Materials Literature
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Abstract Poly[2,7-(9-oxo-9-phosphafluorenylene)-alt-co-(1,4-arylene)]s, readily prepared from 2,7-dibromo-9-oxo-9-phosphafluorenes and arylene bisboronates, behaved as extended π-conjugated polymers in the UV–vis absorption spectroscopy and displayed green-blue fluorescence with high quantum yields. Cyclic voltammetry…
Au nanoparticles exhibit excellent compatibility with biomolecules and some distinct optical properties. Their two popular features, the color change upon aggregation and surface plasmon resonance (SPR) enhancement, have been exploited in analytical chemistry, biosensing platforms, and immunoassays. The preparation of…
Abstract Es wurden fünf Chalcogeno‐Hypodiphosphate dargestellt und röntgenographisch mit Einkristallmethoden charakterisiert. Mg 2 P 2 S 6 ( C 2/ m ; a = 6, 085(1), b = 10, 560(2), c = 6, 835(1)Å, β = 106, 97(3)°; Z = 2) kristallisiert im Fe 2 P 2 S 6 ‐Typ, während Mg 2 P 2 Se 6 ( a = 6, 404(1), c = 20, 194(4)Å) und Z…
We find, from first principles calculations, that an oxygen (anion) vacancy in ${\mathrm{WO}}_{3}$ not only generates a donorlike state near the fundamental band gap, derived from the top valence bands, but also gives rise to an additional pair of defect states: a hyper-deep resonant state in the valence band and a hi…
Abstract Schwarze, plättchenförmige Kristalle von M BiSCl 2 ( M = Cu, Ag)werden durch thermische Umsetzung äquimolarer Gemenge von M Cl und BiSCl erhalten. Aus Röntgenbeugungsuntersuchungen an Pulvern und Einkristallen geht hervor, dass die Verbindungen isotyp im Raumgruppentyp Cmcm kristallisieren ( M = Cu/Ag: a = 39…
${\mathrm{UO}}_{2}$ single crystals with a size of around $1{\mathrm{cm}}^{3}$ are created in a process involving a period of spectacular grain growth. (111) cleavage cross sections through these crystals expose voids that are typically of \ensuremath{\mu}m dimensions. Low voltage scanning electron microscopy of the v…
The remarkable properties of carbon nanotubes give promise of a diverse array of revolutionary technologies and applications. Synthesis remains the key to their development. This article will review many of the current methods used for nanotube synthesis and the recent results towards achieving the goal of large-scale…
Abstract We prepared novel pyrene-fused porphyrins via the oxidative intramolecular ring closure reactions of meso-pyrenylporphyrin. The excitation energies and the oxidation potentials of the isolated dark-colored pyrene-fused porphyrins were significantly low compared with those of the corresponding precursors.
The most significant structural feature of the A -site ordered manganese perovskites, R BaMn 2 O 6 , is that the MnO 2 square sublattice is sandwiched by two types of rock-salt layers, R O and BaO, with much different sizes and consequently the MnO 6 octahedron itself is distorted in a noncetrosymmetric manner. The st…
This paper presents improvements on a previously reported method for the measurement of elements in breast tissue specimens (Geraki et al 2002 Phys. Med. Biol. 47 2327-39). A synchrotron-based system was used for the detection of the x-ray fluorescence (XRF) emitted from iron, copper, zinc and potassium in breast tiss…
The photoinduced alignment of a liquid crystal (LC) on films of azo dyes was studied for the liquid crystal display applications. In order to improve the alignment stability of the photoaligned dye (SD-1), the azo-dye derivative with polymerizable terminal groups was synthesized (SDA-1). The films of SDA-1 exhibit goo…
We present the results of measurements of the dc-magnetic susceptibility chi(T) and the 23Na-NMR response of Na_{0.70}CoO_{2} at temperatures between 50 and 340 K. The chi(T) data suggest that for T > 75 K, the Co ions adopt an effective configuration of Co^{3.4+}. The 23Na-NMR response reveals pronounced anomalies ne…
We strongly disagree with a number of statements by Dolin{š}ek et al. about phason dynamics in quasicrystals (QCs).
The charge-carrier transport properties of ultrathin metallic films are analysed with ab-initio methods using the density functional theory (DFT) on free-standing single crystalline slabs in the thickness range between 1 and 8 monolayers and compared with experiments for Pb films on Si(111). A strong interplay between…
In this work, a finite-difference time-domain (FDTD) method is employed to justify the superlensing effect of left-handed material (LHM) slabs. Our results demonstrate that subwavelength resolution can be achieved by LHM slabs with certain parameters. We present the dynamic feature of the imaging process and the depen…
It was observed that the polyurethane shape memory polymer (SMP) loses its shape fixing capability after being exposed in the air at room temperature for several days. A significant indication for this change is the continuous decrease of the glass transition temperature ( T g ) of polyurethane. Accompanying the decre…
PURPOSE: To compare the in vivo tissue distribution of folate-targeted liposomes (FTLs) injected i.v. in mice bearing folate receptor (FR)-overexpressing tumors (mouse M109 and human KB carcinomas, and mouse J6456 lymphoma) to that of nontargeted liposomes (NTLs) of similar composition. EXPERIMENTAL DESIGN: A small fr…
Abstract The in vitro biodegradation of Bombyx mori silk fibroin was studied by incubating fibers and films with proteolytic enzymes (collagenase type F, α‐chymotrypsin type I‐S, protease type XXI), for times ranging from 1 to 17 days. The changes in sample weight and degree of polymerization of silk fibers exposed to…
We present a numerical study of the electromagnetic response of the metamaterial elements that are used to construct materials with negative refractive index. For an array of split ring resonators (SRR) we find that the resonant behavior of the effective magnetic permeability is accompanied by an antiresonant behavior…
Polymeric micelles incorporating cisplatin (CDDP) were prepared through the polymer-metal complex formation between CDDP and poly(ethylene glycol)-poly(glutamic acid) block copolymers, and their utility as a tumor-targeted drug delivery system was investigated. CDDP-incorporated micelles (CDDP/m) had a size of 28 nm w…