Materials Literature
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Abstract A theoretical model describing the interaction between crystalline swelling and cation exchange selectivity is proposed for expanding 2:1 phyllosilicates. The model is based on the assumption that changes in basal spacing of a clay are phase changes, and that each phase of a clay has a different selectivity c…
A surface science model for the Phillips ethylene polymerization catalyst has been prepared, by impregnating aqueous CrO 3 on a flat silicium (100) substrate covered by amorphous silica. Impregnating in a spin-coating technique offers control over the chromium loading, which was varied between 0.4 and 4.0 Cr/nm 2 . Af…
Isomerically pure α 1 - and α 2 -[Fe(OH 2 )P 2 W 17 O 61 ] 7 - and α 2 [Fe(OH 2 )P 2 Mo 2 W 15 O 61 ] 7 - were synthesized as aqueous-soluble potassium salts. The iron-substituted complexes as well as their immediate lacunary precursors have been characterized by IR, UV−visible, and 31 P NMR spectroscopies. The acid−b…
Static contact angle and dynamic (advancing and receding) contact angles of water on polymeric surfaces were investigated using microscope cover glasses coated with various plasma polymers of trimethylsilane and oxygen. By variation of the mole fraction of the TMS/oxygen mixture, glass surfaces having varying degrees…
The distribution of solvent in block copolymer solutions near their order−disorder transitions is examined experimentally, by small-angle neutron scattering (SANS), and theoretically, by the self-consistent mean-field (SCMF) approach. Three lamellar-forming poly(styrene- b -isoprene) diblocks were employed, in toluene…
This report details an extensive investigation on vanadium−dinitrogen complexes containing the [V(μ-N 2 )V] n + skeleton with a variable oxidation state of the metal and reduction degree of dinitrogen, n varying from 6 → 5 → 4. This skeleton can be associated to alkali cations in ion-separated or ion-pair tight forms.…
The composition of the barrier anodic film formed at 50 A m−2 to 200 V on solution-treated Al-l at.% Cu alloy in ammonium pentaborate electrolyte at 293 K has been investigated by Rutherford backscattering spectroscopy and nuclear reaction analysis. The film contains about 14% more oxygen in comparison with that expec…
We investigate theoretically the chain-length dependence of the electronic and optical properties of molecules representative of the three base forms of polyaniline (PAni), i.e., leucoemeraldine, emeraldine, and pernigraniline. The results establish that the PAni oligomers show a weak evolution of their electronic and…
A model relaxor ferroelectric ${\mathrm{PbMg}}_{1/3}{\mathrm{Nb}}_{2/3}{\mathrm{O}}_{3}$ (PMN) in single-crystal form has been studied by Raman scattering with special attention to the low-frequency spectra in the vicinity of both the diffuse ferroelectric transition (\ensuremath{\sim}270 K) and the electric-field-ind…
Two organosilver(I) compounds of pylene and perylene presented here exhibit an unusual tetra-η2-coordination, bridging four metal centers and leading to W-type sandwich polymeric chains and sheets. Both compounds, show typical radical cation ESR signals upon irradiation with light or iodination.
The alpha-acetolactate decarboxylase gene aldB is clustered with the genes for the branched-chain amino acids (BCAA) in Lactococcus lactis subsp. lactis. It can be transcribed with BCAA genes under isoleucine regulation or independently of BCAA synthesis under the control of its own promoter. The product of aldB is re…
Self-assembled monolayers of a small bifunctional molecule (4-carboxythiophenol) have been formed on Al and Au surfaces. The nature of coordination of the molecules to the two metal surfaces is different, leading to different terminal functionality of the monolayer surface. This aspect has been favorably exploited to…
Vapor-phase pyrolysis of Fe(CO) 5 in the presence of another carbon source such as CO or C 6 H 6 yields iron-filled or hollow nanotubes depending on the relative concentration of the carbon source. Essentially single-walled nanotubes are obtained when the C 6 H 6 /Fe(CO) 5 ratio is high. Pyrolysis of metallocenes yiel…
Abstract The ligand N,N,N',N' ‐tetra‐ethylpyridine‐2,6‐dicarboxamide ( L 9 ) reacts with trivalent lanthanide ions (Ln III ) to give stable mononuclear triple‐stranded helical complexes [Ln( L 9 ) 3 ] 3+ (Ln = La to Lu). The crystal and molecular structures of [La( L 9 ) 3 ](ClO 4 ) 3 .2.5C 2 H 5 CN ( 8 ) and [Eu( L 9…
The conformation of silk fibroin in silk fibroin/chitosan (SF/CS) blend membrane was analyzed by infrared spectrum, X-ray diffractometry, and Raman spectrum. The results demonstrated that the SF could show β-sheet conformation when the SF content in blend membranes was 10% (w/w) and 60–80% (w/w), while the pure SF mem…
Constant strain rate tensile tests have been conductedfor fine grained Mg-Al-Zn (AZ91) and Mg-Zn-Zr (ZK60 and ZK61) alloys processed by powder metallurgy (PM) and ingot metallurgy (IM) routes. The experimental results revealed that the strain rate was inversely proportional to the cube of the grain size and that the a…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTEvidence for Novel Interdigitated Bilayer Formation of Fatty Acids during Three-Dimensional Self-Assembly on Silver Colloidal ParticlesVijaya Patil, K. S. Mayya, S. D. Pradhan, and Murali SastryView Author Information Materials Chemistry Division National Chemical Labo…
The synthesis, X-ray crystal structures, and some spectroscopic and chemical properties of the nitrosylruthenium(II) porphyrin complexes Ru(TPP)(NO)(ONO), Ru(TPP)(NO)(OH), Ru(OEP)(NO)(ONO), and Ru(OEP)(NO)(OH) (TPP = tetraphenylporphyrinato dianion; OEP = octaethylporphyrinato dianion) derived from the analogous Ru(II…
Abstract Ultimate success in the design of solid oxide catalysts as well as other covalently bonded or heterogenised organometallic catalysts predicates knowledge of precisely what structure it is that has to be targetted. This, in turn, demands the greatest possible precision in determining, under operating condition…
Neutron diffraction and inelastic neutron scattering in zero field have been performed on mesoscopic magnetic ${\mathrm{Mn}}_{12}{\mathrm{O}}_{12}$ clusters, well known for their macroscopic quantum effects observed at low temperature. In addition to the static spin correlations of the cluster in its ground state, we…