Materials Literature
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The viscoelastic properties of phase‐separated poly(methyl methacrylate) (PMMA) and poly(styrene–co‐maleic anhydride) (SMA) blend systems have been investigated. It is shown that the samples of initial off‐symmetric and symmetric compositions show different characteristic viscoelastic properties, which are the reflect…
Recent measurements have suggested that the antiplasticizing effect of glycerol on trehalose can significantly increase the preservation times of proteins stored in this type of preservative formulation. In order to better understand the physical origin of this phenomenon, we examine the nature of antiplasticization i…
The ring-opening polymerization (ROP) of the cyclic phosphoester 2-ethoxy-2-oxo-1,3,2-dioxaphospholane (EEP) in tetrahydrofuran solution with co-initiation of stannous octoate and dodecanol yields poly(ethylene ethlyl phosphate) (PEEP) with defined linear molecular structure. NMR analyses reveal every molecule of dode…
The controllable growth of vertically aligned ZnO nanowires using a simple vapour deposition method system is reported. The growth properties are studied as a function of the thickness of the Au catalyst layer, total pressure, deposition temperature and oxygen partial pressure. The experiments indicate the existence o…
Abstract Nano‐SiC dispersed Bi 2 Te 3 was synthesized by mechanical alloying (MA) followed by spark plasma sintering (SPS). The effects of SiC dispersion on the thermoelectric properties of the SPS‐sintered Bi 2 Te 3 alloys were investigated. The results revealed that SiC dispersion in the Bi 2 Te 3 matrix increased t…
We report a facile synthesis of branched gold nanocrystals by the addition of a suitable amount of NaOH to an aqueous solution of cetyltrimethylammonium bromide (CTAB), HAuCl(4), and ascorbic acid. The branched nanocrystals were formed within minutes of reaction and showed monopod, bipod, tripod, and tetrapod structur…
Selecting nanocomposites for photonic switching applications requires optimizing their thermal, nonlinear and two-photon absorption characteristics. We simplify this step by defining a compound figure of merit (FOM_{C}) for nanocomposites of noble metals in dielectric based on criteria that limit these structures in p…
Copper metaborate CuB$_2$O$_{4}$ was studied by muon spin relaxation measurements in order to clarify its static and dynamic magnetic properties. The time spectra of muon spin depolarization suggest that the local fields at the muon site contain both static and fluctuating components in all ordered phases down to 0.3…
We have observed nanopattern formation with robust and controllable spatial ordering by laser-induced dewetting in nanoscopic metal films. Pattern evolution in Co film of thickness 1\leq h\leq8 nm on SiO_{2} was achieved under multiple pulse irradiation using a 9 ns pulse laser. Dewetting leads to the formation of cel…
The evolution of the magnetic moment in iron clusters containing 20 to 400 atoms is investigated using first-principles numerical calculations based on density-functional theory and real-space pseudopotentials. Three families of clusters are studied, characterized by the arrangement of atoms: icosahedral, body-centere…
We show that arrival times for electromagnetic pulses measured through the rate of absorption in an ideal impedance matched detector are equivalent to the arrival times using the average flow of optical energy as proposed by Peatross {\it et al.} [ Phys. Rev. Lett. {\bf 84}, 2370 (2000)]. We then investigate the trans…
Assigning effective atomic charges that properly reproduce the electrostatic fields of molecules is a crucial step in the construction of accurate interatomic potentials. We propose a new approach to calculate these charges, which as previous approaches are, is based on the idea of charge equilibration. However, we on…
We predict a previously unknown phase transformation from wurtzite to a graphitelike (P6(3)/mmc) hexagonal structure in [0110]-oriented ZnO nanowires under uniaxial tensile loading. Molecular dynamics simulations and first principles calculations show that this structure corresponds to a distinct minimum on the enthal…
We apply an analysis of time-dependent spin-polarized current in a semiconductor channel at room temperature to establish how the magnetization configuration and dynamics of three ferromagnetic terminals, two of them biased and third connected to a capacitor, affect the currents and voltages. In a steady state, the vo…
Parallel Molecular Dynamics simulations are conducted for describing growth on surfaces with different kind of roughness: a perfect ordered crystalline flat graphite surface, a disordered rough graphite surface and flat surface with an ordered localized defect. It is shown that disordered rough surfaces results in a f…
A remarkable progress towards functional ferromagnetic semiconductor materials for spintronics has been achieved in p-type (Ga,Mn)As. Robust hole-mediated ferromagnetism has, however, been observed also in other III-V hosts such as antimonides, GaP or (Al,Ga)As which opens a wide area of possibilities for optimizing t…
We report fluorescence blinking statistics measured from single CdSe nanorods (NRs) of seven different sizes with aspect ratio ranging from 3 to 11. This study included core/shell CdSe/ZnSe NRs and core NRs with two different surface ligands producing different degrees of surface passivation. We compare the findings f…
The properties of ferroelectric-ferroelastic twin boundaries in tetragonal $\mathrm{Ba}\mathrm{Ti}{\mathrm{O}}_{3}$-like crystals are analyzed in the framework of the phenomenological Ginzburg-Landau-Devonshire model. Special attention is paid to the introduction and appreciation of the gradient and dipole-dipole term…
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Ni5Zn21 alloy nanowires were fabricated through template-assisted electrochemical deposition method. The morphology and microstructures of as-deposited nanowires were determined by field-emission scanning electron microscope (FE-SEM), X-ray diffraction (XRD), high-resolution transmission electron microscope (HRTEM), e…