Materials Literature
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The interaction of water with the non-polar ZnO(1010) surface has been studied by high resolution electron energy loss spectroscopy (HREELS) and thermal desorption spectroscopy (TDS). Adsorption of water at room temperature leads to the partial dissociation of water molecules giving rise to a well defined (2x1) supers…
Taking advantage of the properties of the ferrocene as a redox and electron donor active unit and the pyrene as a fluorescent unit, dyad 2 shows a fast and reversible redox-switchable fluorescence emission.
We present simulation results of a design for negative index materials that uses magnetic resonators to provide negative permeability and metal films for negative permittivity. We also discuss the possibility of using semicontinuous metal films to achieve better manufacturability and enhanced impedance matching.
carbon nanotube (MWNT) nanocomposites were synthesized by in situ loading on the carbon nanotubes in an alkaline solution. The effects of the added carbon nanotubes on the morphology and electrochemical capacitance of were investigated in various loaded amounts of . The MWNT substrates can reduce the aggregation of na…
The effects of atmospheric air-plasma treatments on woven and non-woven polyester (PET) textile structures were studied by surface analysis methods: wettability and capillarity methods, as well as atomic force microscopy/lateral force microscopy (AFM/LFM). The water contact angle on plasma-treated PET decreased from 8…
Amino-functionalized SBA-15 type mesoporous silicas having unique hexagonal platelet morphologies with short channels (100-300 nm) running parallel to the thickness of the nanostructured hexagonal platelet type morphologies have been directly synthesized by co-condensation of aminopropyltriethoxysilane (APTES) and sod…
Highly dispersed H(3)PW(12)O(40)/SiO(2) catalysts with loadings between 3.6 and 62.5 wt% have been synthesised and characterised. The formation of a chemically distinct interfacial HPW species is identified by XPS, attributed to pertubation of W atoms within the Keggin cage in direct contact with the SiO(2) surface. E…
By finely tuning the TEOS/P123 molar ratio of the octane/water/P123/TEOS quadruple emulsion system and by controlling the synthesis conditions, an ultrafine emulsion system was isolated, under the confinement of which, nanoscale silica particles with ordered large mesopores (approximately 13 nm) have been successfully…
Gold nanorods were used as seeds for platinum growth, using a mild reducing agent, ascorbic acid, in the presence of the cationic surfactant cetyltrimethylammonium bromide (CTAB). Highly preferential growth on the tips or complete overcoating can be achieved by manipulation of the reduction conditions, among which the…
Nano-dimensional single-crystals of Fe, Mn, Co or Ni oxides have been prepared by the decomposition of their metal acetylacetonate at elevated temperatures in hexadecylamine. The amine acts as both a solvent and the capping agent. The crystalline structure and morphology of resulting samples have been characterized by…
A theoretical study of the write, read, and erase processes in electrical scanning probe storage on phase-change media is presented. Electrical, thermal, and phase-transformation mechanisms are considered to produce a physically realistic description of this new approach to ultrahigh-density data storage. Models devel…
This article overviews research in the interdisciplinary area of textile/skin interaction and related cutaneous intolerance. Microclimate in the skin/clothing system and especially the skin responses relates to the moisture and heat transfer within this system and plays a critical role in skin irritation from textiles…
Most long-range telecommunication systems are based upon microwave links. The transmitters use microwave amplifiers which in the very near future will be required to work at up to 30–100GHz with output power in the region of a few tens of watts. Carbon nanotubes (CNTs), which exhibit extraordinary field emission prope…
As the 21st century begins we are witnessing a paradigm shift in medical practice. Whereas the use of polymers in biomedical materials applications, for example as prostheses, medical devices, cont...
Apatite-type silicates have been attracting considerable interest as a new class of oxide ion conductor, whose conduction is mediated by interstitial oxide ions. We report here the first 29Si solid state NMR studies of these materials with a systematic investigation of thirteen compositions. Our results indicate a cor…
The paper describes the development of chemical modules simulating the prechemical and chemical stages of charged particle tracks in pure liquid water. These calculations are based on our physical track structure codes for electrons and ions (KURBUC, LEPHIST and LEAHIST) which provide the initial spatial distribution…
A simple method for surface functionalization of large-pore mesoporous silica by hyperbranching polymerization resulting in a high loading of amine groups is presented.
Macroporous polyacrylamide gels (MPAAGs) with unique elastic morphology and open porous structure are prepared at subzero temperatures. The porous structure of MPAAGs consisting of large, 1–100 µm-sized interconnected pores, is controlled by the freezing temperature, the content of the initiator system (ammonium persu…
This paper series presents detailed modeling and simulation studies of the nature of the impedance of solid oxide fuel cell ͑SOFC͒ anodes caused by gas-phase transport processes.The present part treats bulk gas-phase transport in button-cell experiments where gases are supplied from an outlet perpendicular to the elec…
The novel stilbazolium salt 4-N,N-dimethylamino-4′-N′-methyl-stilbazolium 2-naphthalenesulfonate (DSNS), has been synthesized and small single crystals were grown. The crystal structure of the resulting crystals was determined via X-ray crystallography and it was found to be non-centrosymmetric with the chromophores a…