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Analysis of the linear methods for determining copolymerization reactivity ratios. IV. A comprehensive and critical reexamination of carbocationic copolymerization data

Tibor Kelen、Ferenc Tüdöus、B. Turcsányi 等 4 位作者1977-12-01Journal of Polymer Science Polymer Chemistry Edition

Abstract Increased insight into the mechanism of carbocationic copolymerization has been achieved by classifying and reviewing in detail 334 monomer pairs in terms of the extended Kelen‐Tüdös method. The reactivity ratios ( r values) of essentially all published olefin–olefin, olefin–vinyl ether, vinyl ether‐vinyl eth…

biodegradable polymer synthesis and propertiesOrganometallic Complex Synthesis and CatalysisAdvanced Polymer Synthesis and Characterization

Interaction Between an Oscillating Bubble and a Free Surface

Georges L. Chahine1977-12-01Journal of Fluids Engineering

Abstract Interaction between a collapsing bubble and a free surface is investigated theoretically and experimentally using high speed photography. A limit value for the distance from the free surface to the center of the bubble reported to its radius is found. Under this limit the free surface is not disturbed before…

Fluid Dynamics and Heat TransferUltrasound and Cavitation PhenomenaPickering emulsions and particle stabilization

Density and structure of allophane

Shin–Ichiro Wada、Kōji Wada1977-12-01Clay Minerals

Abstract The densities of two allophane samples measured by displacement with water were 2·72–2·78 g/cm 3 , while those measured by a float-sink test in CH 3 OH-, CH 3 COCH 3 -, C 6 H 6 - and CCl 4 -C 2 H 2 Br 4 mixtures were 1·84, 1·94–1·98, 2·35 and 2·35–2·39 g/cm 3 , respectively. The results of the density determi…

Mineralogy and Gemology StudiesClay minerals and soil interactionsAdsorption, diffusion, and thermodynamic properties of materials

Predicting the Stability of Biological Standards and Products

Thomas B. L. Kirkwood1977-12-01Biometrics

A high level of stability is essential for any biological standard and is desirable in most other biological products. It is in general impossible to observe directly the rate of degradation of a biological standard since no independent scale of measurement is available. An indirect method is therefore required. The m…

Crystallization and Solubility StudiesComputational Drug Discovery MethodsPesticide Residue Analysis and Safety

Preparation and properties of LixVS2 (0 .ltoreq. x .ltoreq. 1)

D. W. Murphy、C. Cros、F. J. Di Salvo 等 4 位作者1977-12-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPreparation and properties of LixVS2 (0 .ltoreq. x .ltoreq. 1)D. W. Murphy, C. Cros, F. J. Di Salvo, and J. V. WaszczakCite this: Inorg. Chem. 1977, 16, 12, 3027–3031Publication Date (Print):December 1, 1977Publication History Published online1 May 2002Published inissue 1 De…

Electronic and Structural Properties of OxidesOrganic and Molecular Conductors ResearchAdvanced Condensed Matter Physics

Glass: Structure by Spectroscopy

Philip Gaskell1977-12-01Physics Bulletin

J Wong and C A Angell New York: Marcel Dekker 1976 pp xv + 864 price SwF 145 The need for an extensive review of this subject was clearly demonstrated by the difficulty in keeping this book on my desk and not on my colleagues'. Studies of the generally recognised spectroscopic techniques applied to inorganic glasses a…

Material Dynamics and PropertiesGlass properties and applicationsMineralogy and Gemology Studies

Supramolecular structure of a high‐modulus polyaromatic fiber (Kevlar 49)

M. G. Dobb、D. J. Johnson、B.P. Saville1977-12-01Journal of Polymer Science Polymer Physics Edition

Abstract The supramolecular organization of the aromatic polyamide fiber Kevlar 49 has been studied using a combination of electron diffraction and electron microscope dark‐field image techniques. The dark‐field images derived using selected reflections from longitudinal sections exhibit axial banding of two main type…

Polymer crystallization and propertiesFiber-reinforced polymer compositesSynthesis and properties of polymers

Acción del CO2 sobre un cemento portlcnd. II. Estudio por espectroscopia infrarroja

Demetrio Gaspar-Tebar、Miguel Muñoz-Plaza、Tomás Vázquez-Moreno1977-12-01Materiales de Construccion

