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Hot Corrosion of Na[sub 2]SO[sub 4]-Coated Ti[sub 3]AlC[sub 2] in Air at 700-1000°C

X. H. Wang、Yanchun Zhou2004-01-01Journal of The Electrochemical Society

Hot corrosion of layered machinable ceramic coated with in air at 700-1000°C has been investigated by means of thermogravimetric analysis, X-ray diffraction, Raman spectroscopy, and scanning electron microscopy/energy-dispersive spectroscopy. The hot corrosion of was slight at low temperatures of 700 and 800°C, while…

Advanced ceramic materials synthesisIntermetallics and Advanced Alloy PropertiesMXene and MAX Phase Materials

Fundamentals of Vertical Density Profile Formation in Wood Composites. Part III. MDF Density Formation During Hot-Pressing

Siqun Wang、Paul M. Winistorfer、Timothy M. Young2004-01-01Wood and Fiber Science (Society of Wood Science and Technology)

The formation characteristics of the vertical density profile of MDF are presented herein. Results of laboratory studies indicate that the vertical density profile of MDF is formed from a combination of actions that occur both during compaction and also after the press has reached final position. The methodology, whic…

Wood Treatment and PropertiesNatural Fiber Reinforced CompositesLignin and Wood Chemistry

Dielectric properties analysis of silicone rubber

Duc‐Hai Nguyen、Alain Sylvestre、P. Gonon 等 4 位作者2004-01-01OpenAlex

Dielectric properties of silica filled silicone rubber used for high voltage insulation are studied as a function of frequency (1 mHz - 1 MHz) and temperature 213K - 433K.. Two different polarization mechanisms are identified. The frequency dependence of the dielectric constant and loss factor is well characterised by…

Liquid Crystal Research AdvancementsHigh voltage insulation and dielectric phenomenaDielectric materials and actuators

Hydrogen on Cobalt: The Effects of Carbon Monoxide and Sulphur Additives on the D2/Co(0001) System

Karin Habermehl-Cwirzen、K. Kauraala、Jouko Lahtinen2004-01-01Physica Scripta

Hydrogen reaction on catalytic surfaces is an important field of research in fuel cell science. The adsorption of hydrogen (deuterium) on Co(0001) and the influence of carbon monoxide and sulphur on the adsorption were studied by XPS, TDS, WF measurements and LEED. The WF increased due to D2 adsorption, revealing the…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysts for Methane Reforming

The remote-oxyfunctionalization of unactivated carbons in (5β)-3-oxobile acids by 2,6-dichloropyridine N-oxide catalyzed by ruthenium–porphyrin and HBr: a direct lactonization at C-20

Shoujiro Ogawa、Takashi Iida、Takaaki Goto 等 6 位作者2004-01-01Organic & Biomolecular Chemistry

Remote-oxyfunctionalization induced by 2,6-dichloropyridine N-oxide (DCP N-oxide) as an oxygen donor and a (5,10,15,20-tetramesitylporphyrinate) ruthenium(II) carbonyl complex (Ru-porphyrin) and HBr as catalysts was examined for a series of methyl ester-peracetylated derivatives of (5 beta)-3-oxobile acids. Using the…

Porphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsOxidative Organic Chemistry Reactions

Summary of ISO/TC 201 standard: XXI. ISO 21270:2004—Surface chemical analysis—X‐ray photoelectron and Auger electron spectrometers—Linearity of intensity scale

M. P. Seah2004-01-01Surface and Interface Analysis

Abstract This International Standard specifies two methods for determining the maximum count rate for an acceptable limit of divergence from linearity of the intensity scale of Auger and x‐ray photoelectron spectrometers. It also includes methods to correct for intensity non‐linearities so that a higher maximum count…

X-ray Spectroscopy and Fluorescence AnalysisNuclear Physics and ApplicationsElectron and X-Ray Spectroscopy Techniques

Theoretical Studies of the Structure of Intermediate Chiral Smectic Phases with Increasing Periodicity

A. V. Emelyanenko、M. A. Osipov2004-01-01Ferroelectrics

Different approaches to the description of the structure of intermediate chiral smectic C* phases are discussed and the concept of the “discrete” flexoelectric effect is introduced that describes a polarization induced in a smectic layer by a difference in director orientation in the two other layers adjacent to it. I…

Liquid Crystal Research AdvancementsForce Microscopy Techniques and ApplicationsAdvanced Materials and Mechanics

Investigation of in-situ Chemical Reactions of Al2O3-SiC-SiO2-C Refractory and Its Interactions with Slag

Lan Hong、Veena Sahajwalla2004-01-01ISIJ International

Experiments were carried out to investigate in-situ reactions of refractory and its interactions with slag (composition: 45.4%SiO2+36.6%CaO+15.9%Al2O3) using a horizontal furnace by detecting CO and CO2 contents in off gas with an infrared (IR) analyzer. The composition of refractory is 69.4%Al2O3+7.3%SiO2+10.6%SiC+12…

Advanced ceramic materials synthesisMetallurgical Processes and ThermodynamicsRecycling and utilization of industrial and municipal waste in materials production

Effect of nonstoichiometry on Raman scattering of VO 2 films

Yuan Hongtao、Feng Ke-cheng、Xuejin Wang 等 6 位作者2004-01-01Chinese Physics

We report on Raman scattering of VO 2 films prepared by radio frequency magnetron sputtering under different conditions. Our investigations revealed that the dominated Raman peaks shift towards high frequency for both V-rich and O-rich VO 2 films, compared with the stoichiometry VO 2 films. The experimental evidence i…

Advanced Fiber Optic SensorsGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Direct synthesis of ordered mesoporous materials constructed with polymer–silica hybrid frameworks

Yoon‐Sok Kang、Hyung Ik Lee、Ye Zhang 等 7 位作者2004-01-01Chemical Communications

Highly ordered mesoporous materials constructed with integrated polymer-silica hybrid frameworks can be obtained via a one-step synthetic strategy using a mixture of polymer and silicate as the framework sources in the presence of a structure-directing agent.

