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Surface-enhanced raman scattering and nonlinear optics applied to electrochemistry

Richard K. Chang、B.L. Laube1984-01-01Critical reviews in solid state and materials sciences/CRC critical reviews in solid state and materials sciences

The most recently developed diagnostic technique in metal-electrolyte and metal-gas interfaces adapts spontaneous Raman scattering and nonlinear optical generation, techniques normally applied to bulk media, to surface science investigation. For certain metallic surfaces, an enormous increase exists in the Raman (as m…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy and Quantum Chemical StudiesElectrochemical Analysis and Applications

Sterically protected hemins with electronegative substituents: efficient catalysts for hydroxylation and epoxidation

Patricia S. Traylor、David Dolphin、Teddy G. Traylor1984-01-01Journal of the Chemical Society Chemical Communications

Meso-tetra(2,6-dichlorophenyl)porphinatoiron(III)chloride and meso-tetra(pentachlorophenyl)porphinatioiron(III)chloride, which resist µ-oxo dimmer formation and oxidative destruction, are found to be unusually efficient catalysts for high-turnover, high-yield alkene epoxidation and alkane hydroxylation.

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsPorphyrin Metabolism and Disorders

Photoluminescence of small cadmium sulphide particles

Jeremy J. Ramsden、Michaël Grätzel1984-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

Colloidal particles of CdS are produced by adding H2S to aqueous solutions of Cd(NO3)2(method 1) or rapid mixing of Na2S and Cd(NO3)2 solutions (method 2). Single crystals with cubic structure are obtained, their size being 50 and 20 Å, respectively. Type 1 particles are associated as dimers or trimers while type 2 pa…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCrystal Structures and Properties

Complexes of aluminum(III) with hydroxy carboxylic acids

Ramunas J. Motekaitis、Arthur E. Martell1984-01-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTComplexes of aluminum(III) with hydroxy carboxylic acidsRamunas J. Motekaitis and Arthur E. MartellCite this: Inorg. Chem. 1984, 23, 1, 18–23Publication Date (Print):January 1, 1984Publication History Published online1 May 2002Published inissue 1 January 1984https://pubs.acs…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisInorganic and Organometallic Chemistry

Directionally Solidified Materials for High Temperature Service

G. A. Chadwick1984-01-01British Corrosion Journal

"Directionally Solidified Materials for High Temperature Service." British Corrosion Journal, 19(4), pp. 154–155

Recycling and utilization of industrial and municipal waste in materials productionAerogels and thermal insulationMagnesium Oxide Properties and Applications

Probabilistic Methods in Structural Engineering

G. Augusti、A. Baratta、Fabio Casciati1984-01-01OpenAlex

Introduction. Glossary. Theory of structures and theory of probability. Part 1: Analytical methods. Random quantities and structural reliability. Models of external actions. Elastic structures. Plastic structures. Structural reliability and structural design. Part 2: Operative methods. Data statistics. Statistical ana…

Structural mechanics and materials

Sonoluminescence

Alan J. Walton、Geo. T. Reynolds1984-01-01Advances In Physics

Sonoluminescence (SL) is the name given to the light emitted when a liquid is cavitated in a particular (rather violent) manner. The appropriate cavitation conditions can be realized by using high intensity ultrasound, a spark discharge, a laser pulse, or by flowing the liquid through a Venturi tube. SL occurs in a wi…

Innovative Microfluidic and Catalytic Techniques InnovationAdvanced Chemical Sensor TechnologiesUltrasound and Cavitation Phenomena

Rapidly solidified alloys

Christine Adam、G. E. Fish1984-01-01OpenAlex

Revue portant sur les applications de ces alliages a solidification rapide a partir des feuilles metalliques amorphes pour dispositifs magnetiques jusqu'aux composants consolides par metallurgie des poudres pour applications structurales; on passe aussi en revue les modeles mathematiques appropries au processus de sol…

Solidification and crystal growth phenomena

Heavy metal fluoride glasses and fibers: A review

D. C. Tran、George H. Sigel、Bernard Bendow1984-01-01Journal of Lightwave Technology

A comprehensive summary is provided on the subject of heavy metal fluoride glasses. This includes discussions on glass compositions, preparation, structure, fiber drawing characteristics, and intrinsic and extrinsic optical properties. Other relevant glass and fiber characteristics such as strength, durability, and th…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsSolid State Laser Technologies

Chemical, electronic, and structural properties of conducting heterocyclic polymers: A view by XPS

P. Pfluger、G. B. Street1984-01-01The Journal of Chemical Physics

XPS techniques have been used to characterize electrically conducting films of polypyrrole and polybithiophenes as grown electrochemically. These techniques have yielded information not only on the nature of the polymeric cation and its counter anion but also on the structural disorder in these polymers. In particular…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsElectrochemical Analysis and Applications