En un artículo anterior (1) se dio cuenta de los trabajos realizados sobre la influencia que ejerce el CO2 puro en las características químicas, físicas y fisicomecánicas de un cemento portland (P-450), fabricado por la industria española, habiendo probado que tanto el cemento anhidro, como el hidratado, experimentan…

Ensayo a escala de obra sobre fisuración y agrietamiento

J. I. Martínez Ynzenga、M. Aguanell1977-12-01Materiales de Construccion

Con objeto de demostrar que el hormigón confeccionado con cemento PA-350 no presenta ninguna anomalía (si se pone en obra y se siguen las reglas elementales de cualquier código de buena práctica y que especifican todas las Normas referentes al hormigón, las cuales se dan para cumplir en todos los hormigones, independi…

Métodos electroquímicos semicuantitativos de estudio de lo corrosión por picaduras del acero para armaduras de hormigón

M. C. Andrade Perdrix、J. A. González1977-12-01Materiales de Construccion

El acero embebido en el hormigón se encuentra sometido a un medio de elevada alcalinidad (pH comprendido entre 12 y 13), debido a la cal libre, a los álcalis que contiene el cemento, y al Ca(0H)2 que se forma durante la hidratación de los silicatos. En esta situación, el acero se halla recubierto por una capa de óxido…

Bibliografía

Equipo Editorial1977-12-01Materiales de Construccion

El problema de la determinación: del contenido de cemento en morteros; y hormigones fraguados

José Calleja1977-12-01Materiales de Construccion

Se trata en este trabajo de señalar el campo y las condiciones de aplicación del método NELC 5.01-a) para determinar la dosificación de cemento en morteros y hormigones fraguados, a la vista de los nuevos tipos de cemento del vigente y reciente Pliego de Prescripciones Técnicas Generales para la Recepción de Cementos…

Resistencia química del hormigón Estudio de dos cementos portland frente al agua de mar

Demetrio Gaspar-Tebar、José Luis Sagrera-Moreno1977-12-01Materiales de Construccion

El comportamiento de los morteros y hormigones sometidos a la acción del agua de mar ha sido objeto de numerosos trabajos como consecuencia de la gran cantidad de obras marítimas construidas a base de hormigón en masa y armado; de aquí, que sea un tema que ha preocupado y sigue interesando no sólo desde un punto de vi…

Influence of particle size ratio on the continuity of aggregates

Robert P. Kusy1977-12-01Journal of Applied Physics

A model is developed which considers the volume fraction of dispersed phase necessary to form an infinitely long network as a function of the particle size ratio. Recognizing that neither a monolayer nor a double layer of dispersed particles around the primary phase is a necessary condition for continuity, the surface…

Polymer crystallization and propertiesMaterial Dynamics and Properties

A theory of a.c. conduction in chalcogenide glasses

Stephen R. Elliott1977-12-01OpenAlex

An electrical conductivity having a frequency dependence ∼ω s , where s < 1, has been reported for many amorphous semiconductors and chalcogenide glasses. It is the purpose of this paper to point out that the mechanism normally postulated for this behaviour, namely, thermally assisted quantum-mechanical tunnelling, is…

Phase-change materials and chalcogenidesSolid-state spectroscopy and crystallographyGlass properties and applications

Study of electron transport in As-Se-Te glasses

Sudha Mahadevan、A. Giridhar、K. J. Rao1977-11-28Journal of Physics C Solid State Physics

The low and high temperature DC and AC conductivities of As-Se-Te glasses have been studied with different Se:Te ratios. The transport behaviour has been discussed in terms of known transport mechanisms. The composition dependence of the conductivities are discussed in terms of known structures. The transport among ex…

Phase-change materials and chalcogenidesGlass properties and applicationsSolid-state spectroscopy and crystallography

ChemInform Abstract: IMIDAZOLATE COMPLEXES OF FERRIC PORPHYRINS

Mario J. Nappa、Joan Selverstone Valentine、P. A. SNYDER1977-11-22ChemInform

Abstract Elektronenspektroskopische Untersuchungen zeigen, daß der aus dem Chloro‐tetraphenylporphinato‐Fe(III)‐Komplex (I) dargestellte Bis‐[imidazol]‐Komplex (II) durch verschiedene Basen wie Tetrabutylammoniumhydroxid,K‐tert.‐butoxid oder K‐imidazolat am Imidazol unter Bildung der Produkte (III) und (IV) deprotonie…

Magnetism in coordination complexesMetal complexes synthesis and propertiesPorphyrin and Phthalocyanine Chemistry