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Neutral bis(1,4-diaza-1,3-butadiene)nickel complexes and their corresponding monocations: molecular and electronic structures. A combined experimental and density functional theoretical study

N. Muresan、Thomas Weyhermüller、Karl Wieghardt2007-01-01Dalton Transactions

The reaction of 2 equivalents of 2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene, ((1)L(Ox))(0), or 2-methyl-1,4-bis(2,6-diisopropylphenyl)-1,4-diaza-1,3-butadiene, ((2)L(Ox))(0), in diethyl ether or n-hexane with 1 equivalent of Ni(cdt) where (cdt)(0) is the ligand cyclododecatriene affords dark red, dia…

Organometallic Complex Synthesis and CatalysisMetal complexes synthesis and propertiesMagnetism in coordination complexes

Effect of thermal evaporation rate on the basic physical properties of glassy (As2S3) x (As2Se3)1−x films

T.I. Goglidze、I V Dement'ev、В. М. Ишимов 等 4 位作者2007-01-01Inorganic Materials

We have studied the effect of thermal evaporation rate on the basic physical properties of glassy (As2S3) x (As2Se3)1−x thin films on glass substrates and have determined the optimal range of deposition rates corresponding to the highest photosensitivity and long-term stability of the films. The results are interprete…

Glass properties and applicationsChalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenides

Mechanochemical Synthesis of Zinc Ferrite, ZnFe<sub>2</sub>O<sub>4</sub>

Yutaka Sawada、Kiyokata Iizumi、Tomokazu Kuramochi 等 9 位作者2007-01-01Materials science forum

Mechanochemical synthesis of zinc ferrite, ZnFe2O4, was attempted from a powder mixture of iron (III) oxide, alpha-Fe2O3 and zinc (II) oxide, ZnO. Nanocrystalline zinc ferrite, ZnFe2O4 powders were successfully synthesized only by milling for 30 hours. The X-ray diffraction spectrum of the as-milled powders (without h…

Magnetic Properties and Synthesis of FerritesIron oxide chemistry and applicationsMagneto-Optical Properties and Applications

Antireflection coating for two-dimensional air hole-type photonic crystal negative refraction slab lens

Bo Zhang、Wang Zhi、(1)北京交通大学电子信息工程学院国家电工电子教学基地,北京 100044; (2)北京交通大学理学院光信息科学与技术研究所,北京 1000442007-01-01Acta Physica Sinica

We propose and optimize the antireflection coating composed of a row of tapered dielectric waveguides for two-dimensional air hole-type photonic crystal negative refraction slab lens. The image quality of the lens with the antireflection coating is improved. The simulation result using finite difference time domain me…

Photonic Crystals and ApplicationsOptical Coatings and Gratings

Numerical simulation of the dynamic interactions between dislocation and solute atoms

Huifeng Jiang、Qingchuan Zhang、Xuedong Chen 等 7 位作者2007-01-01Acta Physica Sinica

Using the Cottrell-Bilby kinetics model for solute atoms, evolution of the solute concentration around dislocation line has been investigated with respect to the strain rate. Three types of interactions between dislocation and solutes were obtained: At low strain rates, the dislocation is effectively pinned by its con…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsAdvanced materials and composites

Influence of Ti on Inclusion Formation of Reduced Activation Ferritic/Martensitic Steels

Atsushi Sawahata、Hiroyasu Tanigawa、Kiyoyuki Shiba 等 4 位作者2007-01-01Journal of the Japan Institute of Metals and Materials

Reduced activation ferritic/martensitic steels (RAFs), such as F82H (Fe-8Cr-2W-0.2V-0.04Ta-0.1C), are the leading candidates for structural materials of fusion reactors, and it is essential for the development of RAFs to assure its good for fusion application. In this study, the influence of Ti on impact property was…

Microstructure and Mechanical Properties of SteelsFusion materials and technologiesNuclear Materials and Properties

Influence of Some Chemical Admixtures on Growth Behavior of Ettringite from Aqueous Solution

Koji Makida、Keita Kunimitsu、Ryuichi Komatsu2007-01-01Transactions of the Materials Research Society of Japan

The growth of ettringite crystal by combining calcium hydroxide and aluminum sulfate solutions including some admixtures have been investigated using the microscope with high magnifications up to 3000 degrees. The nucleation, growth rate and morphology of ettringite were observed to clear the effect of admixtures.

Calcium Carbonate Crystallization and InhibitionCrystallization and Solubility StudiesMaterial Selection and Properties

Thermochemical Properties and Decomposition Kinetics of Ammonium Magnesium Phosphate Monohydrate

Jian Wu、Aiqun Yuan、Zaiyin Huang 等 6 位作者2007-01-01Chinese Journal of Chemistry

Abstract Ammonium magnesium phosphate monohydrate NH 4 MgPO 4 ·H 2 O was prepared via solid state reaction at room temperature and characterized by XRD, FT‐IR and SEM. Thermochemical study was performed by an isoperibol solution calorimeter, non‐isothermal measurement was used in a multivariate non‐linear regression a…

Energetic Materials and CombustionThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Nonlinear Boundary Conditions in Simulations of Electrochemical Experiments Using the Boundary Element Method.

