Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Abstract Starch acetate–corn fiber foams were prepared by extrusion. Corn starch was acetylated (DS 2) to introduce thermoplastic properties. Corn stalks were treated with sodium hydroxide to remove the lignin and to obtain purified cellulose fibers. Starch acetate was blended with treated fiber at concentrations of 0…
Spiropyran is a photoresponsive molecule, and nonionic spiropyran is reversibly changed by UV irradiation to a hydrophilic polar, zwitterionic merocyanine isomer, and back again by visible light irradiation. A copolymer of nitrobenzospiropyran and methyl methacrylate, poly(NSP-co-MMA) was used as a material with a pho…
A central role for the alkali metal cation was determined in the thermally activated electron transfer CoIII(LS)-FeII(LS) ⇌CoII(HS)-FeIII(LS) in a CsCoFe Prussian blue derivative by localizing the alkali metal ion and identifying its interactions with the surrounding network in the high- and low-temperature states (se…
A viologen, N-hexyl-N'-(4-vinylbenzyl)-4,4'-bipyridinium dinitrate (HVVN), was synthesized and subsequently graft-copolymerized on poly(ethylene terephthalate) (PET) films. Silver nanoparticles can be deposited on the surface of the HVVN-PET film through photoinduced reduction of the silver ions in salt solution. The…
Abstract The organic–inorganic hybrid composites comprising acrylic rubber and silica were synthesized through sol–gel technique at ambient temperature. The composites were generated through the acid‐catalyzed hydrolysis and subsequent condensations of inorganic tetraethoxysilane (TEOS) in the organic acrylic rubber (…
The aim of the present solid-state NMR study was to characterize the surface species of γ-aminopropyltriethoxysilane (APTS), γ-aminopropyltrimethoxysilane (APTMS), and γ-aminopropyldiethoxymethylsilane (APDMS) on porous silica when the deposition was performed via the gas phase. The reaction temperature used, that is,…
Lining them up: Purely organic paramagnetic liquid crystals (see picture) showing thermally stable nematic or cholesteric phases were successfully prepared. The molecular orientation of the bulk liquid crystals induced by weak magnetic fields was confirmed by magnetic susceptibility measurements and EPR spectroscopy.
Abstract The photo‐oxidative degradation of polyethylene/montmorillonite (PE/MMT) nanocomposite and microcomposite has been investigated. It has been found that the rate of photo‐oxidative degradation of PE/MMT nanocomposite and PE/M n+ MMT (where M n+ stands for multivalent transition metal cation) microcomposites is…
We use inelastic neutron scattering and molecular dynamics simulation to investigate the interplay between the structure and the fast sodium ion diffusion in various sodium silicates. With increasing temperature and decreasing density the structure factors exhibit an emerging prepeak around 0.9 A(-1). We show that thi…
The only kinetically relevant step for catalytic CH4 activation on Ir clusters is—according to a detailed analysis—CH bond activation (see picture). This step is favored on surfaces of small Ir clusters supported on oxides, as also found on other noble metal catalysts. Other elementary steps remove chemisorbed carbon…
We proposed an approach to precisely control the density of tethered chains on solid substrates using PEO-b-PS and PLLA-b-PS. As the crystallization temperature ${T}_{x}$ increased, the PEO or PLLA lamellar crystal thickness ${d}_{L}$ increased as well as the reduced tethering density $\stackrel{\texttildelow{}}{\ensu…
Ultra-low friction between shells of multiwalled carbon nanotubes indicates that, when the nanotubes are used as reinforcement agents, the mechanical load is carried by the outermost shell of the tube only. We suggest using small-dose electron or ion irradiation to partially transfer the load to the nanotube inner she…
Proposed silicon-based quantum-computer architectures have attracted attention because of their promise for scalability and their potential for synergetically utilizing the available resources associated with the existing Si technology infrastructure. Electronic and nuclear spins of shallow donors (e.g. phosphorus) in…
A series of first principles calculations have been carried out in order to discuss electronic structure, phonon dynamics, structural instabilities and the nature of martensitic transformations of the Heusler alloys Ni$_2$Mn(Ga, Ge, Al) and Co$_2$Mn(Ga, Ge). The calculations show that besides electronic pecularities l…
Ta films with tetragonal crystalline structure (beta-phase), deposited by magnetron sputtering on different substrates (steel, silicon and silicon dioxide), have been studied. In all cases, very highly preferred (001) orientation was observed in x-ray diffraction (XRD) measurements. All diffraction data revealed two w…
Replacing U for Ca in semiconducting CaB$_6$ at the few at.% level induces metallic behaviour and Kondo-type phenomena at low temperatures, a rather unusual feature for U impurities in metallic hosts. For Ca$_{0.992}$U$_{0.008}$B$_6$, the resistance minimum occurs at $T$ = 17 K. The subsequent characteristic logarithm…
We have studied structural and superconducting properties of MgB2 thin films doped with carbon during the hybrid physical-chemical vapor deposition process. A carbon-containing metalorganic precursor bis(cyclopentadienyl)magnesium was added to the carrier gas to achieve carbon doping. As the amount of carbon in the fi…
We investigate the localization property of an electron in the disordered two-chain system (ladder model) with long-range correlation as a simple model for electronic property in DNA sequence. The chains are constructed by repetition of the sugar-phosphate sites, and the inter-chain hopping at the sugar sites come fro…
A simple model of inelastic hard-rods subject to a one-dimensional array of identical wells is introduced. The energy loss due to inelastic collisions is balanced by the work supplied by an external stochastic heat-bath. We explore the effect of the spatial non uniformity on the steady states of the system. The spatia…
Magnetic properties of a mixed spin-$\frac{1}{2}$ and spin-1 Ising model on honeycomb lattice are exactly investigated within the framework of generalized star-triangle mapping transformation. The particular attention is focused on the effect of uniaxial and biaxial crystal-field anisotropies that basically influence…