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Manipulating the microstructure and rheology in polymer‐organoclay composites

Michael Gelfer、Carlos Alberto Ávila‐Orta、Lizhi Liu 等 10 位作者2002-09-01Polymer Engineering and Science

Abstract A series of nanocomposites prepared by melt‐blending of cloisite‐based organoclays with poly(ethylene‐vinylacetate) (EVA) and neutralized poly (ethylene‐methacrylic acid) (EMA) copolymers were investigated via DSC, small‐angle X‐ray scattering (SAXS), and rheological techniques. SAXS results indicated partial…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Crystallinity of In2O3(ZnO)5 films by epitaxial growth with a self-buffer-layer

Naoki Ohashi、Isao Sakaguchi、Shunichi Hishita 等 6 位作者2002-09-01Journal of Applied Physics

Naturally modulated structures, films of In2O3(ZnO)5, were epitaxially grown by rf magnetron sputtering on (0001) sapphire substrates. The crystallographic and morphological features of the films were characterized by using x-ray-diffraction and electron-diffraction patterns. The deposition of strongly c axis orientat…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsElectronic and Structural Properties of Oxides

Effect of shear deformation on refinement of crystal grains

T. Inoue、Shiro Torizuka、Kotobu Nagai2002-09-01Materials Science and Technology

Ferrite grain structures created through transformation from deformed austenite under different deformation modes have been investigated for a low carbon Si–Mn steel. To introduce a large plastic strain, a specimen is compressed by a pair of anvils with edges controlled to keep the strain rate constant by using a comp…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsElectromagnetic Effects on Materials

Modeling of metallicmaterials at high strain rates with continuum damage mechanics

George Z. Voyiadjis、AN Palazotto、X-L Gao2002-09-01Applied Mechanics Reviews

Abstract Damage modeling of metallic materials under high strain rate loading conditions is reviewed. The emphasis is on the modeling efforts based on continuum damage mechanics, although many important references dealing with general aspects of dynamic behavior of materials are also discussed. Relevant issues on the…

Microstructure and mechanical propertiesHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Tb2Se2O7: Terbium(III) Oxide Oxoselenate(IV) according to Tb2O[SeO3]2 with a “Lone—Pair” Channel Structure

Joseph Wontcheu、Thomas Schleid2002-09-01Zeitschrift für anorganische und allgemeine Chemie

The colourless title compound Tb2Se2O7 (≡ Tb2O [SeO3]2, terbium(III) oxide oxoselenate(IV)) was obtained by reacting a mixture of Tb4O7, Tb and SeO2 in a 3:2:14-molar ratio at 850 °C for seven days in an evacuated silica vessel as needle-shaped single crystals. It crystallizes tetragonally (space group: P42/ncm, a = 1…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyInorganic Chemistry and Materials

Magnetic properties of large-area particle arrays fabricated using block copolymer lithography

Jay Cheng、C. A. Ross、Edwin L. Thomas 等 6 位作者2002-09-01IEEE Transactions on Magnetics

50-nm period arrays of Co particles with widths of 35 nm and heights of 5-20 nm have been made using a self-assembled block copolymer lithography. The magnetic particles have in-plane anisotropy due to their shape, and show thermally activated reversal with an activation volume larger than their physical volume, which…

Theoretical and Computational PhysicsBlock Copolymer Self-AssemblyAdvanced Mathematical Modeling in Engineering

MAGNETIC DAMPING OF g-JITTER INDUCED DOUBLE-DIFFUSIVE CONVECTION

Chi‐Wang Shu、B. Q. Li、H. C. de Groh2002-09-01Numerical Heat Transfer Part A Applications

This article describes a numerical study of g-jitter driven double-diffusive convective flows and thermal and concentration distributions in binary alloy melt systems subject to an external magnetic field. The study is based on the finite element solution of transient magnetohydrodynamic equations governing the moment…

Solidification and crystal growth phenomenaMetallurgical Processes and ThermodynamicsFluid Dynamics and Thin Films

