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Surface characterization of alumina-supported catalysts prepared by sol–gel method. Part II. Surface reactivity with CO

Masaaki Haneda、c Emmanuel Joubert、Jean-Christophe Me ́ne ́zo 等 10 位作者2001-01-01Physical Chemistry Chemical Physics

Surface reactivity toward H2 and CO using a pulse method was investigated for Al2O3, In2O3–Al2O3 and Ga2O3–Al2O3. It was found that reduction by either CO or H2 and reoxidation by O2 occurred reversibly on In2O3–Al2O3. Although the surface of Ga2O3–Al2O3 was hardly reduced by H2, CO consumption and CO2 formation was o…

Catalytic Processes in Materials ScienceInorganic and Organometallic ChemistryCatalysis and Oxidation Reactions

Autodeformation bending of gypsum crystals grown under the conditions of counterdiffusion

Yu. O. Punin、O. I. Artamonova2001-01-01Crystallography Reports

The dynamics and kinetics of growth-induced bending of gypsum crystals grown from solution have been studied. Crystallization was performed by the method of chemical reaction under the conditions of component counterdiffusion. It is established that autodeformation bending occurs in the [001] direction at the growth f…

Material Properties and ApplicationsMaterial Properties and Failure Mechanisms

The solidification characteristics of near rapid and supercooling directional solidification

Hengzhi Fu、Faqin Xie2001-01-01Science and Technology of Advanced Materials

In the comparison of the solidification characteristics of supercooling directional solidification (SDS) with constrained directional solidification (DS) and with the consideration of the inheritance of supercooled melt, the SDS technique established with the combination of melt supercooling and traditional DS was pro…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenaMetallurgy and Material Science

Scouring and Dyeing of Polyester Fibers in Supercritical Carbon Dioxide.

Chien‐Tsung Wang、Wen-Fa Lin2001-01-01JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

This study presents a viable method for the scouring and dyeing of polyester fibers (polyethylene terephthalate, PET) by using supercritical carbon dioxide as a mdeium. Scouring of the PET fibers was carried out at pressures ranging from 96 to 350 bar and at temperatures ranging from 313 to 393 K. The overall oil remo…

Polymer crystallization and propertiesPolymer Foaming and Composites

Origin of voltage offset and built-in polarization in in-situ sputter deposited pzt thin films

Stéphane Hiboux、Paul Muralt2001-01-01Integrated ferroelectrics

Voltage offset and built-in polarization were investigated in in-situ reactively sputter deposited PZT thin films on Pt, as a function of composition, doping and cooling conditions. The voltage offset increases with increasing Ti content. Hot-poling treatments show that the voltage offset originates from non-mobile de…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Syntheses and electro(co)polymerization of novel thiophene- and 2,2′:5′,2″-terthiophene-functionalized metal–tetraazamacrocycle complexes, and electrochemical and spectroelectrochemical characterization of the resulting polythiophenes

Simon J. Higgins、Thomas J. Pounds、Paul A. Christensen2001-01-01Journal of Materials Chemistry

We have prepared novel tetraazacyclotetradecane derivatives, functionalised at nitrogen with a pendant thiophene or oligothiophene group, for electropolymerisation. Square planar Ni(II) complexes of these ligands, [Ni(L)](ClO4)2, have been prepared, and their electropolymerisation has been examined. The terthiophene-b…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsElectrochemical Analysis and Applications

Size effect study by bulk crystals: Optical and DC dielectric response of oxygen vacant BaTiO3

Yutaka Watanabe、Motochika Okano、G. A. Thomas 等 4 位作者2001-01-01Ferroelectrics

We have studied the wide-range dielectric spectra of BaTiO3_δ single crystals and traced the evolution of the electronic structure of BaTiO3 with a very low oxygen vacancy concentration δ An extremely small δ can destroy the band edge and the Urbachian temperature dependence, and a so-called mid-infrared (ir) absorpti…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisElectronic and Structural Properties of Oxides

