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Effective Corrosion Protection with the Organic Metal Polyaniline: Basic Principles and Recent Progress

Bernhard Weßling2003-02-28ACS symposium series

After an introduction into the basic principles of corrosionprotection with the Organic Metal Polyaniline, the method of assessing corrosion protection efficiency quantitatively will be described. It will be shown that polyaniline coatings are powerful anti-corrosion coatings, out-performing conventional coatings. The…

Corrosion Behavior and InhibitionConducting polymers and applicationsAnalytical Chemistry and Sensors

Polyester polyols: Synthesis and characterization of diethylene glycol terephthalate oligomers

Oleg N. Kadkin、Karol Osajda、Piotr Kaszyński 等 4 位作者2003-02-28Journal of Polymer Science Part A Polymer Chemistry

Abstract The composition of polyester polyols derived from terephthalic acid (TPA) and diethylene glycol (DEG) was examined. The synthesis of individual oligomers 1 , n is described. The compounds were characterized with 1 H and 13 C NMR, mass spectrometry, and elemental analyses. The resonance signals arising from ar…

Conducting polymers and applicationsbiodegradable polymer synthesis and propertiesSynthesis and properties of polymers

The physics of surfactant dissolution

P.B. Warren、Peter Prinsen、M. A. J. Michels2003-02-28Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences

We have examined the early stages of surfactant dissolution and mesophase formation using a dimer-solvent model with phase behaviour representative of surfactant-water systems. We use an orientational order parameter to characterize systematically the appearance of mesophases. We find the process is diffusion controll…

Surfactants and Colloidal SystemsRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Strongly frustrated magnetism and colossal magnetoresistance in polycrystallineLa0.47Ce0.20Ca0.33MnO3

G. Alejandro、Diego G. Lamas、Laura Steren 等 8 位作者2003-02-28Physical review. B, Condensed matter

We present x-ray diffraction, x-ray photoemission spectroscopy, magnetization, and transport results on the cerium-doped manganite ${\mathrm{La}}_{0.47}{\mathrm{Ce}}_{0.20}{\mathrm{Ca}}_{0.33}{\mathrm{MnO}}_{3}.$ We have achieved good quality, single-phase polycrystalline samples by the nitrate decomposition route. A…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Mechanism of Thermally Induced Morphological Reorganization and Lamellar Orientation from the Herringbone Structure in Cross-Linked Polystyrene-block-polybutadiene-block-polystyrene Triblock Copolymers

Shinichi Sakurai、Sakae Aida、Shigeru Okamoto 等 5 位作者2003-02-28Macromolecules

Structural transformation from the herringbone structure to the preferentially oriented lamellae under the elongational flow has been studied by the two-dimensional small-angle X-ray scattering (2d-SAXS) technique. For this purpose, thermoplastic elastomer SBS (polystyrene- block -polybutadiene- block -polystyrene) tr…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Analysis of residual stresses in main crankshaft bearings after induction surface hardening and finish grinding

Janez Grum2003-02-28Proceedings of the Institution of Mechanical Engineers Part D Journal of Automobile Engineering

The exact pattern of residual stresses will depend on the heat treatment temperatures employed, the depth of hardening and the type of quenchant. Process conditions that give rise to compressive residual stresses on the surface of heat-treated components are favourable. This type of residual stress delays the initiati…

Metal and Thin Film MechanicsMetal Alloys Wear and PropertiesSurface Treatment and Coatings

Monte Carlo simulation on the glass transition of free-standing atactic polypropylene thin films on a high coordination lattice

Guoqiang Xu、Wayne L. Mattice2003-02-28The Journal of Chemical Physics

A recently developed high coordination lattice based Monte Carlo method is applied to investigate the glass transition of free-standing atactic polypropylene thin films. In this method the short-range interactions are described by a rotational isomeric state model and the long-range interactions are obtained from a di…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

A Review of Optical Disk Systems with Blue-Violet Laser Pickups

Takeshi Maeda、Motoyasu Terao、Takeshi Shimano2003-02-28Japanese Journal of Applied Physics

We have applied the blue-violet laser in developing several technologies for the next-generation digital versatile disk (DVD). We are convinced that four items, i.e., large capacity, high data-transfer-rate, cyclability, and portability, are equally important. We have set targets for capacity and data-transfer-rate. S…

Phase-change materials and chalcogenidesSemiconductor Lasers and Optical DevicesNear-Field Optical Microscopy

Nonlinear wave interactions in bubble layers

С. В. Карпов、Andréa Prosperetti、Lev A. Ostrovsky2003-02-28The Journal of the Acoustical Society of America

Due to the large compressibility of gas bubbles, layers of a bubbly liquid surrounded by pure liquid exhibit many resonances that can give rise to a strongly nonlinear behavior even for relatively low-level excitation. In an earlier paper [Druzhinin et al., J. Acoust. Soc. Am. 100, 3570 (1996)] it was pointed out that…

Methane Hydrates and Related PhenomenaUnderwater Acoustics ResearchUltrasound and Cavitation Phenomena

Smart Polymer Surfaces

Spiros H. Anastasiadis、Haris Retsos、Stergios Pispas 等 5 位作者2003-02-28Macromolecules

A methodology is demonstrated for creating responsive polymer surfaces that can alter their wetting characteristics when exposed to a humid environment. For this, we take advantage of the surface partitioning of block copolymers at the polymer/air interface and utilize a hydrophilic group at the end of the surface-act…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsPolymer Surface Interaction Studies

The influence of particle composition in a three-layer particleboard on its physical and mechanical properties