Markus Träuble、Carolina Nunes Kirchner、Günther Wittstock 等 5 位作者2007-01-01AIP conference proceedings

The use of the boundary element method (BEM) in simulating steady‐state experiments of scanning electrochemical microscopy in feedback mode and in generation‐collection mode using complex three dimensional geometries has been shown in previous papers. In the context of generation‐collection mode experiments, catalytic…

Corrosion Behavior and InhibitionForce Microscopy Techniques and ApplicationsAnodic Oxide Films and Nanostructures

Alternative fuel technologies

作者信息未提供2007-01-01Physical Chemistry Chemical Physics

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Graphite, nuclear technology, radiation studies

Effect of far field flow on the spherical crystal in the undercooled melt

Chen Ming-Wen、Zidong Wang、Sun Ren-ji 等 4 位作者2007-01-01Acta Physica Sinica

The influence on the growth morphology of the spherical crystal in the undercooled melt imposed by the far field flow is studied by the asymptotic method. It is shown that the far field flow leads to convection in the melt such that the front interface of a growing spherical crystal grows into the undercooled melt in…

Solidification and crystal growth phenomena

Development of Tungsten Heavy Alloy with Hybrid Structure for Kinetic Energy Penetrator

Woon Hyung Baek、Eun Pyo Kim、Heung Sub Song 等 9 位作者2007-01-01Materials science forum

A new tungsten heavy alloy with hybrid structure was manufactured for the kinetic energy penetrator. The tungsten heavy alloy is composed of two parts: core region is molybdenum added heavy alloy to promote the self-sharpening; outer part encompassing the core is conventional heavy alloy to sustain severe load in a mu…

Fusion materials and technologiesNuclear Materials and PropertiesHigh-Velocity Impact and Material Behavior

Thermoelectric Properties of Fe-Doped CoSb<sub>3</sub> Prepared by Encapsulated Induction Melting and Hot Pressing

Kwan Ho Park、Jung Il Lee、Soon Chul Ur 等 4 位作者2007-01-01Materials science forum

The encapsulated induction melting and hot pressing were employed to prepare the Fedoped CoSb3 skutterudites and their thermoelectric properties were investigated. Single phase δ- CoSb3 was successfully obtained by the subsequent heat treatment at 773K for 24 hours. Iron atoms acted as electron acceptors by substituti…

Advanced Thermoelectric Materials and DevicesChalcogenide Semiconductor Thin FilmsHeusler alloys: electronic and magnetic properties

Lens analysis methods for quasioptical systems

Stig B. Sørensen、K. M. Pontoppidan2007-01-01OpenAlex

The method of moments (MoM), physical optics (PO) and geometrical optics (GO) are compared for analysis of dielectric lenses. It is found that MoM can be used (with normal computers) for diameters of the lens up to 15 λ, λ being the wavelength, whereas the approximate methods PO and GO must be used at higher frequenci…

Advanced optical system designAdvanced Measurement and Metrology TechniquesOptical Coatings and Gratings

Studies on Preparation of Ti<sub>3</sub>SiC<sub>2</sub> Particulate Reinforced Cu Matrix Composite by Warm Compaction and Its Tribological Behavior

Tungwai Leo Ngai、Zhi Yu Xiao、Yuan Biao Wu 等 4 位作者2007-01-01Materials science forum

Conventional powder metallurgy processing can produce copper green compacts with density less than 8.3 g/cm3 (a relative density of 93%). Performances of these conventionally compacted materials are substantially lower than their full density counterparts. Warm compaction, which is a simple and economical forming proc…

Aluminum Alloys Composites PropertiesMXene and MAX Phase MaterialsAdvanced materials and composites

Effect of the Pore Size of Microfilters in Supercritical CO2 Bubbling on the Dissolved CO2 Concentration

Fumiyuki Kobayashi、Yasuyoshi Hayata、Norio Muto 等 4 位作者2007-01-01Food Science and Technology Research

The effect of the pore size of microfilters installed in a supercritical (SC-) CO2 bubbling device on the concentration of CO2 dissolved in the solution was investigated. Dissolved CO2 concentration in the solution treated with a microfilter was approximately 27% higher than that without a microfilter for lower CO2/sa…

Phase Equilibria and ThermodynamicsCarbon Dioxide Capture TechnologiesPolymer Foaming and Composites

Flow-induced crystallization of polybutene-1 and effect of molecular parameters

Chitiur Hadinata2007-01-01OpenAlex

There are two main goals of this thesis: to investigate the flow-induced crystallization behaviour of Polybutene-1 (PB-1 samples, and to study the effects of molecular parameters on the crystallization behaviour While flow-induced crystallization is not a

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesPolymer Foaming and Composites

Solid oxide fuel cells:development status and key technologies

Jian Li2007-01-01Gongneng cailiao yu qijian xuebao

The present paper reviews the development and current technology status of solid oxide fuel cells(SOFCs);and the materials selection,stack design,cell and stack fabrication as well as perform- ance evaluation of SOFCs are discussed in detail according to the author's understanding and experience.

Advancements in Solid Oxide Fuel Cells

Analysis of the property of the beam after spectral beam combining

Zhang Yan、Bin Zhang、Zhu Song-jun 等 4 位作者2007-01-01Acta Physica Sinica

A propagation model for spectral beam combining is set up in this paper. First, using ray tracing method, the phase change induced by the blazed grating is expressed with the optical path differences in the groove and between grooves and the calculation model for the phase change of the beam obliquely incident on the…

Advanced optical system designOptical Coatings and GratingsAdvanced Measurement and Detection Methods

Effects of Monomer Composition and Original Filler Content on Filler Loading in the Resulting Centrifuged Composites

Naomi Tanoue、Atsushi Mikami、Mitsuru Atsuta 等 4 位作者2007-01-01Dental Materials Journal

This study examined the effects of monomer composition, original filler content, and application of centrifugal force on the resulting filler loading of composites. Either Bis-MPEPP or UDMA was mixed with TEGDMA at a molar ratio of 1 : 1. Silane-treated silica (14-20 wt%) was added to each mixture. After the mixtures…

Dental materials and restorationsPolymer Nanocomposites and PropertiesAdditive Manufacturing and 3D Printing Technologies