Physics of Direct Hit and Near Miss Warhead Technology

Richard Lloyd2001-01-01OpenAlex

This title discusses direct hit technology in conjunction with a class of warheads coined near miss or direct hit warhead technology. These warheads utilize most of their entire volume and mass as damage mechanisms generating 10 to 30 times more mass deployed in the target's direction when compared to today's warheads…

Laser-Plasma Interactions and DiagnosticsEnergetic Materials and CombustionHigh-Velocity Impact and Material Behavior

Temperature Dependent Dielectric Relaxation Study of Aniline in Dimethylsulphoxide and Dimethylformamide Using Time Domain Technique

Ajay Chaudhari、Chiranjivi Patil、A. G. Shankarwar 等 5 位作者2001-01-01Journal of the Korean Chemical Society

Department of Electronics and computer science, Dr.B.A.M. University, Aurangabad-431004(M.S.), India(Received February 20, 2001) . aniline-dimethylsulphoxide(DMSO) aniline-dimethylformamide(DMF) dielectric rel-axation 10 MHz-10 GHZ        TimeDomain Reflectometry(TDR) ! !# . dielectric parameter ( %&'…

Nonlinear Optical Materials ResearchSolid-state spectroscopy and crystallographySynthesis and properties of polymers

Non-Equilibration of Nanostructured Mg<SUB>2</SUB>Ni by Bulk Mechanical Alloying

Tatsuhiko Aizawa、Toshiro Kuji、Hiroyuki Nakano2001-01-01MATERIALS TRANSACTIONS

Bulk mechanical alloying was successfully applied to solid-state synthesis of Mg2Ni, which is a promising hydrogen storage alloy. Through XRD, TEM and PCT measurement, the synthesized product was characterized to be a single-phase Mg2Ni, excluding co-synthesized MgNi2 or residuals of nickel or magnesium as in conventi…

Magnesium Alloys: Properties and ApplicationsHydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen Reduction

Perspectives for Biotechnological Production and Utilization of Biopolymers: Metabolic Engineering of Polyhydroxyalkanoate Biosynthesis Pathways as a Successful Example

Alexander Steinbüchel2001-01-01Macromolecular Bioscience

This article provides an overview of biopolymers, classed according to their chemical structures, function and occurrence, the principles of biosynthesis and metabolism in organisms. It will then focus on polyhydroxyalkanoates (PHA) for which technical applications in several areas are currently considered. PHAs repre…

biodegradable polymer synthesis and propertiesBiopolymer Synthesis and Applications

Chlorohydrin water-swellable rubber compatibilized by an amphiphilic graft copolymer. III. Effects of PEG and PSA on water-swelling behavior

Zhihao Zhang、Guo Zhang、Caiqi Wang 等 6 位作者2001-01-01Journal of Applied Polymer Science

Chlorohydrin water-swellable rubber—composed of chlorohydrin rubber (CHR), crosslinked polyacrylate (CPA), the amphiphilic compatibilizer poly(vinyl alcohol)-g-poly(butyl acrylate) (PVA-g-PBA), precipitated silica (PSA), and poly(ethylene glycol) (PEG)—was prepared. The dispersion of PEG in the blend was characterized…

Surface Modification and SuperhydrophobicityHydrogels: synthesis, properties, applicationsPolymer Nanocomposites and Properties

Mesoscale Modelling

David Nicolaides2001-01-01Molecular Simulation

Increasingly, industrial materials are being designed to have structure on length scales of tens to thousands of nanometers. These structures are crucial to achieving a particular desired material property. Such structures, however, may depend on the underlying chemistry of the material for their existence. For exampl…

Surfactants and Colloidal SystemsRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Utilisation of press mud as soil amendment and organic manure – A review

A. Solaimalai、M. Baskar、P. Ramesh 等 4 位作者2001-01-01Agricultural Reviews

Pressmud is an unavoidable waste generated from sugar industries. Pressmud is rich in many plant nutrients and it also has properties to ameliorate degraded soils. For this reason pressmud is believed to be of much use in agriculture. Many research works indicate that application of pressmud improves soil fertility, n…

