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Protein crystallography as a source of data on protein quaternary structures

Eugene Krissinel、K. Henrick2006-08-06Acta Crystallographica Section A Foundations of Crystallography

Protein Quaternary Structures (PQS) represent assemblies of protein chains, which are stable in a particular environment. Biological function of many proteins is closely associated with the ability to aggregation or changing the oligomeric state in general. Therefore, PQS are often viewed as Biological Units. Knowing…

Protein Structure and DynamicsEnzyme Structure and Function

Low temperature phase transition in BaCuSi2O6

Karine Sparta、Michael Merz、G. Roth 等 6 位作者2006-08-06Acta Crystallographica Section A Foundations of Crystallography

An in situX-ray powder diffraction study has shown that cubic modification of (NH4)2SiF6 (cryptohalite) at 0.2-0.3 GPa transforms irreversibly into a trigonal polymorph with cell parameters a = 5.78 A and c = 4.78 A, presumably the previously known bararite, space group P-3m1. The choice of a pressuretransmitting liqu…

Clay minerals and soil interactionsChemical Synthesis and CharacterizationInorganic Fluorides and Related Compounds

Introduction to JANA2006

M. Dusek、V. Petricek、L. Palatinus2006-08-06Acta Crystallographica Section A Foundations of Crystallography

JANA2006 is a new version of crystallographic compu-ting system JANA [1] originally developed for incom-mensurately modulated structures. During more than 20 years of development it became widely used unified system for structure analysis of periodic and aperiodic crystals with emphasis on solving difficult structures…

Quasicrystal Structures and PropertiesMachine Learning in Materials ScienceX-ray Diffraction in Crystallography

Concerning the Different Roles of Cations in Metallic Zintl Phases: Ba7Ga4Sb9 as a Test Case

Pere Alemany、Miquel Llunell、Enric Cañadell2006-08-05Inorganic Chemistry

The question of the different roles of cations in metallic Zintl phases has been examined by taking Ba7Ga4Sb9, an electron-rich phase, as a test case. The electronic structure of this solid has been studied by means of a first-principles density functional theory approach and, indeed, the different Ba atoms are found…

Quantum and electron transport phenomenaAdvanced Thermoelectric Materials and DevicesMolecular Junctions and Nanostructures

Synthesis of Nanometer-Scale Polymeric Structures on Surfaces from Template Assisted Admicellar Polymerization: A Comparative Study with Protein Adsorption

Maricel Marquez、Krupa U. Patel、Andrew D. W. Carswell 等 5 位作者2006-08-05Langmuir

A novel method for the formation of nanometer-scale polymer structures via template assisted admicellar polymerization (TAAP) is described. Admicellar polymerization uses a surfactant layer adsorbed on a surface to localize monomer to the surface prior to polymerization of the monomer. Nanostructures are formed by res…

Advanced Polymer Synthesis and CharacterizationPolymer Surface Interaction StudiesNanofabrication and Lithography Techniques

Zero- and Two-Dimensional Organization of Tetrahedral Cadmium Chalcogenide Clusters with Bifunctional Covalent Linkers

Nanfeng Zheng、Xianhui Bu、J. Lauda 等 4 位作者2006-08-05Chemistry of Materials

Few examples are known in which chalcogenide clusters are assembled with organic ligands into crystallographically ordered covalent superlattices even though molecular crystals of such clusters have been known for decades. Here by using bifunctional organic ligands as the organizing force, semiconducting tetrahedral c…

Quantum Dots Synthesis And PropertiesPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications

Template Removal and Thermal Stability of Organically Functionalized Mesoporous Silica Nanoparticles

Rajeev Kumar、Hung‐Ting Chen、Juan L. V. Escoto 等 5 位作者2006-08-05Chemistry of Materials

The surfaces of organically functionalized, MCM-41-type mesoporous silica nanoparticle materials, prepared by a co-condensation method, were studied by solid-state nuclear magnetic resonance (NMR) spectroscopy following a series of heat treatments between 100 and 400 °C. The surfaces were functionalized with 2,2‘-bipy…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications

Ferromagnetic Cobalt Metallocycles

M. Moragues‐Cánovas、C.E. Talbot-Eeckelaers、Laure Catala 等 7 位作者2006-08-05Inorganic Chemistry

The tripodal alcohol 1,1,1-tris(hydroxymethyl)ethane (H3thme) directs the formation of heptanuclear cobalt metallocycles in which the metal ions are coupled ferromagnetically.

