Materials Literature
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Do início do século passado aos dias atuais o uso dos polímeros tem se tornado cada vez mais freqüente na sociedade. Existe uma incrível quantidade de artigos que utilizam polímeros como matéria-prima para suas diferentes elaborações. A busca inicial por polímeros sintéticos esteve baseada em sua relativa inércia e re…
Nano nickel zinc ferrite (Ni0.58Zn0.42Fe2O4) with fascinating dielectric properties which reveal a direction for application was synthesized by reverse micelle technique. Dielectric constant and dielectric losses are controlled up to a measurement temperature of around 473K at higher frequency range of 9–19MHz. The di…
Based on the first-principles calculations, the electronic structure and magnetic properties of Fe-doped In2O3 were theoretically investigated. The presence of the predominating defects in oxide, i.e., oxygen vacancies, can lead to strong ferromagnetic coupling between the nearest neighboring Fe cations. Spin density…
A strong excitonic optical transition in a Zn1−xMgxO alloy grown by radical source molecular beam epitaxy was observed using both optical reflectivity measurements and photoluminescence (PL) measurements. Clear and strong reflectance peaks at room temperature (RT) were observed from 3.42eV (x=0.05)to4.62eV (x=0.61) fr…
The generally observed bipolar electrical switching of Cu\CuTCNQ\metal memories (metal=Al,Yb,Ti) between two stable resistance states is shown to occur at the CuTCNQ\metal interface and not in the bulk of CuTCNQ. The switching is explained by a model involving electrochemical formation and dissolution of Cu filaments…
In this paper, the elastic and plastic properties of single-walled carbon nanocones (CNCs) under tension are investigated employing molecular dynamics simulation. The force-deformation responses of CNCs are obtained and compared with those of carbon nanotubes (CNTs). CNCs with a larger apex angle present a larger fail…
Ferroelectric switching behavior of single-crystal-like epitaxial Pb(Zr0.2Ti0.8)O3 thin films with different densities of 90° domain walls was investigated under various applied fields. It was found that the saturated switchable polarization of about 170μC∕cm2 did not vary with applied field in the films with low dens…
Vertically aligned multiwalled carbon nanotubes (MWCNTs) were synthesized by remote plasma chemical vapor deposition at a low temperature of 390°C, which meets the requirement of the large scale integration (LSI) process. For wiring application, we measured the electrical properties of MWCNT-via structures with and wi…
High quality vanadium sesquioxide V2O3 films (170–1100Å) were grown using the pulsed laser deposition technique on (0001)-oriented sapphire substrates, and the effects of film thickness on the lattice strain and electronic properties were examined. X-ray diffraction indicates that there is an in-plane compressive latt…
We investigate the hole spin-3/2 relaxation process induced by nonadiabatic stochastic modulations of the instantaneous Luttinger Hamiltonian. The theory allows to consider fluctuations of both the direction and the magnitude of a hole wave vector in all regimes of momentum scattering: from collision-dominated to ball…
The crystallographic structure of (Na,K)NbO3-based compounds and phase transitional behavior in (1−x)(K0.5Na0.5)NbO3–xLiNbO3 (x=0, 3, 6, and 8mol%) ceramics were accurately determined using high resolution x-ray diffraction (XRD). The phase transition between orthorhombic and tetragonal was distinctly characterized fo…
In this work, we present approximate analytical predictions for the contribution to the free energy of curvature of a thin (flexible) membrane rising from a polymer brush, which is grafted to both sides of the membrane. The influence of the approximations is revealed by a detailed comparison with numerically exact sel…
Time-resolved in situ Raman spectroscopy and small-angle X-ray diffraction have been combined in order to characterize the formation of hexagonal mesostructured SBA-3 silica. Experiments were performed under identical synthesis conditions in order to correlate the molecular and mesoscopic scales. Cetyltrimethylammoniu…
The formation of radicals from the gas-phase pyrolysis of phenol over a temperature range of 400-1000 degrees C was studied using the technique of low temperature matrix isolation electron paramagnetic resonance (LTMI EPR). Cooling the reactor effluent in a CO2 carrier gas to 77 K produces a cryogenic matrix that exhi…
The current paper discusses the preparation, characterization, and clarification of the growth mechanism of PbS wires, ribbons, octapods, and hollowed cubes. Those sub-micrometer structures were prepared by a thermal decomposition of a uni-precursor {[Pb(S(2)CNEt(2))(2)](2)}, using either ethylene diamine (en) or ethy…
Dendrons Gn-Cl and Gn-NH (n = 2-4) and novel dendrimers Gn-N approximately N-Gn (n = 2-4) based on triazine and piperazine units were efficiently prepared in good yields without employing the protection and deprotection processes and are fully characterized by 1H NMR and 13C NMR spectroscopies, elemental analysis, and…
We constructed a new plasmid vector for the production of a modified silk fibroin heavy chain protein (H-chain) in the transgenic silkworm. The plasmid (pHC-null) contained the promoter and the 3' region of a gene encoding the H-chain and the coding regions for the N-terminal domain and the C-terminal domain of the H-…
Molecular self-assembly is emerging as a viable "bottom-up" approach for fabricating nanostructures. Self-assembled biomolecular structures are particularly attractive, due to their versatile chemistry, molecular recognition properties, and biocompatibility. Among them, amyloid protein and peptide fibrils are self-ass…
High Resolution Image Download MS PowerPoint Slide We report measurements of the effective thermal conductivity of dispersions of single-wall carbon nanotubes in technologically important fluids: (poly)-alpha olefins and ethylene glycol. The morphology of this dispersion was studied using rheology, AFM, and light scat…
A combination of immiscible molecules in the ligand shell of a gold nanoparticle (NP) has been shown to phase separate into a rippled structure; this phase separation can be used to direct the assembly of the NPs into chains. Here we demonstrate that only NPs within a certain size range can form chains, and we conclud…