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One‐Pot Synthesis of Potassium‐Functionalized Mesoporous γ‐Alumina: A Solid Superbase

Lin‐Bing Sun、Jing Yang、Jia Hui Kou 等 8 位作者2008-03-19Angewandte Chemie

In einem Arbeitsgang: Mesoporöse Kalium-γ-aluminiumoxid-Superbasen, die sich durch eine hohe Basestärke von 27.0 und eine gut ausgeprägte mesoporöse Struktur auszeichnen, sind effiziente Katalysatoren in der Isomerisierung von 1-Hexen. Ihre einfache Synthese in einem Eintopfprozess beruht auf der flexiblen Verwendung…

Metal-Organic Frameworks: Synthesis and ApplicationsMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications

Preparation and Characterization of Cubic and Hexagonal Polytypes of ZnSe:Cu2+ One-Dimensional Nanostructures

Baojuan Xi、Dechen Xu、Shenglin Xiong 等 7 位作者2008-03-19The Journal of Physical Chemistry C

Cu-doped ZnSe single-crystal one-dimensional (1-D) nanostructures were fabricated via thermal treatment of the as-synthesized corresponding precursor, which was prepared through a ternary solution-based method. The evident phase transformation suggests that doping with Cu 2+ favors the formation of the cubic phase ZnS…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanowire Synthesis and Applications

Distribution of Free and Liposomal Doxorubicin After Isolated Lung Perfusion in a Sarcoma Model

Hua Yan、Cai Cheng、Amina Haouala 等 10 位作者2008-03-19The Annals of Thoracic Surgery

BACKGROUND: Isolated lung perfusion (ILP) with free and a novel liposomal-encapsulated doxorubicin (Liporubicin, CT Sciences SA, Lausanne, Switzerland) was compared with respect to drug uptake and distribution in rat lungs bearing a sarcomatous tumor. METHODS: A single sarcomatous tumor was generated in the left lung…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsLung Cancer Research Studies

Properties of styrene‐methyl methacrylate grafted DPNR latex at different monomer concentrations

Siti Hajjar Che Man、Azanam S. Hashim、Hazizan Md Akil2008-03-19Journal of Applied Polymer Science

Abstract The graft copolymerization of styrene and methyl methacrylate (MMA) on to deproteinized natural rubber (DPNR) latex was carried out. The effect of monomer concentrations on grafting efficiency, thermal and mechanical properties was studied. The synthesized graft copolymers were characterized by proton nuclear…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Diffusion-Controlled Self-Assembly and Dendrite Formation in Silver-Seeded Anatase Titania Nanospheres

James A. Corno、J. D. Stout、Rusen Yang 等 4 位作者2008-03-19The Journal of Physical Chemistry C

We study diffusion-controlled, solvent-mediated self-assembly and dendritic structure formation as anatase TiO 2 is seeded with silver oxides and silver that are formed using silver nitrate (zinc-catalyzed). Anatase TiO 2 nanocolloid solutions are seeded with silver nitrate over a concentration range extending to satu…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesSilicon Nanostructures and Photoluminescence

A mixture of fortunes: the curious determination of the structure ofEscherichia coliBL21 Gab protein

Bernhard Lohkamp、Doreen Dobritzsch2008-03-19Acta Crystallographica Section D Biological Crystallography

In protein crystallography, monodisperse protein samples of high purity are usually required in order to obtain diffraction-quality crystals. Here, crystals were reproducibly grown from a protein sample before its homogeneity had been determined. The sample was obtained after the first attempt to purify a recombinant…

Protein Structure and DynamicsEnzyme Structure and FunctionBiochemical and Molecular Research

Electron mobility in Gaussian heavily doped ZnO surface quantum wells

Doan Nhat Quang、Le Tuan、Nguyễn Thành Tiên2008-03-19Physical Review B

We present a theory of the low-temperature mobility of electrons in a Gaussian heavily doped zinc oxide surface quantum well (ZnO SFQW), taking into account both surface impurity and surface roughness scattering. The theory also includes strong confinement due to spontaneous polarization charges on the surface of ZnO.…

Semiconductor Quantum Structures and DevicesZnO doping and propertiesQuantum and electron transport phenomena

Towards a rational approach for heavy-atom derivative screening in protein crystallography

Johnson Agniswamy、Michael Joyce、Carl H. Hammer 等 4 位作者2008-03-19Acta Crystallographica Section D Biological Crystallography

Heavy-atom derivatization is routinely used in protein structure determination and is thus of critical importance in structural biology. In order to replace the current trial-and-error heavy-atom derivative screening with a knowledge-based rational derivative-selection method, the reactivity of more than 40 heavy-atom…

Protein Structure and DynamicsMass Spectrometry Techniques and ApplicationsEnzyme Structure and Function

Thermal and physicomechanical properties of ethylene‐vinyl acetate copolymer and layered double hydroxide composites

B. Ramaraj、Kuk Ro Yoon2008-03-19Journal of Applied Polymer Science

Abstract A series of ethylene‐vinyl acetate (EVA) copolymer films have been prepared with different compositions viz. 2, 4, 6, and 8 wt % layered double hydroxide (LDH) nanoparticles by solution intercalation method. These solution‐casted EVA/LDH nanocomposite films were dried and characterized by differential scannin…

Polymer Nanocomposites and PropertiesLayered Double Hydroxides Synthesis and ApplicationsSilicone and Siloxane Chemistry

Effect of solvents in radiation‐induced grafting of 4‐vinyl pyridine onto fluorinated ethylene propylene copolymer

Sangram K. Rath、Akshaya K. Palai、Swati Rao 等 5 位作者2008-03-19Journal of Applied Polymer Science

