Materials Literature
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In order to describe and quantify the reactivity of silicate melts, the ionic notation provided by the Temkin formalism has been historically accepted, giving rise to the study of melt chemical equilibria in terms of completely dissociated ionic species. Indeed, ionic modelling of melts works properly as long as the t…
The microstructural parameters like the average domain size, effective domain size at a particular crystallographic direction and microstrain within the domains of titanium and Ti-5%Ta-2%Nb, irradiated with 116 MeV O5+ ion, have been characterized as a function of dose by X-Ray Diffraction Line Profile Analysis using…
PbZn2(BO3)2 crystallizes in the space group Pccn, with the Pb cation at a site with imposed twofold symmetry. The compound represents a new structure type in which ZnBO3 layers are bridged by Pb2+ cations, giving rise to a three-dimensional framework. Channels parallel to the [010] direction accommodate the stereochem…
Reaction of the n = 2 Ruddlesden−Popper phase YSr 2 Mn 2 O 7 with NaH at 225 °C yields the topotactically reduced phase YSr 2 Mn 2 O 5.43(3) ( a = 3.62043(4) Å, c = 22.3570(3) Å). Combination of this reduced phase with the stoichiometric starting material at 400 °C yields intermediate phases: YSr 2 Mn 2 O 6.54(3) ( a…
Heterogeneous strong base catalysis for the intramolecular Tishchenko reaction of aromatic 1,2-dicarbaldehydes to the corresponding phthalides in supercritical CO2CscCO2 has been realized with mesoporous alumina containing SO4(2-) ions in the alumina framework (mesoAl2O3/SO4(2-)). Infrared spectroscopy of pyrrole adso…
A convenient synthesis of (t)Bu(3)SiSH and (t)Bu(3)SiSNa(THF)(x)() led to the exploration of "(t)Bu(3)SiSMX" aggregation. The dimer, [((t)Bu(3)SiS)Fe](2)(mu-SSi(t)Bu(3))(2) (1(2)), was formed from [{(Me(3)Si)(2)N}Fe](2)(mu-N(SiMe(3))(2))(2) and the thiol, and its dissolution in THF generated ((t)Bu(3)SiS)(2)Fe(THF)(2)…
The water-soluble, non-mu-oxo dimer-forming porphyrin, [5,10,15,20-tetrakis-4'-t-butylphenyl-2',6'-bis-(N-methylene-(4''-t-butylpyridinium))porphyrinato]iron(III) octabromide, (P(8+))Fe(III), with eight positively charged substituents in the ortho positions of the phenyl rings, was characterized by UV-vis and 1H NMR s…
Two new cyano-bridged one-dimensional heterobimetallic coordination polymers, [(bpca)(2)Fe(III)(2)(CN)(6)Cu(H(2)O)(2).1.5H(2)O](n)() (2) and [(bpca)Fe(III)(CN)(3)Cu(bpca)(H(2)O).H(2)O](n)() (3), and a trinuclear complex, [(bpca)(2)Fe(III)(2)(CN)(6)Mn(CH(3)OH)(2)(H(2)O)(2)].2H(2)O (4), have been synthesized using the t…
We report magnetic and magnetic circular dichroism investigations of a binuclear Co(II) compound. The Hamiltonian of the system involves an isotropic exchange interaction dealing with the real spins of cobalt(II) ions, spin-orbit coupling, and a low-symmetry crystal field acting within the (4)T(1g) ground manifold of…
Nanowires of platinum and gold with high aspect ratios are synthesized in one-dimensional channels of ordered mesoporous organosilica HMM. Water-saturated hydrogen reduction (wet H 2 -reduction) is significantly effective for large-scale synthesis of long nanowires, while dry H 2 -reduction gives monodispersed metal n…
We report crystal structures of the citrate and sn-glycerol-1-phosphate (G1P) complexes of (S)-3-O-geranylgeranylglyceryl phosphate synthase from Archaeoglobus fulgidus (AfGGGPS) at 1.55 and 2.0 A resolution, respectively. AfGGGPS is an enzyme that performs the committed step in archaeal lipid biosynthesis, and it pre…
Steady-state and time-resolved fluorescence techniques are combined with theoretical molecular dynamics calculations and applied to study the secondary structure of some random copolymers of polyphophazenes containing phenoxy and binaphthoxy chromophoric groups. Analysis of excitation and emission spectra, fluorescenc…
[reaction: see text] Electrophilic nitration, formylation or bromination of metalated 5-fluoroalkyl-10,20-diphenylporphyrin (fluoroalkyl = CF3, ClCF2CF2, n-C6F13) proceeded with high regioselectivity, exclusively affording corresponding meso-substituted porphyrins, while the iodination reaction mainly took place at th…
Resonant Raman scattering (RRS) spectra of individual carbon nanotubes on a SiO2 substrate have been investigated first in the temperature range of 100-600 K (Phys. Rev. B 2002, 66, 115411). It was revealed by the intensity abnormality of the radial breathing mode (RBM) that the carbon nanotubes have a temperature-dep…
Calcination at 900-1000 degrees C for 8-12 h of an Fe/MgO catalyst prepared by impregnation was found to result in a uniform MgFe2O4/MgO solid solution that showed a successful settling of well-dispersed iron species into the MgO lattice. During methane reduction, many iron-containing particles with a diameter of abou…
We report the design, synthesis, and characterization of a series of mesogen-jacketed liquid crystalline polymers with bent-core liquid crystals (BCLCs). For the first time, BCLC mesogens were directly side-attached to the polymer backbone and bent-core mesogen-jacketed liquid crystalline polymers (BMJLCPs) were achie…
We present a detailed study on the integration of individual single-walled carbon nanotubes (SWNTs) within a lyotropic hexagonal liquid crystal (LC) for the first time. Two systems are studied in this work; in the first, the same surfactant is used for both the dispersion of the SWNTs and the formation of the LC. In t…
Azobenzene was additionally introduced into side chain of T7 promoter for the photocontrol of transcription reaction by T7 RNA polymerase (T7 RNAP). When a single azobenzene molecule was introduced into the T7 promoter either at the loop-binding region of the RNAP (-7 to -11 position) or at the unwinding region (-1 to…
Experimental IR spectra of carbon monoxide adsorbed on a series of Mo/Al2O3, CoMo/Al2O3, and NiMo/Al2O3 sulfided catalysts have been compared to ab initio DFT calculations of CO adsorption on CoMo and NiMo model surfaces. This approach allows the main IR features of CO adsorbed on the sulfide phase to be assigned with…
We discuss the difference between cohesive and non-cohesive granular media in the context of a recent report of "dry quicksand." Weak low density states with properties like dry quicksand are readily formed in common household powders. In contrast, such states cannot be formed in cohesionless granular media such as or…