Materials Literature
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Electrochemically prepared poly(3,4-dimethoxypyrrole), poly(3,4-dimethoxythiophene), poly(3,4-ethylenedioxypyrrole), and poly(3,4-ethylenedioxythiophene) have been characterized by cyclic voltammetry (CV) and ultraviolet−visible (UV−vis) and Fourier transform infrared (FTIR) spectroscopy and were subsequently investig…
Enzymatic phosphorylation and dephosphorylation reactions were used to modify a genetically engineered variant of spider dragline silk. The approximately 25 kDa protein was phosphorylated with cyclic AMP-dependent kinase and dephosphorylated with calf intestinal alkaline phosphatase. Phosphorylation inhibited beta-she…
A new strategy for synthesis of hyperbranched polymers from commercially available A 2 type and BB‘ 2 type monomers has been developed. In the first part of this series, hyperbranched polysulfone−amine with multiamino groups is prepared by polyaddition of 1-(2-aminoethyl)piperazine (BB‘ 2 ) to divinyl sulfone (A 2 ) w…
We investigate the effects of impurity scattering on the conductance of metallic carbon nanotubes as a function of the relative separation of the impurities. First we compute the conductance of a clean (6,6) tube, and the effect of model gold contacts on this conductance. Then, we compute the effect of introducing a s…
133Cs and 13C-NMR have been used to study the electronic properties of the polymerized phase of CsC60 at ambient and under hydrostatic pressure. The salient result of this study is the finding of fluctuations in the local field at 133Cs site which are independent of the applied pressure and due to thermally activated…
The solution structure and dynamics of metal-bound water exchange have been studied in a series of diastereoisomeric gadolinium complexes of tetra(carboxyethyl) derivatives of 1,4,7,10-tetraazacyclodecane. The structures of the ( RRRS ), ( RSRS ), and ( RRSS ) ligands and the Eu, Gd, and Tb complexes of the ( RRRR ) i…
Core/shell semiconductor nanocrystals with InAs cores were synthesized and characterized. III−V semiconductor shells (InP and GaAs), and II−VI semiconductor shells (CdSe, ZnSe, and ZnS) were overgrown on InAs cores with various radii using a two step synthesis. In the first step cores were prepared, and in the second…
A procedure of the template displacement by organosilanes was utilized to prepare pure-silica and cerium-substituted mesoporous materials with tailored surface functionality. These two self-assembled mesostructured systems exhibit hexagonal arrangement of mesopores but they show different reactivity with respect to or…
The complex {Fe[HC(3,5-Me2pz)3]2}(BF4)2, shown crystallographically to contain a unique octahedral N6Fe site, shows a new type of spin-crossover behavior. The solid is high-spin from 350 K down to a temperature of 206 K, but below 206 K it undergoes a very abrupt decrease in magnetic moment. Mössbauer studies show con…
Depending on the experimental conditions, various charged water soluble porphyrins can aggregate, leading to large supramolecular assemblies whose basic building blocks are constituted by J-type aggregates or heteroaggregated species made up by oppositely charged molecules. The mesoscopic structures resulting on (i) t…
We electrochemically synthesized film -type vanadium hexacyanochromate-based magnets with high critical temperatures ( T c ): K I 0.31 V II 0.49 V III 0.51 [Cr III (CN) 6 ] 0.94 ·6.5H 2 O ( 1 ) ( T c = 310 K) and K I 0.61 V II 0.97 V III 0.03 [Cr III (CN) 6 ] 0.88 ·7.2H 2 O·0.4C 2 H 5 OH ( 2 ) ( T c = 345 K). The colo…
Tm(3+)-doped tellurite glass is investigated as a host for a broadband amplifier at 1.47 mum. The Tm(3+) fluorescence spectrum, lifetime, and cross section in tellurite glass are compared with those in fluorozirconate glasses. The advantages of a Tm(3+)-tellurite amplifier, especially when it is employed in combinatio…
CdWO4 nanorods have been prepared through a hydrothermal method at 130 °C. CdWO4 showed very strong photoluminescence at 486 nm at room temperature with the excitation 253 nm. The TEM image of the sample shows that it was composed of monomorphologic nanorods with a size of 80−280 × 20−40 nm2. We investigated the influ…
We use the spin-polarized excitons in a single quantum dot to design optical controls for basic operations in quantum computing. We examine the ultrafast nonlinear optical processes required and use the coherent nonlinear optical responses to deduce if such processes are physically reasonable. The importance and const…
We perform ab initio plane wave supercell density functional calculations on three candidate models of the (3 x 2) reconstruction of the beta-SiC(001) surface. We find that the two-adlayer asymmetric-dimer model (TAADM) is unambiguously favored for all reasonable values of Si chemical potential. We then use structures…
Recent high transverse field muon spin relaxation (TF-uSR) experiments performed on Bi2212 single crystals show that the phase parameter extracted from individual histogram, an indication of the angle between the muon's initial polarization direction and the detector direction, is temperature dependent. This phase shi…
This paper gives an outline of testing carried out in conjunction with Electroimpact to support the introduction of the A319/A320/A321 and A340-500/600 Panel Assembly Cells in Broughton, UK. Testing compared the percussion insert/EMR swaging of lockbolts with existing hydraulic installation methods. Tests included pre…
The electron-phonon coupling for Cr 3+ in different oxide host lattices (MgO, α-Al 2 O 3 and LaAlO 3 ) was probed by performing temperature dependent line broadening measurements for zero-phonon emission lines of single ions and exchange coupled pairs. No differences in electron-phonon coupling were found comparing th…
Aqueous gelatin slowly cooled from the sol state (60 °C) to different temperatures around the gel point has been investigated using dynamic light scattering. Three modes of correlation decay have been observed and their dependence on scattering vector ( q ), concentration ( c ), and temperature interpreted in the ligh…
A new manganese oxide, Ba 4 Ca 1 - x Mn 3+ x O 12 - δ, closely related to the hexagonal perovskite family has been synthesized. It crystallizes in the P 6̄ m 2 space group with a = 5.8003(3) Å and c = 38.958(1) Å. This structure derives from the rare hexagonal 16L polytype and exhibits ordered oxygen deficient vacanci…