New Magnetic Functionalities Presented by Prussian Blue Analogues

Shin‐ichi Ohkoshi、Kazuhito Hashimoto2002-09-01The Electrochemical Society Interface

Molecular magnetism has been one of the active areas in molecular chemistry for the last 15 years. The advantages of molecule-based magnets compared to classical metal and metal oxide ones are that the magnets can be obtained through a selection of proper spin sources (e.g., transition metal ions, organic radicals) an…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Adamantane Selective Hydroxylation by 2,6-Dichloropyridine N-Oxide and Organoruthenium(II) Polyoxometalates as Catalyst Precursors

Marcella Bonchio、Gianfranco Scorrano、P. Toniolo 等 6 位作者2002-09-01Advanced Synthesis & Catalysis

Organoruthenium polyoxometalates with general formula [{Ru(C6Me6)}3M5O18], M  Mo, W, serve as catalyst precursors, together with 2,6-dichloropyridine N-oxide, to effect the hydroxylation of adamantane with conversion up to 94%, and C3-H/C2-H selectivity >100. Under analogous conditions, hydroxylation of cis-decalin o…

Polyoxometalates: Synthesis and ApplicationsSynthetic Organic Chemistry MethodsOxidative Organic Chemistry Reactions

Tetragonal low-temperature phase of MgCr 2 O 4

Helmut Ehrenberg、Michael Knapp、Carsten Baehtz 等 4 位作者2002-09-01Powder Diffraction

Magnesiumchromite, MgCr 2 O 4 , undergoes a structural transition from a cubic spinel structure [space group Fd 3 m, a=8.32768(4) Å at 16 K] into a tetragonal distorted structure [space group I4 1 /amd, a=5.89199(5) Å, c=8.31677(8) Å at 10 K], isotypic with Hausmannite, Mn 3 O 4 . This phase transition is translatione…

Multiferroics and related materialsAdvanced Condensed Matter PhysicsX-ray Diffraction in Crystallography

Loss evaluation of induction motor by using magnetic hysteresis E&S/sup 2/ model

Masato Enokizono、Hiroyasu Shimoji、T. Horibe2002-09-01IEEE Transactions on Magnetics

This paper presents calculated results of iron loss distribution in an induction motor model core. The authors have analyzed the induction motor model by using the improved finite-element method considering the vector magnetic properties. The vector magnetic properties are the relationship between the measured magneti…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Modern Coordination Chemistry–The Legacy of Joseph Chatt

作者信息未提供2002-09-01Chemistry International

organic chemistry appear different from those found in other comparable textbooks (e.g.,

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesAdvanced NMR Techniques and Applications

SYNTHESIS OF ISOMERS OF ORGANOTIN SUBSTITUTED POLYOXOTUNGSTATES AND COMPARISON OF THE ANTITUMOR ACTIVITY OF ISOMERS

Xiaohong Wang、Jutao Liu、Rongchang Zhang 等 5 位作者2002-09-01Main Group Metal Chemistry

Article SYNTHESIS OF ISOMERS OF ORGANOTIN SUBSTITUTED POLYOXOTUNGSTATES AND COMPARISON OF THE ANTITUMOR ACTIVITY OF ISOMERS was published on September 1, 2002 in the journal Main Group Metal Chemistry (volume 25, issue 9).

Polyoxometalates: Synthesis and ApplicationsChemical Synthesis and ReactionsVanadium and Halogenation Chemistry

Comparison Study of Mixing Effect on Batch Cooling Crystallization of 3-Nitro-1,2,4-triazol-5-one (NTO) Using Mechanical Stirrer and Ultrasound Irradiation

Y. H. Kim、Kangtaek Lee、Kee‐Kahb Koo 等 5 位作者2002-09-01Crystal Research and Technology

The insensitive explosive 3-Nitro-1,2,4-triazol-5-one (NTO) has been recrystallized from water in an effort to prepare crystals with smaller size and narrower distribution in a batch cooling crystallizer. Two mixing devices, i.e., a mechanically stirred system with and without ultrasound in aqueous media were employed…

