Materials Literature
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New luminescent isomeric europium(III) complexes with carboxylic carbonyl group coordination (I and II) have been prepared by solvothermal synthesis using the ligand 2,2'-bipyridine-4,4'-dicarboxylic acid (bpdc), with the nonradiatively shielded Eu3+ coordination sphere completed by dimethyl sulfoxide ligands. The roo…
This paper describes the synthesis of new magnetic, reactive polystyrene/polypyrrole core/shell latex particles. The core consists of a polystyrene microsphere containing gamma-Fe2O3 superparamagnetic nanoparticles (PSmag), and the shell is made of reactive N-carboxylic acid-functionalized polypyrrole (PPyCOOH). These…
Abstract Nylon 6 (PA‐6) organoclay nanocomposites were prepared by melt processing using three different twin screw extruders (TSEs). The effect of mixing conditions, feed port location, residence time, and number of extrusion passes on the morphology and mechanical properties of the nanocomposites were examined. Wide…
Abstract In this study, the flammability characterization and synergistic effects of different particle size of expandable graphite (EG) with modified magnesium hydroxide (MH) in flame‐retardant polypropylene (PP) composites were studied by limiting oxygen index (LOI), UL‐94 test, thermogravimetric analysis (TGA), and…
We study the thermodynamics of a binary hard-disk mixture in which the ratio of disk diameters is kappa=1.4. We use a recently developed molecular dynamics algorithm to calculate the free-volume entropy of glassy configurations and obtain the configurational entropy (degeneracy) of the supercompressed liquid as a func…
Abstract Carbon nanotube (CNT)‐reinforced poly(ethylene 2,6‐naphthalate) (PEN) nanocomposites were prepared by direct melt blending process in a twin‐screw extruder. There is significant dependence of the crystallization and melting behavior of PEN/CNT nanocomposites on CNT content and crystallization temperature. The…
Grafting of flax fiber with binary vinyl monomer mixtures such as methylmethacrylate (MMA)/ethyl acrylate (EA), MMA/acrylonitrile (AN), and MMA/acrylic acid (AA) was carried out. At a pressure of 8 Kg/cm2 under optimum reaction conditions 41.74% grafting resulted. Maximum grafting (109.9%) was found with MMA + EA bina…
In this paper, we study the effect of cotton wastes and different spinning parameters on the rotor yarn quality. Statistical models are established to predict a total quality index and the optimum spinning conditions by using maximum cotton waste rate. The results indicate that rotor parameters (diameter, form and spe…
Abstract The dependence of optical transition energies in single‐walled carbon nanotubes (SWNTs) on environmental dielectric constant ( ε env ) have been investigated in the range of ε env from 1.0 to 37, by immersing SWNTs bridged overtrenches in various organic solvents by means of photoluminescence (PL) and the exc…
The three-dimensional motion of single colloidal particles close to a plane wall is measured by optical microscopy. In accordance with classical theoretical predictions, we find an asymmetric motion of the particles in the directions parallel and perpendicular to the wall. We also find that, close to the wall, the dis…
Dynamic mechanical analysis, DMA, is an adequate technique for characterizing the mechanical features of biomaterials, as one can use test conditions that can more closely simulate the physiological environments in which they are going to be applied. In this work it was possible to perform different tests on chitosan…
Abstract Transparent and conductive patterns of carboxyl functionalized single‐walled carbon nanotubes (SWCNT‐COOHs) and the composites of those with poly(3,4‐ethylenedioxythiophene)‐poly(styrenesulfonate) (PEDOT‐PSS) were deposited on various substrates by inkjet printing. For low print repetitions, the PEDOT‐PSS/SWC…
OBJECTIVE: Nephrogenic systemic fibrosis (NSF) is a rapidly progressive, debilitating condition that causes cutaneous and visceral fibrosis in patients with renal failure. Little is known about its prevalence or etiology. The aim of this study was to establish the prevalence of NSF and associated risk factors METHODS:…
The effective atomic numbers ( Z eff ) and effective electron density ( N e ) for Fe–Mn alloy with different Mn contents are calculated using the mass attenuation coefficients μ/ρ obtained via XCOM in the photon energy range of 1 keV–1 GeV. The results are compared with the values measured at the photon energy of 662,…
BCN nanotube brushes have been obtained by the high temperature reaction of amorphous carbon nanotube (a-CNT) brushes with a mixture of boric acid and urea. The a-CNT brushes themselves were obtained by the pyrolysis of glucose in a polycarbonate membrane. The BCN nanotubes have been characterized by EELS, XPS, electr…
Abstract Wheat starch‐Cloisite Na+ nanoclay composites containing different glycerol and nanoclay concentrations were extruded using a twin‐screw extruder. X‐ray diffraction and transmission electron microscopy were used to determine the extent of nanoclay dispersion and thermogravimetric analysis was used to characte…
Thiol stabilized CdTe quantum dots (QDs) synthesized in aqueous phase were used as energy donors to aluminium tetrasulfonated phthalocyanine (AlTSPc) through fluorescence resonance energy transfer (FRET). Energy transfer occurred from the QDs to AlTSPc upon photoexcitation of the QDs. An enhancement in efficiency of e…
The structure and chemical ordering of CoPt nanoclusters in the size range of 1 to 3 nm are investigated by global optimization methods and Monte Carlo simulations using a many body potential derived from the tight binding model. For the smaller systems (number of atoms N < 100), the optimized clusters display a polyi…
Half-metallic ferromagnets and especially the full-Heusler alloys containing Co are at the center of scientific research due to their potential applications in spintronics. For realistic devices it is important to control accurately the creation of defects in these alloys. We review some of our late results on the rol…
An expression for the microwave power generated by a spin-torque oscillator in the presence of thermal noise is derived. This expression, when used in a subcritical regime, demonstrates that generated power is determined by the noise level and provides a simple way to experimentally determine the threshold current for…