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Mechanical Relaxations in Mixed‐Alkali Silicate Glasses: I, Results

James E. Shelby、Delbert E. Day1969-04-01Journal of the American Ceramic Society

The internal friction of silicate glasses containing mixtures of Li‐Na, Li‐K, Li‐Rb, Li‐Cs, Na‐K, Na‐Rb, Na‐Cs, and K‐Rb was measured from ‐180° to 500°C at a frequency of 0.4 Hz. Values for the density, index of refraction, and dynamic shear modulus are also reported. With small additions of a second alkali, a new in…

Nuclear materials and radiation effectsGlass properties and applicationsLuminescence Properties of Advanced Materials

Structure and properties of .mu.-oxobis(tetraphenylporphineiron(III)

Everly B. Fleischer、T.S. Srivastava1969-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStructure and properties of .mu.-oxobis(tetraphenylporphineiron(III)Everly B. Fleischer and T. S. SrivastavaCite this: J. Am. Chem. Soc. 1969, 91, 9, 2403–2405Publication Date (Print):April 1, 1969Publication History Published online1 May 2002Published inissue 1 April 1969ht…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsMetal complexes synthesis and properties

The rate of selenium removal from tellurium by hydrogen purging

J. R. Rawling、J. M. Toguri1969-04-01The Canadian Journal of Chemical Engineering

Abstract The reaction between hydrogen gas and selenium dissolved in liquid tellurium is described as follows H 2 (g) + Se ⇄ H 2 Se(g) The kinetics of this reaction have been investigated at temperatures ranging between 525 and 625°C and at concentrations of selenium varying between 250 and 3,300 ppm. Under all condit…

Nuclear Materials and PropertiesChemical Looping and Thermochemical ProcessesChemical Thermodynamics and Molecular Structure

Diamond-windowed cell for spectrophotometry of molten fluoride salts

L.M. Toth、J. P. Young、George Pedro Smith1969-04-01Analytical Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDiamond-windowed cell for spectrophotometry of molten fluoride saltsLouis M. Toth, Jack Phillip. Young, and George Pedro. SmithCite this: Anal. Chem. 1969, 41, 4, 683–685Publication Date (Print):April 1, 1969Publication History Published online1 May 2002Published inissue 1 A…

Semiconductor materials and devicesElectron and X-Ray Spectroscopy Techniques

Role of Interfacial Area in Sulfuric Acid Alkylation

F. B. Sprow1969-04-01Industrial & Engineering Chemistry Process Design and Development

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRole of Interfacial Area in Sulfuric Acid AlkylationF. B. SprowCite this: Ind. Eng. Chem. Process Des. Dev. 1969, 8, 2, 254–257Publication Date (Print):April 1, 1969Publication History Published online1 May 2002Published inissue 1 April 1969https://pubs.acs.org/doi/10.1021/i…

Crystallization and Solubility StudiesCatalysis for Biomass Conversion

A Study of Residual Stress Induced During Rolling

E. V. Zaretsky、R. J. Parker、W. J. Anderson1969-04-01Journal of Lubrication Technology

Subsurface residual stress measurements were made on SAE 52100 steel inner races from 207-size deep-groove ball bearings in which ΔH (ball hardness minus race hardness) ranged from −1.1 to 3.5 points Rockwell C. These bearings had been run at an inner-race speed of 2750 rpm and a radial load of 1320 lb producing maxim…

Metal Alloys Wear and PropertiesTunneling and Rock MechanicsGear and Bearing Dynamics Analysis

Series of rare earth garnets Ln3+3M2Li+3O12 (M=Te, W)

H. M. Kasper1969-04-01Inorganic Chemistry

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSeries of rare earth garnets Ln3+3M2Li+3O12 (M=Te, W)H. M. KasperCite this: Inorg. Chem. 1969, 8, 4, 1000–1002Publication Date (Print):April 1, 1969Publication History Published online1 May 2002Published inissue 1 April 1969https://pubs.acs.org/doi/10.1021/ic50074a058https:/…

Glass properties and applicationsLanthanide and Transition Metal ComplexesLuminescence Properties of Advanced Materials

Redox chemistry of the system O2-O2--O22--O2- in fused salts

P. G. Zambonin、Joseph Jordan1969-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRedox chemistry of the system O2-O2--O22--O2- in fused saltsPier G. Zambonin and Joseph JordanCite this: J. Am. Chem. Soc. 1969, 91, 9, 2225–2228Publication Date (Print):April 1, 1969Publication History Published online1 May 2002Published inissue 1 April 1969https://pubs.acs…

Polyoxometalates: Synthesis and ApplicationsChemical and Physical Properties in Aqueous Solutions

Luminescence of Phosphors Based on Host Lattices ABO4 (A is Sc, In; B is P, V, Nb)

G. Blasse、A. Bril1969-04-01The Journal of Chemical Physics

The luminescence of the unactivated and Bi3+- and Eu3+-activated compounds ABO4 (A is Sc, In; B is P, V, Nb) is reported and compared with the luminescence of the corresponding rare-earth and yttrium compounds. The ScNbO4 shows a weak, blue emission, ScVO4 a blue-green, and InVO4 a green emission. The other host latti…

Glass properties and applicationsNuclear materials and radiation effectsLuminescence Properties of Advanced Materials

The stress at which dislocations are generated at a particle-matrix interface

Michael F. Ashby、S. H. Gelles、L.E. Tanner1969-04-01Philosophical magazine

When a hydrostatic pressure is applied to a metal containing particles or inclusions of different elastic constant, the local shear stresses which develop can be large enough to cause the interface between the particle and the metal matrix to emit dislocations. We have measured the pressure (from which we calculate th…

Composite Material MechanicsNumerical methods in engineeringMicrostructure and mechanical properties

Zur Kenntnis der Nickelhydroxidelektrode. II. Über die Oxydationsprodukte von Nickel(II)‐hydroxiden

Hans R. Bode、K. Dehmelt、Josef Witte1969-04-01Zeitschrift für anorganische und allgemeine Chemie

Abstract Die reinen Phasen oxydierter Nickelhydroxide, die auf der Nickelhydroxidelektrode im alkalischen Akkumulator auftreten können, wurden hergestellt, ihre kristallographischen Daten und ihr chemisches Verhalten untersucht und Umwandlungsbedingungen ermittelt.

