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A developed strict kinetic model for the growth of porous anodic films was employed to the experimental results obtained at different bath temperatures and current densities of Al anodization. Treatment of the values of parameters involved in the kinetic equation showed that the pore/cell surface density depends only…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTStabilization of NiO(111) Thin Films by Surface HydroxylsM. A. Langell and M. H. NassirCite this: J. Phys. Chem. 1995, 99, 12, 4162–4169Publication Date (Print):March 1, 1995Publication History Published online1 May 2002Published inissue 1 March 1995https://pubs.acs.org/doi/…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAbsorption, Adsorption, and Desorption Studies of the Oxygen/Rh(111) System Using O2, NO, and NO2Kevin A. Peterlinz and Steven J. SibenerCite this: J. Phys. Chem. 1995, 99, 9, 2817–2825Publication Date (Print):March 1, 1995Publication History Published online1 May 2002Publis…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDynamic Light Scattering and Dynamic Viscoelasticity of Poly(vinyl alcohol) in Aqueous Borax Solutions. 1. Concentration EffectAkihiro Koike, Norio Nemoto, Tadashi Inoue, and Kunihiro OsakiCite this: Macromolecules 1995, 28, 7, 2339–2344Publication Date (Print):March 1, 1995…
The recombinant CelS (rCelS), the most abundant catalytic subunit of the Clostridium thermocellum cellulosome, displayed typical exoglucanase characteristics, including (i) a preference for amorphous or crystalline cellulose over carboxymethyl cellulose, (ii) an inability to reduce the viscosity of a carboxymethyl cel…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHigh-Temperature Chemical and Microstructural Transformations of a Nanocomposite OrganoceramicPhillip B. Messersmith and Samuel I. StuppCite this: Chem. Mater. 1995, 7, 3, 454–460Publication Date (Print):March 1, 1995Publication History Published online1 May 2002Published in…
This work discusses the results of a self-consistent-field calculation of conformational and thermodynamic properties of polymers end-grafted to a surface in athermal solvents. Three primary issues are addressed. First, we address the question raised recently by Carignano and Szleifer as to whether the second virial t…
Polyanilines are particularly flexible family of electronic polymers. There are three insulating forms; one of which, pernigraniline base, sustains soliton excitations with very unusual properties due to the key role of ring-torsion angle alternation in additon to bond length dimerization. Protonation of the emeraldin…
The viscous Cahn-Hilliard equation arises as a singular limit of the phase-field model of phase transitions. It contains both the Cahn-Hilliard and Allen-Cahn equations as particular limits. The equation is in gradient form and possesses a compact global attractor A, comprising heteroclinic orbits between equilibria.…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTA Free Volume Distribution Model of Gas Sorption and Dilation in Glassy PolymersS. S. Jordan and W. J. KorosCite this: Macromolecules 1995, 28, 7, 2228–2235Publication Date (Print):March 1, 1995Publication History Published online1 May 2002Published inissue 1 March 1995https…
SPATIAL AND TEMPORAL DISTRIBUTION OF AUTHIGENIC MINERALS IN CONTINENTAL SHELF SEDIMENTS: IMPLICATIONS FOR SEQUENCE STRATIGRAPHIC ANALYSIS
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTGeneral Theoretical Concepts for Solid State Reactions: Quantitative Formulation of the Reaction Cavity, Steric Compression, and Reaction-Induced Stress Using an Elastic Multipole Representation of Chemical PressureTadeusz Luty and Craig J. EckhardtCite this: J. Am. Chem. So…
A cubic-tetragonal-trigonal sequence of phase transitions in the relaxor ferroelectric ${\mathrm{Na}}_{1/2}$${\mathrm{Bi}}_{1/2}$${\mathrm{TiO}}_{3}$ (NBT) has been studied by Brillouin scattering. Pronounced anomalies for both the hypersonic velocity and damping have been found that peak just between two phase transi…
We apply both self-consistent-field theory (SCFT) and strong-segregation theory (SST) to the lamellar phase of a melt of linear multiblock copolymers. We present a new solution for the SST which now agrees with that obtained for the SCFT. Using both theories, we calculate the distribution of monomers from the center o…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXT1H NMR Spectroscopic Study of Paramagnetic Lanthanide(III) Texaphyrins. Effect of Axial LigationJerzy Lisowski, Jonathan L. Sessler, Vincent Lynch, and Tarak D. ModyCite this: J. Am. Chem. Soc. 1995, 117, 8, 2273–2285Publication Date (Print):March 1, 1995Publication History…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRegiospecific and Nonlinear Substituent Effects on the Electronic and Fluorescence Spectra of PhthalocyaninesNagao Kobayashi, Natsuko Sasaki, Yasuhiro Higashi, and Tetsuo OsaCite this: Inorg. Chem. 1995, 34, 7, 1636–1637Publication Date (Print):March 1, 1995Publication Histo…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSynthesis in Molten Alkali Metal Polyselenophosphate Fluxes: A New Family of Transition Metal Selenophosphate Compounds, A2MP2Se6 (A = K, Rb, Cs; M = Mn, Fe) and A2M'2P2Se6 (A = K, Cs; M' = Cu, Ag)Timothy J. McCarthy and Mercouri G. KanatzidisCite this: Inorg. Chem. 1995, 34…
Nonlinear optical (NLO) properties of CsLiB 6 O 10 (CLBO) have been investigated. Frequency quadrupling of the 1.064 µ m Nd:YAG laser output for type-I phase matching was observed by using CLBO. The walk-off angle and the effective NLO coefficient deff were estimated to be 1.83° and 1.01 pm/V for fourth harmonics gene…
The effect of silanation on the dispersion of quartz and zirconia-silica fillers by monomers used to formulate composites was studied. Sixteen silane coupling agents and three methods were used, and the amounts of the monomers needed to reach wet and flow point values were determined. The silanes were selected to have…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDensity Functional Analysis of Phenomenological Theories of Gas-Liquid NucleationV. Talanquer and D. W. OxtobyCite this: J. Phys. Chem. 1995, 99, 9, 2865–2874Publication Date (Print):March 1, 1995Publication History Published online1 May 2002Published inissue 1 March 1995htt…