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Structure determination of sodium nitrate near the order-disorder phase transition

J. Lefebvre、R. Fouret、C.M.E. Zeyen1984-01-01Journal de physique

Two models are proposed to solve the sodium nitrate structure near the order-disorder phase transition (Tc = 276 °C). The first model is built with the static disorder assumption between the two equilibrium positions of NO-3 ions. In this case, disorder is characterized by an order parameter : η. For the second model,…

Nonlinear Optical Materials ResearchSpectroscopy and Quantum Chemical StudiesSolid-state spectroscopy and crystallography

Subtidal Benthic Diatoms from a Stratified Estuarine Basin

Diana M Kennett、Paul E. Hargraves1984-01-01Botanica Marina

Fifty-six of the more abundant estuarine epipelic diatoms are described from surface sediment samples collected from the upper basin of the Pettaquamscutt River, Rhode Island. Biraphid diatoms are the dominant primary producers on the muddy sediment under 2 to 7 m water. Three families are represented (Navicula-ceae,…

Aquatic Ecosystems and Phytoplankton DynamicsMarine Biology and Ecology ResearchDiatoms and Algae Research

Struktur und Kristallchemie von Ba2M(B3O6)2mit M = Ca, Cd, Mg, Co und Ni

J. Liebertz、Roland Fröhlich1984-01-01Zeitschrift für Kristallographie

Description de la structure cristalline de Ba 2 Ca(B 3 O 6 ) 2 qui cristallise dans le groupe d'espace R3 avec a=7,165, c=17,680 A, Z=3. Relations structurales se rapprochant davantage de la forme β haute temperature que de la forme α basse temperature de Ba 13 ZO 4 . Composes isotypiques obtenus pour Cd, Mg, Co et Ni…

Crystal Structures and PropertiesNuclear materials and radiation effectsX-ray Diffraction in Crystallography

Precipitation of M23C6 and .SIGMA.-phase in .DELTA./.GAMMA. duplex stainless steels.

Yasuya Ohmori、Yasuhiro Maehara1984-01-01Transactions of the Iron and Steel Institute of Japan

Precipitation of M23C6 and σ-phase during isothermal aging of δ/γ duplex stainless steels has been studied mainly by means of transmission electron microscope coupled with energy dispersive X-ray analyser. M23C6 particles form at both γ/γ and γ/δ boundaries. The particles are crystallo-graphically related to either on…

Corrosion Behavior and InhibitionMicrostructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metals

Magnetic interactions in Tm6Fe23and its hydride as studied by means of169Tm and57Fe Mossbauer spectroscopy

P.C.M. Gubbens、A. M. van der Kraan、K.H.J. Buschow1984-01-01Journal of Physics F Metal Physics

The crystallographic and magnetic properties of Tm 6 Fe 23 before and after hydrogen absorption were studied by means of X-ray diffraction, bulk magnetic measurements and 169 Tm and 57 Fe Mossbauer spectroscopy. The data were analysed in terms of a mean-field model. Coupling constants describing the magnetic interacti…

Rare-earth and actinide compoundsHydrogen Storage and MaterialsMagnetic Properties of Alloys

Interactions of aqueous 7 F and 5 D 1 europium(III) ions with bromide and inner-sphere coordination exciplex formation

M.D. Marcantonatos、M. Deschaux、Jean-Jacques Vuilleumier1984-01-01Journal of the Chemical Society Faraday Transactions 2 Molecular and Chemical Physics

The study of the europium(III) ion + water + bromide system shows totally outer-sphere interactions between the anion and the ground-state 7F octa-(E8) and nona-(E9) hydrated europium species. An appropriate analysis of these interactions, involving the corresponding (E8B) and (E9B) outer-sphere bromocomplexes or any…

Magnetism in coordination complexesPhotochemistry and Electron Transfer StudiesLanthanide and Transition Metal Complexes

Exciton Transitions in Indium Halides

Masashi Yoshida、Nobuhito Ohno、Hideo Watanabe 等 5 位作者1984-01-01Journal of the Physical Society of Japan

Reflection, absorption and emission spectra of InBr, InI and InBr 1- x I x mixed crystals have been measured at 2 K by using polarized light. In InBr, a prominent exciton peak is found at 2.48 eV for the polarization E // b , which is on the high energy side of the lowest direct exciton peak at 2.33 eV allowed for E /…

Semiconductor Quantum Structures and DevicesAdvanced Semiconductor Detectors and MaterialsElectron and X-Ray Spectroscopy Techniques

CSF GABA levels in Parkinson's disease.

Pieter J. de Jong、J.P.W.F. Lakke、A.W. Teelken1984-01-01PubMed

CSF levels of GABA were investigated in a group of Parkinson patients without drug treatment and a group of Parkinson patients under treatment with L-DOPA or anticholinergics. Probenecid results in an elevation of CSF GABA levels in healthy persons. The results indicate a significant decrease of GABA levels in CSF in…

Conducting polymers and applications

Viscoelastic properties of a homologous series of nematic liquid crystalline Schiff's bases

J.P. van der Meulen、R.J.J. Zijlstra1984-01-01Journal de physique

Experimental values are reported for the distortion viscoelastic and elastic ratios for a homologous series of nematic Schiff's bases : APAPAm (m = 1-5, 9) and OHMBBA as a function of temperature. In the experiments the homodyne photoelectric self-beat technique was used to detect noise intensity spectra and to determ…

Liquid Crystal Research AdvancementsPhotochemistry and Electron Transfer StudiesMolecular spectroscopy and chirality

A single-crystal investigation of the solid solution NiB48.5ofβ-rhombohedral boron type structure

Torsten Lundström、Lars-Erik Tergenius、Iwami Higashi1984-01-01Zeitschrift für Kristallographie

A solid solution of nickel in β -rhombohedral boron of composition NiB 48.5 has been investigated using X-ray single-crystal diffractometry. The space group is R [unk] m (No. 166) and the hexagonal unit cell dimensions a = 10.9615(5) Å and c = 23.8544(7) Å. The boron atoms occupy 16 atomic positions, of which two are…

Rare-earth and actinide compoundsBoron and Carbon Nanomaterials ResearchMuon and positron interactions and applications

Crystal growth of PbTe and (Pb, Sn)Te by the bridgman method and by THM

P. Gille、Manfred Mühlberg、L. Parthier 等 4 位作者1984-01-01Crystal Research and Technology

Abstract Synthesis and growth of PbTe and (Pb, Sn)Te single crystals by the Bridgman method and by the Travelling Heater Method (THM) from Te‐rich solutions are described. It is to be seen from comparative investigations that seeded THM growth reproducibly provides oriented single‐crystalline ingots free of low‐angle…

Chalcogenide Semiconductor Thin FilmsSolidification and crystal growth phenomenaAdvanced Semiconductor Detectors and Materials

The photoreversible oxidative-addition, reductive-elimination reactions Fe+H2⇄FeH2 in low-temperature matrices

Geoffrey A. Ozin、John G. McCaffrey1984-01-01The Journal of Physical Chemistry

Par photo-excitation a 307 nm d'atomes Fe dans H 2 en matrice de Xe a 12 K, insertion de Fe dans H-H et formation de FeH 2 . La reaction de photo-insertion Fe+H 2 →FeH 2 peut etre suivie a l'echelle microscopique par la photoreaction inverse a 440 nm FeH 2 →Fe+H 2 a 12 K selon un processus d'elimination reductive non…

Catalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen ReductionSurface Chemistry and Catalysis

The renfinement of the structure of synthetic kalsilite.

Y. ANDOU、Akira Kawahara1984-01-01Mineralogical Journal

Several crystals of kalsilite were synthesized and the structural refinement was carried out to elucidate the structural detail of the pure end-member of the KAlSiO4. The crystal is hexagonal, P63, with a=5,151(5) and c=8.690(8)Å. The structure was refined by the full-matrix least-squares method on the basis of counte…

Zeolite Catalysis and SynthesisCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Biphenylene end-capped polyquinoline and polyimide prepolymers as matrix resins for high-use-temperature composites

John P. Droske、J. K. Stille、William B. Alston1984-01-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBiphenylene end-capped polyquinoline and polyimide prepolymers as matrix resins for high-use-temperature compositesJohn P. Droske, John K. Stille, and William B. AlstonCite this: Macromolecules 1984, 17, 1, 14–18Publication Date (Print):January 1, 1984Publication History Pub…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Mechanics of Muco-ciliary Transport

J. R. Blake1984-01-01IMA Journal of Applied Mathematics

A cilia sublayer model of mucous transport in the lung is developed by considering a two-layer model of the fluid. Both the lower peri-ciliary layer and the upper mucous layer are modelled by Newtonian fluids. Cilia are allowed limited penetration into the more viscous upper layer during the effective stroke, otherwis…

Pickering emulsions and particle stabilization

Herstellung und Struktur von (η6-Hexamethyl-benzol)gallium(I)-tetrabromogallat(III): π-Komplex undnido-Cluster

Hubert Schmidbaur、Ulf Thewalt、T.F. Zafiropoulos1984-01-01Angewandte Chemie

Die ersten Monoarenkomplexe von Gallium(I) wurden aus Ga2X4 (X = Cl, Br), in Toluol suspendiert, und Hexamethylbenzol erhalten. In 1b sind C-1 und C-4 des Arenliganden zum GaI hin verschoben: 1b kann somit sowohl als π-Komplex als auch als nido-Cluster angesehen werden.

Fungal Infections and StudiesSilicone and Siloxane ChemistryGa2O3 and related materials

Stress Corrosion Cracking of 18 Ni Maraging Steel in Chloride Solutions

I.H. Craig、R. N. Parkins1984-01-01British Corrosion Journal

A variety of techniques involving electrochemical, hydrogen permeation and acoustic emission measurements have been used in studying the stress corrosion cracking of initially smooth and pre-cracked specimens of a maraging steel in different chloride-containing solutions. In solutions having pH's in excess of 2, crack…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Interreaction Between Al 2 O 3 and a CaO‐Al 2 O 3 Melt

Lutgard C. De Jonghe、Herbert Schmid、Mei Chang1984-01-01Journal of the American Ceramic Society

Poly crystalline and single‐crystalline α‐alumina were reacted with a eutectic CaO‐Al 2 O 3 melt at 1530°C. A reaction zone develops in which a strongly textured CA 6 layer, as well as a CA 2 layer, forms, with a remaining layer of unreacted CaO‐AI 2 O 3 melt. Silica, an impurity in the α‐alumina, is rejected by the a…

Advanced ceramic materials synthesisGlass properties and applicationsAluminum Alloys Composites Properties

Strength and toughness of T42 high-speed steel

Christopher S. Wright、A. S. Wronski、M. M. Rebbeek1984-01-01Metals Technology

Hardness and compressive strength, Young's modulus, bend strength, and fracture toughness were measured in wrought and commercially sintered T42 high-speed steel. After identical heat treatments, no significant differences were found between wrought and sintered materials in hardness (800–1010 HV50), Young's modulus (…

Microstructure and Mechanical Properties of SteelsMetal Alloys Wear and PropertiesPowder Metallurgy Techniques and Materials