Mesoporous Materials and CatalysisPolyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and Applications

Two-dimensional molecular ordering of Os( ii ) complexes in organo-clay hybrid ultrathin films

Yasushi Umemura、Emi Shinohara2004-01-01Chemical Communications

An ordered structure of [OsL(3)](2+)(L = 2, 2'-bipyridine or 1, 10-phenanthroline) layer in an ultrathin film composed of the complex cations, clay nanosheets and alkylammonium cations is reported on the basis of its in-plane X-ray diffraction and polarized electronic spectral data.

Mesoporous Materials and CatalysisClay minerals and soil interactionsIron oxide chemistry and applications

The Influence of Sweating on the Heat Transmission Properties of Cold Protective Clothing Studied With a Sweating Thermal Manikin

Harriet Meinander、Mari Hellsten2004-01-01International Journal of Occupational Safety and Ergonomics

One of the objectives of the European SUBZERO project was to study the influence of sweat evaporation and condensation on the heat transmission properties of cold protective clothing. With the sweating thermal manikin Coppelius, water vapour transfer through and water condensation in the clothing can be determined sim…

Thermoregulation and physiological responsesExercise and Physiological ResponsesTextile materials and evaluations

A bio-driven lime and pickle free tanning paves way for greener garment leather production

B. Chandrasekaran、Jonnalagadda Raghava Rao、B. Uni Nair 等 6 位作者2004-01-01Journal of the American Leather Chemists Association

Conventional methods employed in leather processing subject the skin or hide to a wide variety of chemicals. This contributes to an increase in COD, TDS, chlorides, sulfates and other mineral salts in tannery effluent. A process sequence has now been explored viz., enzymatic dehairing, enzymatic fiber opening, and pic…

Protein Hydrolysis and Bioactive PeptidesCollagen: Extraction and Characterization

Solid oxide fuel cells

Peng Su2004-01-01OpenAlex

Solid oxide fuel cells (SOFCs) convert chemical energy in the reaction materials to electrical energy directly, and are characterized by their high effeciency, cleanliness, all-solid structure, and high temperature operation.This new technology is one of the fastest developing forms of energy source, and may well be a…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Evaluation of IGSCC Growth Behavior of 316NG PLR Piping in BWR

Katsuhiko Kumagai、Shunichi Suzuki、Jun Mizutani 等 7 位作者2004-01-01OpenAlex

Through inspections of Japanese boiling water reactors (BWRs) from 2002, a high occurrence rate of Inter Granular Stress Corrosion Cracking (IGSCC) was confirmed in core shrouds and re-circulation (PLR) pipings made of low-carbon (L-grade) stainless steels (Okamura, et al., 2003), and the evaluation of IGSCC growth be…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNon-Destructive Testing Techniques

Recognition of Cotton Contaminants via X-Ray Microtomographic Image Analysis

Aditi S Pai、Hamed Sari‐Sarraf、Eric Héquet2004-01-01IEEE Transactions on Industry Applications

Technologies currently used for cotton contaminant assessment suffer from some fundamental limitations. These limitations result in the misassessment of the cotton quality, and have a serious impact on its economic value. Through our research, we have shown that X-ray microtomographic image analysis may be applied wit…

Textile materials and evaluationsForest ecology and managementStatistical Methods and Applications

Visualization of Hydrogen Distribution in Tensile-Deformed Al-5%Mg Alloy Investigated by means of Hydrogen Microprint Technique with EBSP Analysis

Keitaro Horikawa、Kenichi Yoshida2004-01-01MATERIALS TRANSACTIONS

Hydrogen distribution in high-purity-based polycrystalline Al-5%Mg alloys prepared by changing the melting atmosphere was visualized by means of hydrogen microprint technique with electron backscattering pattern analysis after a tensile deformation at room temperature. The number of hydrogen atoms observed as silver p…

Fusion materials and technologiesHydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and Properties

A Novel Method for “Wet” SEM

Iris Barshack、Juri Kopolovic、Yehuda Chowers 等 7 位作者2004-01-01Ultrastructural Pathology

Progress in the processing of wet tissues, without the need of fixation and complex preparation procedures, may facilitate the microscopic examination of tissues and cells. Microscopic examination of tissues is a central tool in clinical diagnosis as well as in diverse areas of research. The authors present the applic…

Corrosion Behavior and InhibitionAdvanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy Techniques

An investigation of the structure of stearate monolayers on Au@ZrO 2 and Ag@ZrO 2 core–shell nanoparticles

Anoop S. Nair、Thalappil Pradeep、Ian MacLaren2004-01-01Journal of Materials Chemistry

Monolayer protected nanoparticles, Au@ZrO2@stearate and Ag@ZrO2@stearate, in which the core–shell nanoparticles, Au@ZrO2 and Ag@ZrO2 (ZrO2 coated Au and Ag nanoparticles) are functionalized with stearic acid, have been synthesized and characterized. The air-dried powders, freely dispersible in several organic solvents…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesMolecular Junctions and Nanostructures