Clay minerals and soil interactionsSugarcane Cultivation and Processing

High figure of merit ZT in PbTe and Bi/sub 2/Te/sub 3/ based superlattice structures by thermal conductivity reduction

A. Lambrecht、H. Beyer、J. Nurnus 等 5 位作者2001-01-01OpenAlex

In superlattice (SL) structures an enhancement of the thermoelectric figure of merit ZT compared to homogeneous materials can be achieved by reduction of the thermal conductivity /spl lambda/. In this context thermoelectric properties of PbTe/ PbSe/sub x/Te/sub 1-x/-SL's, and PbTe(BaF/sub 2/) doping superlattices (SL)…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsPhase-change materials and chalcogenides

Growth and Oxidation of Thin Film Al[sub 2]Cu

Kirak Son、Nancy A. Missert、J. C. Barbour 等 6 位作者2001-01-01Journal of The Electrochemical Society

Al 2 Cu thin films (∼382 nm) are fabricated by melting and resolidifying Al/Cu bilayers on a SiO 2 on Si(100) substrate in the presence of a ∼3 nm Al 2 O 3 passivating layer. X-ray photoelectron spectroscopy (XPS) measures a 1.0 eV shift of the Cu 2 p 3 / 2 peak and a 1.6 eV shift of the valance band relative to metal…

Corrosion Behavior and InhibitionCopper Interconnects and ReliabilityAnodic Oxide Films and Nanostructures

Synthesis, characterisation and structure–property analysis of derivatives of the non-linear optical material 5-nitro-N-(1-phenylethyl)pyridin-2-amine

P.J. Langley、Ray T. Bailey、Frank R. Cruickshank 等 9 位作者2001-01-01Journal of Materials Chemistry

The effects of a series of small structural changes to (S)-5-nitro-N-(1-phenylethyl)pyridin-2-amine on its solid state non-linear optical properties, including the phenomenon of rotating dielectric axes, have been investigated. Installation of a methyl group in the 3-position of the heterocyclic ring or at the amino n…

Crystallography and molecular interactionsNonlinear Optical Materials ResearchStructural and Chemical Analysis of Organic and Inorganic Compounds

IR and XPS Studies on the Surface Structure of Poled ZnO–TeO 2 Glasses with Second‐Order Nonlinearity

Aiko Narazaki、Katsuhisa Tanaka、Kazuyuki Hirao 等 6 位作者2001-01-01Journal of the American Ceramic Society

The effect of thermal/electrical poling on the surface structure of 30ZnO·70TeO 2 glass has been investigated by means of IR reflectance and X‐ray photoelectron spectroscopy (XPS). All the poled glasses exhibit a common characteristic that the second‐order nonlinearity is induced preferentially in an anode‐side surfac…

Glass properties and applicationsCrystal Structures and PropertiesPhase-change materials and chalcogenides

Crystal and molecular structures of norbornene

Michela Brunelli、Andrew N. Fitch、A. Jouanneaux 等 4 位作者2001-01-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract The ordered, low-temperature phase of the globular organic molecule norbornene, (bicyclo[2.2.1]hept-2-ene, C 7 H 10 ), has been determined by high resolution powder X-ray diffraction using synchrotron radiation, by auto-indexing, then by intensity extraction and direct methods using the EXPO package. The stru…

Crystallography and molecular interactionsThermal and Kinetic AnalysisX-ray Diffraction in Crystallography

The Structure of an Al-Co-Ni Crystalline Approximant with an Ordered Arrangement of Atomic Clusters with Pentagonal Symmetry

Kenji Hiraga、Tetsu Ohsuna、Kunio Yubuta 等 4 位作者2001-01-01MATERIALS TRANSACTIONS

The structure of a crystalline approximant (called “PD3c phase”) in an Al71.5Co16Ni12.5 alloy annealed at 900°C for 120 h has been studied by high-angle annular detector scanning transmission electron microscopy (HAADF-STEM) and high-resolution transmission electron microscopy (HREM). The PD3c phase has an orthorhombi…

Quasicrystal Structures and PropertiesX-ray Diffraction in Crystallography