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Measurements of changes in permittivity, tanδ, and d∂∂ as function of compressive stress parallel to the polar axis are presented for lead zirconate—lead titanate transducer ceramics. The “hard” ceramics (PZT-4 and PZT-8) suitable for high-power application show large changes of properties for stresses to 20 kpsi, but…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMoessbauer spectra of some porphyrin complexes with pyridine, piperidine, and imidazoleLawrence M. Epstein, Darel K. Straub, and C. MaricondiCite this: Inorg. Chem. 1967, 6, 9, 1720–1724Publication Date (Print):September 1, 1967Publication History Published online1 May 2002P…
The results of an investigation of the structure of Ni+ +, ions in Na2O–B2O3 glasses by optical and EPR techniques are reported. The coordination about the ion sites is found to be octahedral, and a small amount of covalency is inferred. The crystal-field splitting of the d8 levels decreases as the Na2O content of the…
Abstract Graphitoxid entsteht aus Graphit und leicht Sauerstoff abgebenden Oxydationsmitteln nur dann, wenn der Graphit zuerst zum Graphitsalz (C A − · 2 HA) oxydiert wird. Die weitere Oxydation verläuft um so schneller und vollständiger, je mehr Wasser die Oxydations‐mischung enthält, wobei jedoch eine kritische Konz…
Abstract A simple theory is developed which correlates the Izod impact strength of polymers with ( G ′ 100 ‐ G ′ 300 ) 2 / G ′ 100 , where G ′ 100 and G ′ 300 are dynamic shear moduli at 100°K. and 300°K., respectively. The theory assumes the Maxwell element for the material and the fracture time smaller than the rela…
A modified superposition principle has been employed to describe creep in the nonlinear range under combined stresses which change abruptly from time to time. The stress function fij employed is derived from three integrals of the multi-integral theory for constant stress. Several means of treating the nonlinearity in…
The electrostriction and polarization in the perovskite-type ferroelectric ceramics have been calculated in the state under the arbitrary biasing field. Domain configurations produced by 180°-reversal or 90°-rotation have been represented here by the threshold angle θ 180 or θ 90 ; that is, domains, making smaller ang…
Abstract Oriented amylose fibers in the V form were prepared and subjected to x‐ray analysis. Unit cells and the probable space group of P2 1 2 1 2 1 were determined for the V anhydrous and V hydrate forms of amylose; the analysis confirms previous predictions of these structures based on x‐ray powder patterns. Chain…
Abstract The thermal stability and degradation process for a specific poly(aryl ether) system have been studied. In particular, the polymer which is available from Union Carbide Corporation as Bakelite polysulfone has been examined in detail. Polysulfone can be prepared from 2,2‐bis(4‐hydroxyphenyl)propane and 4,4′‐di…
The concentration of argon in sputtered nickel films has been obtained as a function of the film-growth temperature, the discharge pressure, and of the energy (bias voltage) with which the argon ions bombard the growing film. The concentrations vary from about 10−1 argon atoms/Ni atom to 10−4 argon atoms/Ni atom, depe…
Abstract Stabilization of metastable aragonite and Mg-calcites is an inevitable process and constitutes a large and important part of carbonate diagenesis. Stabilization can occur in only a limited number of ways. "Solid state" stabilization takes place by inversion or exsolution for aragonite and Mg-calcite, respecti…
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The temperature dependence of the second-order Raman spectrum of SrTiO3 and KTaO3 has been observed over the temperature range 4°—473°K using the mercury 4358-Å exciting line. From group-theoretical arguments for cubic perovskite lattices the spectra have been interpreted in terms of phonon pairs at critical points in…