Materials Literature
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Tellurite glasses optimized for higher Raman gain and broad bandwidth have been realized. These glasses were found to have improved thermal stabilities, which make them suitable for fiber devices applications. While maintaining the Raman gains at higher values, the Raman bandwidths could be broadened by proper additio…
We have carried out theoretical investigations to explore the diffusion of lithium on the exteriors and the interiors of single-walled carbon nanotubes (SWNTs). We found that lithium can adsorb on both interior and exterior surfaces with adsorption energy around $\ensuremath{-}2.44\phantom{\rule{0.3em}{0ex}}\mathrm{eV…
Periodic DFT and combined quantum mechanics/interatomic potential function (QM-pot) models were used to describe the interaction of CO with the Cu+ sites in FER. The CO stretching frequencies were calculated using omega(CO)(CCSD(T))/r(CO)(DFT) scaling method relating frequencies determined using a high-level quantum-c…
In the last two decades, the development of polymers which change their structures and properties in response to environmental stimuli such as pH, temperature, and light has attracted a great deal of attention (1-3). Such polymers have been called ‘‘smart polymers,’’ ‘‘intelligent polymers,’’ ‘‘stimulus-sensitive poly…
Carbon nanotubes with a double coaxial structure of nitrogen-doped and undoped multiwalls were successfully prepared by the template technique using porous anodic aluminum oxide film as a template. The inner carbon layer (or the outer carbon layer) of the double coaxial carbon nanotubes is free from N, while the outer…
Electrochromic multilayer films consisting of polyoxometalate (POM) cluster alpha-K(10)[P(2)W(17)O(61)].17H(2)O (P(2)W(17)), copper(II) complex [Cu(II)(phen)(2)](NO(3))(2) (phen = 1,10-phenithroline), and iron complex [Fe(II)(phen)(3)](ClO(4))(2) were fabricated on silicon, quartz and ITO substrates by layer-by-layer…
The synthesis of tetrakis(tetrathiafulvalene)-annulated metal-free and metallophthalocyanines 5-8 via the tetramerization of the phthalonitrile derivative 4 is reported. All of them have been fully characterized by electronic absorption spectroscopy, thin-layer cyclic voltammetry, mass spectrometry, and elemental anal…
Maintenance of genetic diversity in eukaryotic microbes reflects a synergism between reproductive mode (asexual vs. sexual) and environmental conditions. We determined clonal diversity in field samples of the planktonic marine diatom, Ditylum brightwellii, during a bloom, when cell number increased by seven-fold becau…
Using the full-potential linearized-augmented-plane-wave (FLAPW) method, we have analyzed systematically the trends in the structural and electronic properties of the 3d and 4d transition-metal oxides SrMO_3 (M = Ti, V, Zr and Nb). The optimized lattice parameters, bulk modules, densities of states, band structures an…
Coherent bremsstrahlung of high energy electrons moving in a three-dimensional imperfect periodic lattice consisting of a complicated system of atoms is considered. On the basis of the normalized probability density function of the distribution of atomic centers in the fundamental cell the relations describing coheren…
Atomistic molecular dynamics simulations are used to study generation 5 polyamidoamine (PAMAM) dendrimers immersed in a bath of water. We interpret the results in terms of three classes of water: buried water well inside of the dendrimer surface, surface water associated with the dendrimer-water interface, and bulk wa…
The Volmer-Weber mode for growing polycrystalline films, which comprises island, network, and channel stages before the films become continuous, is well known for its complex stress behavior with compressive and tensile stress alternating in the initial three growth stages. Recently, two new mechanisms for the compres…
The influence of twin boundaries on the heat capacity and diffuse scattering in a crystal is described within the framework of a macroscopic dynamic theory.
This article presents a characterization and evaluation of silicon carbide for high-velocity impact. This includes a wide range of loading conditions that produce large strains, high strain rates, and high pressures. Experimental data from the literature are used to determine constants for the Johnson–Holmquist–Beisse…
We apply a first-order reversal curve (FORC) diagram analysis to a perpendicular nickel nanopillar array. We find that the FORC diagram signature of this system consists of a two-branch ``wishbone'' structure. Two distinct negative regions are also observed, along with a prominent reversible ridge. The objective of th…
Ionic liquids (ILs) have been used as electrolytes for supercapacitors. Two phosphonium salts such as trihexyl(tetradecyl)phosphonium bis(trifluoromethylsulfonyl)imide (IL1) and trihexyl(tetradecyl) phosphonium dicyanamide (IL2) have been selected for this target. To decrease the viscosity of ILs, a small amount of ac…
A discrete model describing defects in crystal lattices and having the standard linear anisotropic elasticity as its continuum limit is proposed. The main ingredients entering the model are the elastic stiffness constants of the material and a dimensionless periodic function that restores the translation invariance of…
Within the ``anisotropic relaxation time'' approach to transport processes, I obtain a new geometric formula for the weak-field Hall conductivity of metals, which generalizes previously-known formulas due to Tsuji (restricted to cubic 3D metals) and Ong (for 2D metals).
The pioneer work of Krim and Widom unveiled the origin of the viscous nature of friction at the atomic scale. This generated extensive experimental and theoretical activity. However, fundamental questions remain open like the relation between sliding friction and the topology of the substrate, as well as the dependenc…
Polycrystalline BiFeO3 thin films were fabricated on (111)Pt∕Ti∕SiO2∕Si substrates via Bi-acetate- and Fe-acetylacetonate-based chemical solution deposition and spin-coating techniques. The processing parameters were optimized in order to obtain films with high resistivity. The optical properties (refractive indices a…