Materials Literature
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This letter reports the formation of a reacted layer between Cu film and barrierless Si substrate during annealing. The Cu films with a minor WN phase are deposited by reactive cosputtering of Cu and W in an Ar∕N2 mixture gas. After annealing at 530 °C for 1 h, a ∼200-nm-thick reacted layer formed at the Cu(WN)∕Si int…
Powder x-ray diffraction patterns of magnetite (Fe 3 O 4 ) have been recorded at 90 K, below the Verwey transition, at three wavelengths in the pre- to mid-edge region of the 7.1 keV Fe K absorption. Simultaneous fitting of these profiles has been used to refine the anomalous scattering coefficients for the octahedral…
Porous anodic alumina membranes (PAAMs) have uniform and high-density nanopores, and the dimension and interval of the pores can be easily controlled by varying the anodization conditions. The application of PAAMs could widely impact the cost and efficiency of the liquid-based nanoscale separations. We report here the…
Ba(dmae)2 (dmaeH=N,N-dimethylaminoethanol, C4H11NO) reacts with Co(acac)2 (acac=2,4-pentanedionate) to produce the trinuclear coordination complex [Ba2Co(acac)4(dmae)3(dmaeH)] in an 85% yield. Spectroscopic and single-crystal X-ray diffraction experiments indicate that the complex possesses a structure in which two ba…
Abstract The treatment of nanoscopic silica grafted in the blend during the processing of silica‐filled styrene butadiene rubber was performed with silane, introduced at different concentrations, or at a constant concentration with a given length of alkyl chain. From swelling measurements in water and in solvent, the…
[chemical structure: see text]. A series of L-amino acid functionalized gold nanoparticles with oligo(ethylene glycol) (OEG) tethers of varying length are prepared. These studies show that the hydrophobic side chains of amino acids facilitate the structural retention of alpha-chymotrypsin (ChT) but the interior alkyl…
In the perfect magnesium aluminate spinel structure all the tetrahedral sites are occupied by Mg 2+ ions, while Al 3+ ions occupy all the octahedral sites. Real MgAl 2 O 4 , however, exhibits cation disorder (inversion), so that some Mg 2+ ions reside in octahedral sites with an equal number of Al 3+ ions in tetrahedr…
Abstract Polyurethane prepolymers are widely used in the reactive hot melt adhesives and moisture‐cured coatings. The chemically crosslinked moisture‐cured formulation based on PEG‐1000 and isophorone diisocyanate was prepared with NCO/OH ratio of 1.6:1.0. Trimethylol propane was used as a crosslinking agent. The exce…
Theoretical studies using density functional theory are carried out to understand the electronic structure and bonding and electronic properties of elemental $\ensuremath{\beta}$-rhombohedral boron. The calculated band structure of ideal $\ensuremath{\beta}$-rhombohedral boron $({\mathrm{B}}_{105})$ shows valence elec…
Unique inorganic-organic hybrid mesoporous materials incorporating arenetricarbonyl complexes [-C6H4M(CO)3-] (M = Cr, Mo) within their mesoporous frameworks have been successfully prepared by a simple CVD treatment of the phenylene-bridged organosilica mesoporous materials with metal hexacarbonyls [M(CO)6] (M = Cr, Mo…
Nanocomposites based on vinyl alcohol-containing polymers and nanostructured gold have been efficiently prepared by a UV photo-reduction process. The very fast process provided dispersed gold nanoparticles with average diameters ranging from 3 to 20 nm depending on the host polymer matrix and the irradiation time. Uni…
Much of the material in the introduction of this article was taken from the work of N A Hill without due acknowledgement. In particular, the last 12 lines of the second paragraph and all of the third and fourth paragraphs are taken verbatim from reference [41] (numbering as in the paper). The authors apologise to N A…
Polyelectrolyte multilayers are now a well established concept with numerous potential applications in particular as biomaterial coatings. To timely control the biological activity of cells in contact with a substrate, multicompartment films made of different polyelectrolyte multilayers deposited sequentially on the s…
This study aimed at demonstrating complementary roles offered by both Fourier transform infrared (FTIR) spectrophotometry and x-ray powder diffraction (XRPD) techniques in characterizing clay size fraction of kaolins. The clay size fraction of kaolin samples obtained from Kgwakgwe, Makoro, Lobatse and Serule kaolin oc…
The impact of particle geometry on the phase behavior of hard colloidal tetragonal parallelepipeds (TPs) was studied by using Monte Carlo simulations in continuum space. TPs or "cuboids" of aspect ratios varying from 0.25 to 8 were simulated by approximating their shapes with multisite objects, i.e., via rigid cluster…
Reaction of in situ generated copper-monosubstituted Keggin polyoxometalate (POM) and copper-phenanthroline complexes in potassium or sodium acetate buffers led to the formation of the potassium salt of [[SiW(11)O(39)Cu(H(2)O)][Cu(2)(phen)(2)(H(2)O)(ac)(2)]](4-) (1) and [[Si(2)W(22)Cu(2)O(78)(H(2)O)][u(2)(phen)(2)(H(2…
While the energy levels in Ho:YLF have been measured previously, they have not been as thoroughly investigated in the isomorphs, Ho:LuLF and Ho:GdLF. We report here the measurement of the energy levels of the trivalent lanthanide Ho 3+ in GdLiF 4 (GdLF), YLiF 4 (YLF), and LuLiF 4 (LuLF). The measurement of the energy…
The intrinsic p-type ZnO thin films were prepared by controlling the oxygen partial pressure during growth. The E2 (high) mode at 432.2cm−1 appeared in the Raman spectrum of the film. The photoluminescence spectra taken at 77 K showed the emission band C in the violet region, which originated from zinc vacancy and var…
The electronic structure of CdSe semiconductor nanocrystals has been used to sensitize Tb3+ in solution by incorporation of Tb3+ cations into the nanocrystals during synthesis. Doping of luminescent Tb3+ metal ions in semiconductor nanocrystals utilizes the positive attributes of both species' photophysical properties…
A novel organic−inorganic hybrid solid, ( n -Bu 4 N) 2 [Mo 6 O 17 (NAr) 2 ] (Ar = o -CH 3 OC 6 H 4 ) 1, has been prepared by refluxing of ( n -Bu 4 N) 2 [Mo 6 O 19 ] and appropriate o -anisidine in acetonitrile with N - N ‘ -dicyclohexylcarbodiimide (DCC) as the dehydrating agent. Compound 1 has been characterized by…