J. Hrázský、Pavel Král2003-02-28Journal of Forest Science

The paper deals with results of research aimed at the problem of the maximum possible amount of added sawdust to standard particles into surface and central layers of three-layer particleboards in order that the physical and mechanical properties of particleboards will comply with the CSN 49 2614 Standard. Waste from…

Natural Fiber Reinforced CompositesForest Biomass Utilization and Management

Solvent-Free Polyaniline Coating for Corrosion Prevention of Metal

Xianhong Wang、Jinlong Lu、Ji Li 等 5 位作者2003-02-28ACS symposium series

Solvent free emeraldine base/epoxy resin coating was prepared employing liquid aliphatic polyamine as the "solvent" for emeraldine base(EB) as well as the "hardener" for epoxy resin(EPR). EB/EPR Coatings with EB loading of 1-2wt% showed good corrosion prevention on mild steel either in 0.1 M HCl solution or in 3.5wt%…

Corrosion Behavior and InhibitionConducting polymers and applicationsAnalytical Chemistry and Sensors

Three Dimensional Crystallization Simulation and Recording Layer Thickness Effect in Phase Change Optical Recording

Zhaohui Fan、David E. Laughlin2003-02-28Japanese Journal of Applied Physics

The development of phase change optical recording requires better understanding of the crystallization kinetics of recording materials. Most of the existing simulation methods are based on two-dimensional crystallization models. In this work, we develop a new method to simulate the crystallization of phase change reco…

Liquid Crystal Research AdvancementsChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Determination of the Crystallisation Kinetics of Fast-Growth Phase-Change Materials for Mark-Formation Prediction

Erwin R. Meinders、M.H.R. Lankhorst2003-02-28Japanese Journal of Applied Physics

A mark simulation tool for fast-growth phase-change materials was developed to predict the formation and erasure of amorphous marks in phase-change discs that are based on doped Sb 2 Te compositions. One of the main challenges of such a simulation tool is the accurate determination of the input parameters. The thermal…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesAdvanced Semiconductor Detectors and Materials

Raman Spectroscopic Study on Hydrogen Bonding in Recovered Ice IV

Christoph G. Salzmann、Ingrid Kohl、Thomas Loerting 等 5 位作者2003-02-28The Journal of Physical Chemistry B

Ice IV was prepared in a reproducible manner on heating high-density amorphous ice (HDA) at pressure of 0.81 GPa up to ≈162 K at a slow rate of ≈0.5 K min -1, quenching thereafter to 77 K, and recovering the sample under liquid N 2 at 1 bar. Recovered ice IV was characterized by X-ray diffraction and it was free of HD…

Material Dynamics and PropertiesGlass properties and applicationsSpectroscopy and Quantum Chemical Studies

On the relationship between modulus of elasticity and microhardness

Галина Замфирова、Vicente Lorenzo、Rosario Benavente 等 4 位作者2003-02-28Journal of Applied Polymer Science

Abstract The correlation between the modulus of elasticity, on the one side, and Vickers microhardness and total microhardness, on the other side, was analyzed in the case of ultrahigh molecular weight polyethylenes. An extension of the application of the power relation between microhardness and the modulus ( MH = aE…

Corrosion Behavior and InhibitionForce Microscopy Techniques and ApplicationsConcrete Corrosion and Durability

Giant magnetothermopower associated with large magnetoresistance in Ag2−δTe

Young Sun、M. B. Salamon、M. Lee 等 4 位作者2003-02-28Applied Physics Letters

We have probed the temperature and magnetic-field dependence of the thermopower and resistance of a p-type silver chalcogenide, Ag2−δTe. The application of a magnetic field causes not only a large magnetoresistance but also a giant magnetothermopower effect. The maximum change of thermopower is as high as 470 μV/K in…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsMagnetic and transport properties of perovskites and related materials

Compressive stress relaxation through buckling of a low-k polymer-thin cap layer system

Francesca Iacopi、Sywert Brongersma、Karen Maex2003-02-28Applied Physics Letters

The thermomechanical stability of a system composed of a metallic cap layer on top of a low-k thermosetting polymer film is investigated. It is observed that, when metal layers with high compressive stresses are used, a stress relaxation takes place during thermal anneal at temperatures above 300 °C through buckling o…

3D IC and TSV technologiesCopper Interconnects and ReliabilityNanofabrication and Lithography Techniques

Ge2Sb2Te5Thin Film Doped with Silver

Chao-Te Lie、Po‐Cheng Kuo、Wei-Chih Hsu 等 6 位作者2003-02-28Japanese Journal of Applied Physics

(Ge 2 Sb 2 Te 5 ) 100- X Ag X films (where x =0∼3 at.%) with 100 nm thickness were deposited on natural-oxidized silicon wafer and glass substrates by dc magnetron co-sputtering of Ge 2 Sb 2 Te 5 and Ag targets. The effects of Ag content on the optical properties of the (Ge 2 Sb 2 Te 5 ) 100- X Ag X film were examined…

Glass properties and applicationsPhase-change materials and chalcogenidesOptical and Acousto-Optic Technologies

Electroactive Polymers for Corrosion Control

Peter Zarras、John D. Stenger‐Smith、Yen Wei2003-02-28ACS symposium series

An introduction to the chemistry and corrosion properties of electroactive polymers (EAPs) will be presented. This chapter will focus on both the synthesis of several classes of EAPs and the processes by which the insulating form is converted to the conducting form. The book chapter will present a compelling argument…

Conducting polymers and applicationsAnalytical Chemistry and SensorsDielectric materials and actuators