Advancements in Solid Oxide Fuel CellsPower Transformer Diagnostics and InsulationCorrosion Behavior and Inhibition

Peel Adhesion: Influence of Surface Energies and Adhesive Rheology

D. H. Kaelble1969-04-01The Journal of Adhesion

The adhesion properties of polymers are known to be influenced by both intermolecular forces operative at the interface and the rheological history of both bonding and unbonding. Recent adsorption and viscoelastic theories of adhesion and cohesion are implemented in a comprehensive examination of these phenomena. Eigh…

Polymer crystallization and propertiesAdhesion, Friction, and Surface InteractionsPolymer Nanocomposites and Properties

Attachment of amino groups to polymer surfaces by radiofrequency plasmas

John R. Hollahan、B. B. Stafford、Richard Falb 等 4 位作者1969-04-01Journal of Applied Polymer Science

Abstract Low temperature gaseous plasmas of ammonia or nitrogen–hydrogen mixtures contain NH 2 groups, or precursors thereof, formed in the plasma, which experimental evidence strongly suggests, can add to various polymer surfaces. The plasmas were established in the 0.3–1.5 torr range by radiofrequency (13.56 MHz) e…

Surface Modification and Superhydrophobicity

DISTORTION OF A CHOLESTERIC STRUCTURE BY A MAGNETIC FIELD

Robert B. Meyer1969-04-01Applied Physics Letters

An experiment is described which confirms the theory of the distortion of a cholesteric structure by a magnetic field. Field effects in a sample of p-azoxyanisole doped with cholesteryl acetate were viewed directly with a microscope, and the pitch of the helical structure was measured as a function of field strength.

Optical Polarization and EllipsometryLiquid Crystal Research AdvancementsMolecular spectroscopy and chirality

Diamagnetic susceptibility exaltation in hydrocarbons

Hyp J. Dauben、James D. Wilson、John L. Laity1969-04-01Journal of the American Chemical Society

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDiamagnetic susceptibility exaltation in hydrocarbonsHyp J. Dauben Jr., James Dennis Wilson, and John L. LaityCite this: J. Am. Chem. Soc. 1969, 91, 8, 1991–1998Publication Date (Print):April 1, 1969Publication History Published online1 May 2002Published inissue 1 April 1969…

Advanced Chemical Physics StudiesSolid-state spectroscopy and crystallographyChemical and Physical Properties of Materials

Electromigration—A brief survey and some recent results

J. R. Black1969-04-01OpenAlex

Recently, electromigration has been identified as a potential wear-out failure mode for semiconductor devices employing metal film conductors of inadequate cross-sectional area. A brief survey of electromigration indicates that although the effect has been known for several decades, a great deal of the processes invol…

Semiconductor materials and devicesElectronic Packaging and Soldering TechnologiesCopper Interconnects and Reliability

Conduction in non-crystalline materials

N. F. Mott1969-04-01OpenAlex

If the distance between atoms in a crystalline lattice is increased, an energy gap appears, which in a divalent material will separate occupied from unoccupied states of an electron. In a non-crystalline substance, a minimum is expected in the density of states (a ‘pseudogap’). An approximate theoretical estimate is g…

Glass properties and applicationsHigh-pressure geophysics and materialsMaterial Dynamics and Properties

The kinetics of twinning in zinc and tin crystals

J. H. Brunton、Michael P. Wilson1969-03-25Proceedings of the Royal Society of London A Mathematical and Physical Sciences

Abstract By using a high speed rotating mirror camera combined with a microscope, the rapid initial lengthening of twins and their subsequent broadening have been studied. In zinc, twins of up to 1·9 mm appeared in crystal surfaces within 1 μs and subsequently the tips of such twins were observed to move at up to 780…

Microstructure and mechanical propertiesMetallurgical and Alloy ProcessesElectronic Packaging and Soldering Technologies

Effect of Magnetic Field on the Fluorescence of Tetracene Crystals: Exciton Fission

Nicholas E. Geacintov、Martin Pope、F.L. Vogel1969-03-24OpenAlex

The fluorescence efficiency of tetracene single crystals may be enhanced by as much as 38% in a magnetic field $H>2000$ G. The enhancement is anisotropic with respect to the orientation of $H$ in the $\mathrm{ab}$ plane. It is shown that a magnetically sensitive coupling of singlet states to a double-triplet-excito…

Photoreceptor and optogenetics researchAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

Glass-Transition Temperature of Water

A. A. Miller1969-03-21Science

The glass-transition temperature of water (T(g)) has been calculated by use of the Tammann-Hesse viscosity equation with the viscosity equal to 10(13) poise at T(g). The derived value of T(g),162 +/- 1 degrees K, is significantly higher than previous estimates.

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesGlass properties and applications