Materials Literature
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Single crystals of SrxBa1−xNb2O6 (SBN) with congruent composition (x = 0.61) and Sr0.61Ba0.39Nb2O6 crystals doped with various concentrations of cerium are grown with the Czochralski method. A subsequent doping of the crystals with protons and deuterons is performed either by hydrothermal high temperature treatment or…
The tracer diffusion coefficient of 44Ti in α-Fe is determined by the serial sectioning method in the temperature range of 948 to 1174 K. In paramagnetic α-Fe the diffusion coefficient of Ti shows a linear Arrhenius relationship from the α-γ transformation temperature to about 30 K above the Curie temperature TC = 104…
The optical and electrical properties of c-axis-oriented ZnO films prepared by chemical vapour deposition (CVD) in oxygen atmosphere containing water vapour are investigated. The minimum dc resistivity gives 2.20 Ω cm at a film formation temperature of 550°C. The temperature dependence of electrical conductivity for t…
The chemical species in the asymmetric unit of the title complex, [Cu(C 2 H 3 N) 4 ]PF 6 .C 2 H 3 N, consist of tetrahedral [Cu(CH 3 CN) 4 ] + cations [Cu−N 1.968 (6)-2.030 (6) A], [PF 6 ] − anions and acetonitrile solvate molecules
The diffusion constant in a silicon melt is calculated using molecular dynamics simulation based on the modified Stillinger–Weber [Phys. Rev. B 31, 5262 (1985)] interatomic potential in the temperature range 1550 K<T<1900 K. Temperature dependence of the calculated diffusion constant can be expressed usi…
We present the results of density-functional calculations of the dielectric function and the photoelastic tensor---the susceptibility for strain-induced birefringence---in GaAs for photon frequencies below the direct band gap. These calculations were performed in the Kohn-Sham local-density approximation in a pseudopo…
Crystal structure refinement of copper-bearing tourmaline from Paraiba, Brazil, rim composition {Na 0.54 Ca 0.05 } {Li 1.21 Mn 0.04 Cu 0.10 Al 1.66 } Al 6 {Si 5.92 - Al 0.08 } O 18 {BO 3 } 3 ,(OH) 3.56 F 0.44 }, core composition {Na 0.55 Ca 0.01 } {Li 1.16 Mn 0.08 Cu 0.05 Al 1.71 } Al 6 {Si 5.88 -Al 0.12 } O 18 {BO 3…
Spin-resolved x-ray photoelectron-spectroscopy (SRXPS) studies of metallic-Ni core-level and valence-band photoemission are reported. Prominent spin polarizations are observed for all main components and satellites. A spin-dependent splitting of 0.38 eV is observed for the main Ni 3s component. The Ni 3s 6-eV satellit…
Abstract Extraction and swelling experiments were carried out in order to measure the crosslinkability by dicumyl peroxide (DCP) of new homogeneous linear low‐density polyethylenes (LLDPEs) with different molecular weight, branch content, and length of branches. Considering that the tertiary radicals are most probable…
We have studied the luminescence properties of a ${\mathrm{Si}}_{8}$ cubic cluster, octasilacubane. The photoluminescence (PL) is observed around 1.7 eV at low temperatures and the PL decay is a single exponential with a time constant of 3.1 ms. The PL intensity and the PL lifetime abruptly decrease with increasing te…
Novel ring-disk ultramicroelectrodes (RD-UMEs) with analytical tip diameters as small as 25-30 microns were fabricated. Carbon RD-UMEs were reproducibly prepared by the chemical vapor deposition of alternating concentric layers of silica and carbon on resistively heated 10 microns carbon fibers. High-quality films wit…
Strained CdSe/CdS superlattices show very strong intrinsic piezoelectric fields due to the high piezoelectric constants in combination with a large lattice mismatch of 3.9%. The linear as well as the nonlinear optical properties are formed by these fields, which dominate the band structure. We report on the excitation…
Steady-state- and time-resolved-photoluminescence (PL) and cathodoluminescence (CL) studies have been carried out on several synthetic type-IIb boron-doped semiconducting diamond samples. The behavior of the 1.84-eV red donor-acceptor pair band is compared directly with that of the well-known green band-A emission nea…
This work reports a successful electron-electron coincidence experiment performed in grazing-angle reflection geometry. (e,2e) measurements with a 300-eV impact energy have been carried out on a clean highly oriented pyrolytic graphite surface and the feasibility of binding-energy spectroscopy with quasimomentum discr…
We present and discuss photoemission (PES) and O 1s x-ray-absorption spectra (XAS) of ${\mathrm{Ti}}_{4}$${\mathrm{O}}_{7}$ taken at different temperatures in the range 50--300 K. The PES taken at 300 K show Ti 3d bands at the Fermi level and O 2p bands at higher binding energies. The Ti 3d bands shift approximately 0…
Abstract The Monte Carlo sampling technique is used to investigate the branched structure formation during free‐radical polymerization that involves chain transfer to polymer. This method accounts for the history of the generated branched structure and can provide virtually any structural information, because one can…
Abstract Polyethylene–polystyrene blends containing small amounts of polyethylene (20 wt %) display a cocontinuous phase morphology that is very unstable in the absence of an emulsifier. The kinetics of coalescence at high temperature is therefore very sensitive to differences in the interfacial activity of added poly…
Abstract Crystallization behavior of synthetic cis ‐1,4 polyisoprene mixed with methyl linolate was investigated by differential scanning calorimetry and dilatometry. At isothermal crystallization temperature of −25°C, a rate of crystallization decreased with the addition of 1 wt % methyl linolate, whereas it increase…
The local empirical pseudopotential theory in the S-matrix implementation was used to study the structure of (Zn,Cd)(S,Se) polytypes considered as natural heterocrystalline superlattices. Hexagonal polytype superlattices of (Zn,Cd)(S,Se) are predicted to be characterized by direct band gaps and have minibands derived…
Thermal annealings of amorphous gallium antimonide films were accompanied using Raman spectroscopy, both for stoichiometric and nonstoichiometric compositions. The films were prepared by flash evaporation on silicon substrates. Structural changes were induced by the heat treatments: an increasing degree of crystalliza…