Energetic Materials and CombustionCrystallization and Solubility Studies

Low-field magnetic properties as indication of disorder, frustration and cluster formation effects in La1−xCaxMn1−yFeyO3

R. Laiho、K.G. Lisunov、E. Lähderanta 等 5 位作者2002-09-01Journal of Magnetism and Magnetic Materials

Low-field (B=2–80 G) DC magnetic susceptibility, χ, is investigated in ceramic La1−xCaxMn1−yFeyO3 (LCMFO) samples with x=0.3. When y is increased from 0 to 0.1 the ferromagnetic (FM) Curie temperature, TC, decreases from 259 to 107 K, indicating growth of disorder by iron doping. A transformation of LCMFO from a weakl…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Cation Ordering in Pb(Mg 1/3 Nb 2/3 )O 3 –Pb(Sc 1/2 Nb 1/2 )O 3 (PMN–PSN) Solid Solutions

Leon Farber、Matjaž Valant、Mehmet A. Akbas 等 4 位作者2002-09-01Journal of the American Ceramic Society

Extended thermal annealing treatments were used to modify the B‐site cation order in the (1 − x )PMN– x PSN perovskite system (where PMN is lead magnesium niobate, Pb(Mg 1/3 Nb 2/3 )O 3 , and PSN is lead scandium niobate, Pb(Sc 1/2 Nb 1/2 )O 3 ). Extensive 1:1 ordering could be induced in compositions with x ≥ 0.1. Th…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Two-directional N2 desorption in thermal dissociation of N2O on Rh(110), Ir(110), and Pd(110) at low temperatures

Hideyuki Horino、Izabela I. Rzeźnicka、Anton Kokalj 等 7 位作者2002-09-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Two-directional N2 desorption was found in N2O dissociation on Rh(110), Ir(110), and Pd(110) below 160 K by angle-resolved thermal desorption. N2O(a) is mostly dissociated during heating procedures, emitting N2(g) and leaving O(a). N2 showed four desorption peaks in the temperature range of 110–200 K. One of them comm…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceAmmonia Synthesis and Nitrogen Reduction

Objective Evaluation of the Trash and Color of Raw Cotton by Image Processing and Neural Network

Tae Jin Kang、Soo Chang Kim2002-09-01Textile Research Journal

The trash and color of raw cotton are very important and decisive factors in the current cotton grading system. In this paper, an image system is developed that can characterize trash from a raw cotton image captured by a color CCD camera and acquire color parameters. The number of trash particles and their content, s…

Textile materials and evaluationsIndustrial Vision Systems and Defect DetectionResearch in Cotton Cultivation

Effect of added Cu on disorder-order transformation of L1/sub 0/-FePt

Tomoki Maeda、Akira Kikitsu、Tadashi Kai 等 6 位作者2002-09-01IEEE Transactions on Magnetics

The L1/sub 0/-FePt ordered phase is formed at lower annealing temperature by addition of Cu. FePtCu films start ordering at 300/spl deg/C or a lower temperature, whereas FePt and FePtAg films are still disordered alloys after annealing at 300/spl deg/C. The results of X-ray diffraction indicate that FePt and the added…

Microstructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsMetallurgical and Alloy Processes

Synthesis of Mono-Dispersed Mesoporous Silica Spheres with Hexagonal Symmetry

Kazuhisa Yano、Noritomo Suzuki、Yuusuke Akimoto 等 4 位作者2002-09-01Bulletin of the Chemical Society of Japan

Abstract Mono-dispersed mesoporous silica spheres with ordered hexagonal regularity were synthesized from tetramethoxysilane and dodecyltrimethylammonium bromide as a surfactant under very specific conditions. By adjusting the optimum concentrations of the reactants, silica particles with diverse morphology were obtai…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisPolyoxometalates: Synthesis and Applications