (amic acid) film was converted to a soluble polyimide by staging at 25°C intervals to 325°C and characterized at each interval by several analytical methods. The behavior observed was consistent with an interpretation that a reduction occurred in molecular weight of the poly (amic acid…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Viscoeleastic properties of solutions of star-branched polystyrene

Kunihiro Osaki、Eiichi Takatori、Michio Kurata 等 6 位作者1990-10-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTViscoeleastic properties of solutions of star-branched polystyreneKunihiro Osaki, Eiichi Takatori, Michio Kurata, Hiroshi Watanabe, Hirotsugu Yoshida, and Tadao KotakaCite this: Macromolecules 1990, 23, 20, 4392–4396Publication Date (Print):October 1, 1990Publication History…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

MODELING RHEOLOGICAL BEHAVIOR OF GELATINIZING STARCH SOLUTIONS USING MIXER VISCOMETRY DATA

Kirk D. Dolan、James F. Steffe1990-10-01Journal of Texture Studies

A Brookfield RVTD mixer viscometer was used to gelatinize 5.5, 6.4, and 7.3% (d.b.) native corn starch solutions, and a 6% bean starch solution. Torque, the dependent variable, was used to estimate parameters in a generalized viscosity model. The independent variables were impeller speed, temperature (50–95°C), concen…

Thermal and Kinetic AnalysisMaterials Engineering and ProcessingAdsorption, diffusion, and thermodynamic properties of materials