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

Surfactant-Assisted Synthesis of SnS Nanowires Grown on Tin Foils

Subhendu K. Panda、Anuja Datta、Apurba Dev 等 5 位作者2006-08-05Crystal Growth & Design

Crystalline SnS wires of micro- and nanometer scale have been synthesized over tin metal foils at room temperature using a simple surfactant-assisted approach. Scanning electron microscopy, transmission electron microscopy, UV−Vis−near infrared (NIR) and Fourier transform infrared (FTIR) spectroscopy were used to char…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanowire Synthesis and Applications

Facile Method To Prepare Surface-Enhanced-Raman-Scattering-Active Ag Nanostructures on Silica Spheres

Kwan Kim、Hyung Soo Kim、Hyoung Kun Park2006-08-05Langmuir

In this paper we describe a very simple electroless plating method used to prepare Ag-coated silica beads. Robust Ag nanostructures can be reproducibly fabricated by soaking silica beads in ethanolic solutions of AgNO(3) and butylamine. When the molar ratio of butylamine to AgNO(3) is far below 1.0, distinct nanosized…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And Properties

Preparation of Monodisperse Au/TiO2 Nanocatalysts via Self-Assembly

Jing Li、Hua Chun Zeng2006-08-05Chemistry of Materials

In this work, we report that presynthesized metallic nanoparticles (such as gold nanoparticles), rather than on-site growing ones that are prepared under thermally or photochemically activated conditions, can be “impregnated” uniformly onto premade oxide supports with organic interconnects which have bifunctional grou…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

Matter-wave soliton control in optical lattices with topological dislocations

Yaroslav V. Kartashov、Lluis Torner2006-08-05arXiv

We address the concept of guiding and transporting matter-wave solitons along the channels of optical lattices made by interference patterns of beams containing topological wavefront dislocations. The local lattice distortions that occur around the dislocations cause solitons to move along reconfigurable paths, a phen…

Materials Sciencephysics.optics

Electronic structure, structural and optical properties of thermally evaporated CdTe thin films

S. Lalitha、S. Zh. Karazhanov、P. Ravindran 等 6 位作者2006-08-05arXiv

Thin films of CdTe were deposited on glass substrates by thermal evaporation. From the XRD measurements itis found that the films are of zinc-blende-type structure. Transmittance, absorption, extinction, and refractive coefficients are measured. Electronic structure, band parameters and optical spectra of CdTe were ca…

Materials Science

Molecular Dynamics Simulation of Sputtering Process of Hydrogen and Graphene Sheets

HIROAKI NAKAMURA、ATSUSHI ITO2006-08-05arXiv

To clarify the yielding mechanism of small hydrocarbon molecules in chemical sputtering between hydrogen and graphene sheets, we made classical molecular dynamics simulation with modified Brenner's REBO potential which we proposed to deal with chemical reaction. As the simulation model, we prepared more realistic phys…

Materials Science

Synthesis, Properties, and Applications of Ferromagnetic‐Filled Carbon Nanotubes.

A. Leonhardt、Silke Hampel、Christian Mueller 等 9 位作者2006-08-04ChemInform

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Carbon Nanotubes in CompositesGraphene research and applicationsConducting polymers and applications

Theoretical analysis of polydispersity in the nematic phase of self-assembled semiflexible chains

Xinjiang Lü、James T. Kindt2006-08-04The Journal of Chemical Physics

In recent simulations of semiflexible equilibrium polymers [X. Lu and J. T. Kindt, J. Chem. Phys. 120, 10328 (2004)] a roughly biexponential distribution of chain lengths was observed in the nematic phase. In this study, we show that a theory representing the nematic phase as an equilibrium mixture of randomly oriente…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Resonance of curved nanowires

L. Calabri、Nicola M. Pugno、Weiqiang Ding 等 4 位作者2006-08-04Journal of Physics Condensed Matter

The effects of non-ideal experimental configuration on the mechanical resonance of boron (B) nanowires (NWs) were studied to obtain the corrected value for the Young’s modulus. The following effects have been theoretically considered: (i) the presence of intrinsic curvature, (ii) non-ideal clamps, (iii) spurious masse…

Carbon Nanotubes in CompositesForce Microscopy Techniques and ApplicationsMechanical and Optical Resonators

Strategies for Increasing the Sensitivity of Gadolinium Based MRI Contrast Agents

Peter Caravan2006-08-04ChemInform

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Advanced MRI Techniques and ApplicationsRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Synthesis and properties of new aromatic poly(ester‐imide)s derived from 4‐p‐biphenyl‐2,6‐bis(4‐trimellitimidophenyl) pyridine and various dihydroxy compounds

Hossein Behniafar、Ali Akbar Khaje Mirzai、Ali Beit Saeed2006-08-04Polymer International

Abstract A novel class of wholly aromatic poly(ester‐imide)s, having a biphenylene pendant group, with inherent viscosities of 0.32–0.49 dL g −1 was prepared by the diphenylchlorophosphate‐activated direct polyesterification of the preformed imide‐ring‐containing diacid, 4‐ p ‐biphenyl‐2,6‐bis(4‐trimellitimidophenyl)p…

Synthetic Organic Chemistry MethodsN-Heterocyclic Carbenes in Organic and Inorganic ChemistrySynthesis and properties of polymers

Amphidynamic Crystals: Structural Blueprints for Molecular Machines

Steven D. Karlen、Miguel A. Garcı́a-Garibay2006-08-04ChemInform

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Magnetism in coordination complexesMolecular Junctions and NanostructuresInorganic Chemistry and Materials