Materials Literature
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Linear free energy relations have been used to calculate rate coefficients for the stages in the polycondensation reaction of the potassium salt of 4-fluoro-4′-hydroxybenzophenone and for the polycondensation reactions of 4,4′-difluorobenzophenone with the dipotassium salt of 4,4′-dihydroxybenzophenone and the dipotas…
Using drug concentration remaining at a given time as the criterion, a 24x3 factorial design has been employed to investigate the effects of temperature, light, media (aqueous or organic/aqueous), ionic strength and pH on the stability of doxorubicin hydrochloride. Following the application of first order kinetics, an…
Hydrolysis of [Mo(NBut)(CH2But)2(CHBut)], which leads to the trimetallic title compound, is shown to occur stepwise via four identificable oxo-bridged dimetallic intermediates.
Abstract When ferrites are used for electromagnetic wave absorbers in the VHF and UHF bands we note their excellent properties such as their wider dynamic frequency bandwidth and their thinner thickness than that of lossy dielectric absorbers, which are due to their magnetic losses. However, there exists an upper freq…
Adhesive hard-sphere colloidal dispersions. III. Stickiness in n-dodecane and benzene.- The structure of colloidal suspensions under shear flow: Light scattering experiments.- Kinetic and spectroscopic properties of small colloids of metal iodide semiconductors.- Charge carrier dynamics in colloidal semiconductors.- C…
Facteurs agissant sur le fluage: degre de cristallinite, epaisseur lamellaire, temperature, vitesse de contrainte
The effect of shed configuration on the contamination performance of post insulators for HVDC converter stations is reported. Field measurements of contamination severity are used to define the contaminant levels utilized in artificial contamination tests made with the clean fog method. Test results for naturally cont…
The permanganate oxidation of L-leucine in aqueous phosphate buffers over the pH range 6.1 – 7.6 is autocatalyzed by the manganese reduction product, a soluble form of colloidal manganese dioxide. The kinetic data for both the non-catalytic and autocatalytic reaction pathways have been obtained, and mechanism in agree…
Dimethylindium(III) complexes have been isolated from aqueous methanol on reaction of dimethylindium(III) nitrate with the neutral nitrogen donor ligands 1,10-phenanthroline, 2,2′-bipyridyl, and 4,4′ disubstituted 2,2′-bipyridyls, bis(pyridin-2-yl)methane [(py)2CH2], bis(N-methylimidazol-2-yl)methanol, 2,2′:6′,2″-terp…
The structure of Na5[Cu{TeO4(OH)2}2]·16H2O has been determined by X-ray structure analysis. It crystallises in the triclinic space group P with a= 5.922(4), b= 8.939(2), c= 12.528(2)Å, α= 98.45(1), β= 99.11(3), γ= 93.82(4)°, and Z= 1. The structure was refined to R= 0.040 for 2 131 observed reflections [F > 3σ(F)]. Th…
A detailed model structure of dodecagonal quasicrystals is proposed which applies to both dodecagonal Ni-Cr and V-Ni or V-Si-Ni. This model structure can be represented as the restriction of a 5d periodic structure to a 3d subspace, which is identified with physical space. The point group and the space group of the 5d…
The peak toughness of a commercial magnesia‐partially‐stabilized zirconia was strongly dependent on a postprocessing, postspecimen preparation, and modest annealing (1000°C for 20 min), increasing it from ∼9 to almost ∼18 MP a·m 1/2 . Further study of this surprising phenomenon revealed that increases in toughness occ…
Magnetostriction in modern (110)[001] grain-oriented Si-Fe sheets can be understood by considering magnetic domain structures and their variation with magnetization on the basis of magnetic domain theory. Magnetostrictive elongation in g.o. sheets is dominated by the behavior of 90° domain walls included in subdomains…
The wettabilities of α-SiC, hot pressed SiC, and reaction bonded SiC by liquid Cu were investigated using the sessile drop method under various experimental conditions.The main results obtained are summarized as follows:(1) The contact angle of liquid Cu on SiC depended on SiC used.(2) The characteristic wetting was o…
The elastic problem in two-dimensional percolation is investigated on a hierarchical lattice, in the context of Cosserat elasticity (or granular elasticity). For this regular fractal, the exponent of elastic moduli ($\frac{T}{v}$) is slightly smaller than the expected value ($\frac{t}{v}+2$) deduced from the conductiv…
Distribution of doping cations between A and B sites of perovskite ABO3 structure obeys certain conditions derived in terms of energy. These can be applied to predict semiconducting BaTiO3-based compositions, to account for yet unexplained anomalies in concentrational dependencies of electrical resistivity and Curie t…
Dislocation structures in fatigue were investigated with special consideration given to the compatibility of the macroscopic observation by an optical microscope and the microscopic observation by a transmission electron microscope (TEM). First, previous works are reviewed from this point of view, that is, the compata…
The polypeptide produced by expressing a chemically synthesized gene coding for the amino-acid sequence of T4-lysozyme has been crystallized and subjected to X-ray diffraction. The crystal structure has been refined to a standard R-factor of 0.191 for data between 8 and 2 A resolution. The refined model is essentially…
We are probing the determinants of catalytic function and substrate specificity in serine proteases by kinetic and crystallographic characterization of genetically engineered site-directed mutants of rat trypsin. The role of the aspartyl residue at position 102, common to all members of the serine protease family, has…
The effect of Zr addition to FeTi on the initial hydriding process, the pressure-composition isotherms and the microstructure was investigated. The partial substitution of Zr (1∼15 at%) for Fe, Ti or both enhanced the activation of FeTi and it hydrided at 303 K after a short incubation time without any heat treatment.…