Abstract A wide range of solvents have been examined to find their effect on radiation‐induced grafting of 4‐vinyl pyridine onto fluorinated ethylene propylene copolymer by simultaneous irradiation technique. The effect of solvent on percentage of grafting has been monitored by varying monomer concentration and total…

Fuel Cells and Related MaterialsFiber-reinforced polymer compositesPolymer Nanocomposite Synthesis and Irradiation

Critical currents in graphene Josephson junctions

J González、E Perfetto2008-03-19Journal of Physics Condensed Matter

We study the superconducting correlations induced in graphene when it is placed between two superconductors, focusing in particular on the supercurrents supported by the 2D system. For this purpose we make use of a formalism placing the emphasis on the many-body aspects of the problem, with the aim of investigating th…

Graphene research and applicationsTopological Materials and PhenomenaAdvanced Physical and Chemical Molecular Interactions

Inside-out electromagnetic cloaking

Nina A. Zharova、Ilya V. Shadrivov、Yuri S. Kivshar2008-03-19Optics Express

We introduce a novel concept of an inside-out (or inverse) cloak for electromagnetic waves based on the coordinate transformation of Maxwell's equations. This concept can be employed for creating absorbing non-reflecting media as matching layers in numerical simulations. In contrast to the commonly used perfectly matc…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies

Active material reversible attachments: shape memory polymer based

Thomas B. Stanford、William Barvosa-Carter、Alan L. Browne 等 4 位作者2008-03-19Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

We detail the joint concept generation and embodiment development by HRL and GMR&D of shape memory polymer (SMP) based reversible-on-demand attachments. In this initial study of active material enabled reversible-on-demand attachments, our primary focus was on hook-and-loop type fasteners. The approach followed, in br…

Polymer composites and self-healingSoft Robotics and ApplicationsAdvanced Materials and Mechanics

Systematic investigation on the geometric dependence of the calculated nuclear magnetic shielding constants

Igor Ying Zhang、Xin Xu、YiJing Yan2008-03-19Journal of Computational Chemistry

We perform a systematic examination on the dependence of the calculated nuclear magnetic shielding constants on the chosen geometry for a selective set of density functional methods of B3LYP, PBE0, and OPBE. We find that the OPBE exchange-correlation functional performs remarkably well when either the optimized geomet…

Magnetism in coordination complexesCrystal Structures and PropertiesAdvanced NMR Techniques and Applications

d-Glucose-Derived Polymer Intermediates as Templates for the Synthesis of Ultrastable and Redispersible Gold Colloids

Ziyi Zhong、Daohao Sim、Jaclyn Teo 等 6 位作者2008-03-19Langmuir

A two-stage hydrothermal process was developed for the synthesis of highly dispersed Au colloids. In the first stage, a novel glucose-derived polymer template was prepared by the hydrothermal treatment of glucose at 160 degrees C. This template was then further used in the next step to synthesize highly dispersed gold…

Catalytic Processes in Materials ScienceNanocluster Synthesis and ApplicationsNanomaterials for catalytic reactions

Novel phenylethynyl‐endcapped polyimide oligomers: Synthesis and characterization

Jiansheng Chen、Ximing Qu、Jingang Liu 等 6 位作者2008-03-19Polymer Engineering and Science

Abstract A series of novel phenylethynyl‐endcapped polyimide oligomers were prepared by polycondensation of an aromatic diamine mixture of 1,3‐bis(4‐aminophenoxy) benzene (1,3,4‐APB) and 3,4′‐oxydianiline (3,4′‐ODA) with different aromatic dianhydrides including 3,3′,4,4′‐biphenyltetracarboxylic dianhydride (BPDA), 4,…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Amorphous orientation and its relationship to processing stages of blended polypropylene/polyethylene fibers

Amy M. Trottier、Josef W. Zwanziger、N. Sanjeeva Murthy2008-03-19Journal of Applied Polymer Science

Abstract Changes in the molecular orientation, melting behavior, and percent crystallinity of the individual components in a fibrous blend of isotactic polypropylene (iPP) and high‐density polyethylene (HDPE) that occur during the melt extrusion process were examined using wide‐angle X‐ray diffraction (WAXD) and diffe…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Exploring structural variability in X-ray crystallographic models using protein local optimization by torsion-angle sampling

Jennifer L. Knight、Zhiyong Zhou、Emilio Gallicchio 等 7 位作者2008-03-19Acta Crystallographica Section D Biological Crystallography

Modeling structural variability is critical for understanding protein function and for modeling reliable targets for in silico docking experiments. Because of the time-intensive nature of manual X-ray crystallographic refinement, automated refinement methods that thoroughly explore conformational space are essential f…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

AUTOGAMOUS AUXOSPORULATION IN PINNULARIA NODOSA (BACILLARIOPHYCEAE)1

Aloisie Poulíčková、David G. Mann2008-03-19Journal of Phycology

Auxosporulation of the freshwater epipelic diatom Pinnularia nodosa (Ehrenb.) W. Sm. was studied in a clonal culture. Interphase cells possessed two chloroplasts with invaginated pyrenoids. The nucleus contained a single small body of heterochromatin at one end, also visible during most of meiotic prophase. During aux…

Marine and coastal ecosystemsAquatic Ecosystems and Phytoplankton DynamicsDiatoms and Algae Research

Effect of weakly interacting nanofiller on the morphology and viscoelastic response of polyolefins

Jan Kalfus、Josef Jančář、Jaroslav Kučera2008-03-19Polymer Engineering and Science

Abstract Effect of silica nanofiller on the deformation response and morphology of low‐ and high‐density polyethylene (HDPE, LDPE) and isotactic polypropylene (PP) modified with fumed silica was investigated. The dynamic‐mechanical thermal spectroscopy, differential scanning calorimetry, optical microscopy, and densit…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites