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Novel Superstructure of Nondiscoid Mesogens: Uneven-Parallel Association of Half-Disk Molecules, 3,4,5-Trialkoxybenzoic Anhydrides, to a Columnar Structure and Its One-Directionally Geared Interdigitation

Keiki Kishikawa、Shigetaka Furusawa、T. Yamaki 等 6 位作者2002-02-01Journal of the American Chemical Society

Compact and simple nondiscoid mesogens, trialkoxybenzoic anhydrides 2-11 ((RO)(3)C(6)H(2)-CO-O-CO-C(6)H(2)(OR)(3), R = C(2)H(5), n-C(3)H(7), n-C(4)H(9), n-C(6)H(13), n-C(8)H(17), n-C(10)H(21), n-C(12)H(25), n-C(14)H(29), n-C(16)H(33), and (S)- and (R)-3,7-dimethyloctyl) were designed and synthesized, and their superst…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Liposomal doxorubicin in conjunction with reirradiation and local hyperthermia treatment in recurrent breast cancer: a phase I/II trial.

Vassilis Kouloulias、Costas E. Dardoufas、John Kouvaris 等 10 位作者2002-02-01PubMed

PURPOSE: This is the first study to evaluate the tolerability and activity of liposomal doxorubicin (Caelyx; Schering-Plough Pharmaceuticals) < or =60 mg/km(2) in patients with locally recurrent breast cancer, when administered in conjunction with reirradiation and local hyperthermia treatment. EXPERIMENTAL DESIGN: Fi…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsUltrasound and Hyperthermia Applications

Refinement of the crystal structures of Cu3PS4and Cu3SbS4and a comment on normal tetrahedral structures

Arno Pfitzner、Sara Reiser2002-02-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract The crystal structures of yellow Cu 3 PS 4 and of black Cu 3 SbS 4 were refined from single crystal X-ray diffraction data. Cu 3 PS 4 crystallizes orthorhombic in an ordered wurtzite superstructure type with the space group Pmn 2 1 (no. 31), a = 7.282(1) Å, b = 6.339(1) Å, c = 6.075(1) Å, V = 280.38(8) Å 3 ,…

Crystal Structures and PropertiesAdvanced Condensed Matter PhysicsIron-based superconductors research

Continuum Limits of Discrete Systems without Convexity Hypotheses

Andrea Braides、Maria Stella Gelli2002-02-01Mathematics and Mechanics of Solids

We describe the variational limit of one-dimensional nearest-neighbour systems of interactions, under no structure hypotheses on the discrete energy densities. We show that the continuum limit is characterized by a bulk and a interfacial energy density, which can be explicitly computed from the discrete energies throu…

Numerical methods in engineeringComposite Material MechanicsNonlocal and gradient elasticity in micro/nano structures

Hybrid Polyamide/Silica Nanocomposites: Synthesis and Mechanical Testing

Werner E. van Zyl、Monserrat Garcı́a、Bernard A. G. Schrauwen 等 6 位作者2002-02-01Macromolecular Materials and Engineering

A hybrid inorganic-polymer composite was formed through nanosize silica filler particles (< 30 nm) that were incorporated inside a nylon-6 matrix. The composite was microtomed and examined with TEM which revealed that the silica particles were well dispersed and non-aggregated. Optimization of the synthesis conditions…

Polymer Nanocomposites and PropertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

Appearance of n-Type Semiconducting Properties of cBN Single Crystals Grown at High Pressure

Takashi Taniguchi、Tokuyuki Teraji、Satoshi Koizumi 等 5 位作者2002-02-01Japanese Journal of Applied Physics

Semiconducting properties of two types of cubic boron nitride (cBN) single crystals prepared at high pressure and high temperature were evaluated by Hall measurement. Sulfur was intentionally doped in one type as a donor and the other type contained no intentional dopants. Both crystals exhibit n-type conduction. Sulf…

Graphene research and applicationsDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Sandia Octahedral Molecular Sieves (SOMS): Structural and Property Effects of Charge-Balancing the MIV-Substituted (M = Ti, Zr) Niobate Framework

May Nyman、Akhilesh Tripathi、John B. Parise 等 5 位作者2002-02-01Journal of the American Chemical Society

Sandia octahedral molecular sieves (SOMS) is an isostructural, variable composition class of ion exchangers with the general formula Na(2)Nb(2-x)M(IV)(x)O (6-x)(OH)(x).H(2)O (M(IV) = Ti, Zr; x = 0.04-0.40) where up to 20% of the framework Nb(V) can be substituted with Ti(IV) or Zr(IV). This class of molecular sieves i…

Ferroelectric and Piezoelectric MaterialsCrystal Structures and PropertiesElectronic and Structural Properties of Oxides

Size effect on the thermal conductivity of nanowires

Xiang Lü、Wei Shen、Junhao Chu2002-02-01Journal of Applied Physics

The size effect on thermal conductivity of a free-standing wire with rectangular cross-section is investigated. The electronic thermal conductivity is calculated within a Boltzmann transport equation approach. A simple expression for the reduction in conductivity due to the increase of boundary scattering is presented…

Nanowire Synthesis and ApplicationsThermal properties of materialsAdhesion, Friction, and Surface Interactions

Analyzing Structural and Physical Properties of Ring, Rotor, and Friction Spun Yarns

You Huh、Young Ryul Kim、William Oxenham2002-02-01Textile Research Journal

This research is a comparative study of the structural and physical properties of ring, rotor, and friction spun yams and an attempt to explain the differences in their physical properties on the basis of yam structure. Results show that the ring spun yam exhibits the highest fiber migration, followed by rotor spun ya…

Natural Fiber Reinforced CompositesTextile materials and evaluationsStructural Analysis and Optimization

Polymer−Silica Hybrid Monolayers as Precursors for Ultrathin Free-Standing Porous Membranes

Hui Xu、Werner A. Goedel2002-02-01Langmuir

Forty-nanometer-thin free-standing membranes with 55-nm-wide pores have been prepared via Langmuir−Blodgett transfer. Hydrophobized silica colloids and polyisoprenes with quaternary ammonium headgroups were jointly spread onto a water surface to form a hybrid monolayer in which two-dimensional ordered domains of parti…

Photonic Crystals and ApplicationsMesoporous Materials and CatalysisPolymer Surface Interaction Studies

Significance of the Formation of Calcium Carbonate Minerals in the Pedogenesis and Management of Cracking Clay Soils (Vertisols) of India

Pankaj Srivastava、T. Bhattacharyya、Dilip Kumar Pal2002-02-01Clays and Clay Minerals

Abstract Micromorphological studies were performed in order to understand the factors and processes involved in the formation of calcium carbonate (CaCO 3 ) in twenty three soil series of Vertisols representing sub-humid, semi-arid and arid climatic regions of Peninsular India. The study indicates that Vertisols conta…

Geology and Paleoclimatology ResearchSoil and Unsaturated FlowClay minerals and soil interactions

Synthesis and spectroscopic characterization of Ni, Zn, Pd and Pt tetra(pentafluorophenyl)porpholactone with comparisons to Mg, Zn, Y, Pd and Pt metal complexes of tetra(pentafluorophenyl)porphine

Gamal Khalil、Martin Gouterman、Stephen Ching 等 11 位作者2002-02-01Journal of Porphyrins and Phthalocyanines

Ni , Zn , Pd and Pt tetra(pentafluorophenyl)porpholactone (TFPL) were synthesized and identified by their optical and mass spectra. The lactone ring was produced from the parent free-base porphyrin using silver nitrate and oxalic acid with a yield of 73%, and the metals were inserted by standard procedures from metal…

Porphyrin and Phthalocyanine ChemistryPhotodynamic Therapy Research StudiesPhotochemistry and Electron Transfer Studies

Optical absorption and photoluminescence studies on CdS quantum dots in Nafion

P. Nandakumar、C. Vijayan、Y. V. G. S. Murti2002-02-01Journal of Applied Physics

Excitonic effects are observed in the optical absorption and photoluminescence of strongly confined CdS quantum dots embedded in the polymer Nafion. The three bands identified in the optical absorption spectra could be attributed to 1se-1sh, 1pe-1ph, and 2se-2sh transitions of the noninteracting particle model. Photol…

Perovskite Materials and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Hall–Petch behaviour of 316L austenitic stainless steel at room temperature

K. K. Singh、S. Sangal、G. S. Murty2002-02-01Materials Science and Technology

The room temperature plastic deformation behaviour of two different batches (with differences in chemical composition) of 316L austenitic stainless steel has been studied. By thermomechanical treatments, a wide range of grain sizes varying from 2·7 to 64·0 νm was obtained in this study. The different microstructural p…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsHigh Temperature Alloys and Creep

Real time resistivity measurements during sputter deposition of ultrathin copper films

E. V. Barnat、D. Nagakura、P.-I. Wang 等 4 位作者2002-02-01Journal of Applied Physics

Measurements of the electrical resistivity of thin copper films sputtered onto silicon dioxide, in real time, are reported. The electrical resistivity is shown to strongly depend on the film’s thickness for thicknesses below the bulk mean free path of copper (39 nm). Model fits to the electrical resistivity combined w…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Plasticization of soy protein polymer by polyol‐based plasticizers

Xiaoqun Mo、Xiuzhi Susan Sun2002-02-01Journal of the American Oil Chemists Society

Abstract Soy protein isolate (SPI) was mixed with four polyol‐based plasticizers and molded into plastics using a hot press. The plasticized SPI powder was evaluated for denaturation temperatures and denaturation enthalpies. The SPI plastics were studied for mechanical properties, glass transition temperatures, storag…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced Compositesbiodegradable polymer synthesis and properties

Crystalline phase and orientation control of manganese nitride grown on MgO(001) by molecular beam epitaxy

Haiqiang Yang、Hamad Albrithen、Eugen M. Trifan 等 5 位作者2002-02-01Journal of Applied Physics

The phase and orientation of manganese nitride grown on MgO(001) using molecular beam epitaxy are shown to be controllable by the manganese/nitrogen flux ratio as well as the substrate temperature. The most N-rich phase, θ phase (MnN), is obtained at very low Mn/N flux ratio. At increased Mn/N flux ratio, the next mos…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Physical characterization and diel dynamics of different fractions of extracellular polysaccharides in an axenic culture of a benthic diatom

J.F.C. de Brouwer、K. Wolfstein、Lucas J. Stal2002-02-01European Journal of Phycology

The excretion of extracellular polymeric substances (EPS) by an axenic culture of the benthic diatom Cylindrotheca closterium was investigated. Two sequential extraction steps proved to be sufficient to remove the bulk of the EPS present. Soluble EPS was recovered by a simple centrifugation step and represented a frac…

Aquatic Ecosystems and Phytoplankton DynamicsWastewater Treatment and Nitrogen RemovalDiatoms and Algae Research

XPEEM WITH ENERGY-FILTERING: ADVANTAGES AND FIRST RESULTS FROM THE SMART PROJECT

Thomas Schmidt、U. Groh、R. Fink 等 18 位作者2002-02-01Surface Review and Letters

The second development step of the SMART project, i.e. an energy-filtered but not yet corrected photoelectron emission microscope, operates at the undulator U49/1-PGM beamline at BESSY II. It already demonstrates the variety of methods of the final version: microscopy, spectroscopy and electron diffraction. Some recen…

Advancements in Photolithography TechniquesElectron and X-Ray Spectroscopy TechniquesPhotocathodes and Microchannel Plates

A Chiral Lead Borate Containing Infinite and Finite Chains Built up from BO4 and BO3 Units

Zhen‐Tao Yu、Zhan Shi、Yusheng Jiang 等 5 位作者2002-02-01Chemistry of Materials

With a hydrothermal technique, a novel chiral lead borate (Pb 6 B 11 O 18 (OH) 9 ) has been prepared. The sample has been characterized by powder X-ray diffraction, infrared spectroscopy, energy-dispersive spectroscopy, thermal analysis, and second-harmonic generation powder measurement. The structure of the compound,…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyX-ray Diffraction in Crystallography