Materials Literature
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This contribution summarizes investigations of organic-inorganic hybrid materials wherein the inorganic phase is ordered mesoporous silica such as MCM-41 and SBA-15. The review, which covers work performed in the last three years, emphasizes studies of: (1) covalently attached functional groups, (2) new approaches to…
The development of a new class of polyurethane polyols from cardanol, a renewable organic resource obtained as a byproduct of the cashew industry, is reported. For synthesizing polyols the monoglycidyl ether of cardanol was prepared first, followed by ring opening to prepare the diol or reaction with diethanol amine t…
Wautersia eutropha, formerly known as Ralstonia eutropha, a gram-negative bacterium, accumulates polyhydroxybutyrate (PHB) as insoluble granules inside the cell when nutrients other than carbon are limited. In this paper, we report findings from kinetic studies of granule formation and degradation in W. eutropha H16 o…
Photoelectronic properties of Alq3 were studied by photoconductivity measurements in thin film, sandwich (ITO/Alq3/LiF/Al) devices. We find that the photocurrent is dominated by bulk generation of carriers for incident photon energies greater than 2.75 eV. The quantum efficiency of photocarrier generation has been mea…
We report on resonant tunneling magnetoresistance via localized states through a ZnSe semiconducting barrier which can reverse the sign of the effective spin polarization of tunneling electrons. Experiments performed on Fe/ZnSe/Fe planar junctions have shown that positive, negative or even its sign-reversible magnetor…
We report on the muon Knight shift measurement in single crystals of LiV2O4. Contrary to what is anticipated for the heavy-fermion state based on the Kondo mechanism, the presence of inhomogeneous local magnetic moments is demonstrated by the broad distribution of the Knight shift at temperatures well below the presum…
A phenomenological treatment of domain walls based on the Ginzburg-Landau-Devonshire theory is developed for uniaxial, trigonal ferroelectrics lithium niobate and lithium tantalate. The contributions to the domain wall energy from polarization and strain as a function of orientation are considered. Analytical expressi…
A fundamental, yet underexplored, materials system is the interface between biological molecules and inorganic surfaces. In an elemental approach to this problem, we have systematically examined the adhesion of amino acids to a series of inorganic surfaces including metals, insulators, and semiconductors. Significant…
We consider the shape of the magnetic Compton profile (MCP), $J_{mag}(p_z)$, in La$_{1.2}$Sr$_{1.8}$Mn$_2$O$_7$ for momentum transfer $p_z$ along the [110] direction and the associated reciprocal form factor $B(r)$ defined by taking the one-dimensional Fourier transform of $J_{mag}(p_z)$. $B(r)$ is shown to contain a…
We discuss an efficient scheme for obtaining spin-polarized quasi-particle excitation energies within the general framework of the density functional theory (DFT). Our approach is to correct the DFT eigenvalues via the electrostatic energy of a majority or minority spin electron resulting from its interaction with the…
The solvents o-, m-, p-xylene, p-dichlorobenzene, 1,2,4-trichlorobenzene, and naphthalene were calibrated as condensates used in the thermoporosimetry technique. Exponential relationships were found connecting the pore radii R(p) (in nm) and the freezing-point depression of the swelling solvent deltaT (in degrees C) o…
We show that the bulk-inversion-asymmetry-type strain-induced spin-orbit coupling can be used to effectively modify the Dresselhaus spin splitting in (001) GaAs quantum wells with small well width and the resulting spin lifetime can be increased by two orders of magnitude to nanoseconds under right conditions. The eff…
We are concerned with free energy analysis of the system comprising an AFM tip, water meniscus, and polymer film. Under applied electrostatic potential, the minimum in free energy is at a distance greater than the initial tip--substrate separation in the absence of potential. This equilibrium distance, t_0, mostly dep…
6-d polyhedral models give a periodic description of aperiodic quasicrystals. There are powerful tools to describe their structural surface properties. Basis of the model for icosahedral quasicrystals are given. This description is further used to interpret high resolution STM images of the surface of i-AlPdMn which s…
We present a numerical algorithm to evaluate the self-consistent field theory for melts composed of block copolymers with multiply branched architecture. We present results for the case of branched copolymers with doubly functional groups for multiple-branching generations. We discuss the stability of the cubic phase…
Recent measurements of the magnetoimpedance (at a fixed frequency of 1 MHz) of cobalt-rich wires subjected to torsion stress show an asymmetry as a function of torsion angle stemming from residual anisotropies induced during wire fabrication. We interpret these measurements with a simple model based on the competition…
Very recently, a giant recoverable electrostrain effect has been found in aged Fe-doped ${\mathrm{BaTiO}}_{3}$ single crystals; this effect is based on a defect-mediated reversible domain-switching mechanism. However, the reversible domain-switching process itself is yet to be directly verified. In the present study,…
Monte Carlo simulation is applied to investigate phonon transport in single crystalline Si nanowires. Phonon-phonon normal (N) and Umklapp (U) scattering processes are modeled with a genetic algorithm to satisfy energy and momentum conservation. The scattering rates of N and U scattering processes are found from first…
We report a systematic study of the purification of nitric acid treated single-walled carbon nanotubes (SWNTs) by centrifugation at constant pH. The progress of the purification procedure was followed by estimating the purity by solution-phase near-infrared spectroscopy, and it was found that the sediment obtained by…
We demonstrate that highly efficient photoluminescence is generated from gold nanoparticles as small as a few nanometers in diameter upon irradiation with sub-100-fs pulses of 790-nm light. Strong emission is observed at excitation intensities comparable to or less than those typically used for multiphoton imaging of…