The preparation of cross‐section specimens for transmission electron microscopy

J. C. Bravman、Robert Sinclair1984-01-01Journal of Electron Microscopy Technique

Abstract The structure and chemistry of thin solid films are best studied by transmission electron microscopy (TEM) when they are viewed in cross‐section—that is, when the surface normal of the film is made perpendicular to the electron beam. In this orientation, the substrate, the thin film layers, and the interfaces…

Advanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy TechniquesAnodic Oxide Films and Nanostructures

Vibrational studies of the cluster carbonyls of ruthenium and osmium. Part 1. Raman solution data for [Ru3(CO)12], [Os3(CO)12], and [Ru4H4(CO)12] in the CO stretching region

T. R. Gilson1984-01-01Journal of the Chemical Society Dalton Transactions

Hitherto unobtainable Raman solution data for [Ru3(CO)12], [Os3(CO)12], and [Ru4H4(CO)12] in the carbonyl stretching region are presented. The results were obtained by careful choice of solvent and specialist instrumentation. They are shown to confirm previous assignments, by examining the special vibrational properti…

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesNanocluster Synthesis and Applications

A lattice-dynamics model of the interaction of a dislocation with point defects

J. Caro、Nina E. Glass1984-01-01Journal de physique

We consider a lattice dynamics model of a straight screw dislocation moving in a simple cubic lattice with nearest-neighbour « snapping bonds ». The effect on the lattice of the dislocation motion is described by a dynamic source-force, or Kanzaki-force, and the lattice response by the phonon Green's function. A rando…

Microstructure and mechanical propertiesHigh-pressure geophysics and materialsHigh Temperature Alloys and Creep

Molecular weight determination of pyrrole-based polymers

A. I. Nazzal、G. B. Street1984-01-01Journal of the Chemical Society Chemical Communications

The first molecular weight determination for a pyrrole based conducting polymer indicates that poly(β,β′-dimethylpyrrole) consists of chains of up to ca. 1000 pyrrole units.

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Soluble conducting poly(acetylene)block copolymers

M. Aldissi1984-01-01Journal of the Chemical Society Chemical Communications

Soluble conducting poly(acetylene)–poly(isoprene) block copolymers have been synthesized by using the polymeric catalyst formed by the reaction of poly(isoprenyl-lithium) with tetrabutoxytitanium in toluene at room temperature; an instantaneous polymerization of acetylene is observed leading to the formation of a bloc…

Organic Electronics and PhotovoltaicsAdvanced Battery Materials and TechnologiesConducting polymers and applications

Novel heterocyclic systems from selective oxidation at the β-pyrrolic position of porphyrins

Maxwell J. Crossley、Lionel G. King1984-01-01Journal of the Chemical Society Chemical Communications

Novel heterocyclic systems in which a porphyrin pyrrole has been ring-expanded to a morpholine derivative (5), ring-contracted to an azetine derivative (6), and converted into the oxazolone derivatives (4) and (9) result from selective oxidation of 2-amino-5,10,15,20-tetraphenylporphyrin (1).

Porphyrin and Phthalocyanine ChemistrySynthesis and Reactivity of HeterocyclesSynthesis and Reactions of Organic Compounds

The organization of cholesteric spherulites

Yves Bouligand、F. Livolant1984-01-01Journal de physique

Germs of cholesteric liquids were studied in classical mixtures of nematic compounds (MBBA, PAA) with a twisting substance (cholesterol benzoate). These germs were also studied with different polymers of biological interest : synthetic polypeptides (PBLG), nucleic acids (DNA) and polysaccharides (xanthan). Germs are e…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsFood Chemistry and Fat Analysis

The defect structure of nickel oxide surfaces as revealed by photoelectron spectroscopy

M.W. Roberts、Roger St.C. Smart1984-01-01Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases

Nickel oxides characterised by electron microscopy and with different defect concentrations have been studied by X-ray photoelectron spectroscopy. Oxides preannealed in air at 700, 1100 and 1450 °C were examined after heating in vacuo in the spectrometer between 20 and 500 °C. High-binding-energy components of O(1s) s…

Catalytic Processes in Materials ScienceTransition Metal Oxide NanomaterialsElectron and X-Ray Spectroscopy Techniques

Boundary-layer model of pattern formation in solidification

Eshel Ben‐Jacob、Nigel Goldenfeld、J. S. Langer 等 4 位作者1984-01-01Physical Review A

We propose and investigate the properties of a model of pattern formation in crystal growth. The principal dynamical variables in this model are the curvature of the solidification front and the thickness (or heat content) of a thermal boundary layer, both taken to be functions of position along the interface. This mo…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaFluid Dynamics and Thin Films