Materials Literature
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Cahn's general argument for complete wetting in the vicinity of critical points is critically reviewed. Critical-point wetting does occur in systems with short-range (exponentially decaying) forces. Whenever short-range forces favor wetting, while at the same time there is a tendency towards drying due to weak long-ra…
The photoluminescence (PL) and excitation spectra of various thermoluminescence dosimetry (TLD) phosphors were measured at temperatures of 6, 17, 80 and 300 K. Their PL spectra at 300 K consist of a single band in the vicinity of 380 nm. The emission bands and their excitation bands are ascribed to the electronic 4 f…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTToward a unified view of the mechanism responsible for paint defects by metallic corrosionWerner FunkeCite this: Ind. Eng. Chem. Prod. Res. Dev. 1985, 24, 3, 343–347Publication Date (Print):September 1, 1985Publication History Published online1 May 2002Published inissue 1 Se…
ABSTRACT A nitrogen limitation technique elicited the entire life cycle of the marine centric diatoms Chaetoceros diadema (Ehr.) Gran and Leptocylindrus danicus Cleve. In C. diadema the sexual cycle followed the same pattern as in the previously investigated C. didymus. Sexuality took place in narrow diameter cells, o…
The RFe2alloys (R=Tb,Dy,Sm) offer opportunities for achieving very high magnetostrictions at temperatures far above room temperature. Saturation strains greater than 1000 ppm have been measured at temperatures as high as 200°C. In addition to saturation strain measurements, we have measured magnetostriction of Tb.27DY…
The dc conductivities (α) of PbO‐P 2 O 5 ‐V 2 O 5 glasses containing up to 80 mol% V 2 O 5 were measured at T = 100°C to T = 10°C below the glass transition temperature. Dielectric constants at 1 MHz, densities, and the fraction of reduced V ion were measured at room temperature. The conduction mechanism of glasses co…
ABSTRACT The axial retractive stresses that cause the supercontraction of wetted major ampullate silk fibres and the stresses developed upon reextension from the supercontracted condition are quantified and illustrated. The viscoelastic behaviour of major ampullate silk fibres, subjected to the amounts of elongation t…
Abstract The substitution of Fe for Co of La1−xSrxCoO3−δ makes it possible to preserve perovskite-type structure at higher Sr contents. While the amount of oxygen reversibly absorbed or desorbed was mostly determined by the Sr content, the Fe substitution was found to enhance the oxygen desorption particularly in a lo…
Three empirical equations introduced by Jonscher to represent the imaginary part of the small-signal frequency response of dielectric materials and termed ‘‘universal dielectric response’’ by him are generalized in three ways. The equations may be applied in normalized form at the impedance level as well as at the usu…
When the small-signal ac frequency response of a dielectric or conductive system is known, either functionally or as data, it is shown that the corresponding response of an associated conductive or dielectric system may be immediately obtained through the use of new duality relations. A specific model is considered wh…
Abstract Chemically modified electrodes are prepared by deposition of copper hexacyanoferrate (CuHCF) on glassy carbon. These electrodes are characterized by voltammetric and potentiometric measurements. After suitable conditioning they exhibit nearly Nernstian response to changes in activity of potassium or ammonium…
Abstract Previous work has shown that sorption of CO 2 at relatively high pressures by glassy polymers reduces their glass transition temperatures and may convert the glass into a rubber under certain conditions. It is shown here that this plasticization by a gas can induce crystallization just as sorption of vapors o…
Details of the optical-spectroscopic properties of alexandrite (${\mathrm{BeAl}}_{2}$${\mathrm{O}}_{4}$:${\mathrm{Cr}}^{3+}$) crystals were studied by different laser-spectroscopy techniques. The temperature dependences of the fluorescence lifetimes and widths of the zero-phonon lines were found to be quite different…
Ribonuclease A has been used as a model protein for studying the specificity of glycation of amino groups in protein under physiological conditions (phosphate buffer, pH 7.4, 37 degrees C). Incubation of RNase with glucose led to an enhanced rate of inactivation of the enzyme relative to the rate of modification of ly…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCatalytic photochemical dehydrogenation of organic substrates by polyoxometalatesCraig L. Hill and Donald A. BouchardCite this: J. Am. Chem. Soc. 1985, 107, 18, 5148–5157Publication Date (Print):September 1, 1985Publication History Published online1 May 2002Published inissue…
Abstract The microdomain structure of a series of segmented polyurethane block copolymers is characterized by small‐angle x‐ray and neutron scattering analyses. The materials contain hard segments formed from 4,4′‐ diphenylmethane diisocyanate (MDI) and butanediol (BD), and range in hard‐segment content from 20 to 80%…
I describe some results of the first systematic study of above-bandgap optical anisotropies in cubic semiconductors. The anisotropies are large, of the order of 1% of the relative reflectance differences for light polarized along orthogonal principal axes of the dielectric tensor of the anisotropic phase. Extrinsic co…
The various photo-induced phenomena that occur in chalcogenide glasses are classified and described, with particular emphasis on the photo-dissolution effect. The detailed mechanisms responsible for many of these processes are still unknown, although in the case of photo-darkening in annealed a-As2S3 films, Raman expe…
Over-quenched melt-spun ribbons of nominal composition Nd0.14(Fe0.91B0.09)0.86can be compacted to fully dense permanent magnets by hot-pressing at 700-750°C to 100 kPa (-15 kpsi). The resulting material is only slightly magnetically aligned with room temperature magnetics:B_{r}/H_{ci}\simeq 8kG/19 kOe. Die-upsetting t…
A square-lattice model of amphiphile-oil–water systems is developed in which oil and water molecules occupy single sites and amphiphiles occupy chains of sites. Energies and free energies estimated by Monte Carlo sampling of configuration space show that when the head, or water-loving portion, of the amphiphile has no…