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Elastic and thermal properties of the layered compound (CH3NH3)2FeCl4

T. Goto、M. Yoshizawa、Akira Tamaki 等 4 位作者1982-05-20Journal of Physics C Solid State Physics

Several elastic constants of the perovskite-type layer-structure compound (CH 3 NH 3 ) 2 FeCl 4 have been measured. The anomaly of the C 66 mode and the lambda -type heat capacity near the structural phase transition from the tetragonal high-temperature phase to the orthorhombic room-temperature phase gave the critica…

Perovskite Materials and ApplicationsOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

Freely Suspended Strands of Tilted Columnar Liquid-Crystal Phases: One-Dimensional Nematics with Orientational Jumps

David H. Van Winkle、Noel A. Clark1982-05-17Physical Review Letters

Observations of stable, freely suspended liquid-crystal strands are reported. Liquid crystals of triphenylene hexa-$n$-dodecanoate can be stretched into strands of diameter \ensuremath{\gtrsim}1 \ensuremath{\mu}m, with the disk-shaped molecules arranged into columns along the strand axis. In the $D1$ phase ($T<110\…

Liquid Crystal Research AdvancementsNonlinear Dynamics and Pattern FormationMolecular spectroscopy and chirality

Oxygen nonstoichiometry of tantalum-doped calcium titanate

U. Balachahdean、N.G. Eror1982-05-16physica status solidi (a)

The reversible change of oxygen content observed by gravimetric measurements on tantalum (donor)-doped calcium titanate between P02 = 10−16 and 1 atm is proportional to the dopant concentration. These measurements indicate that the tantalum addition is compensated by additional oxygen uptake in the oxidized state. The…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Thermoelectric properties and phase transitions in Bi2Te3 under hydrostatic pressure up to 9 GPa and temperature up to 300 °C

L. G. Khvostantsev、A. I. Orlov、N. Kh. Abrikosov 等 5 位作者1982-05-16physica status solidi (a)

The thermoelectric tensor component S11 and the relative electrical resistance along the binary axis of Bi2Te3 single crystals of p- and n-type are measured under hydrostatic pressure up to 9 GaP and temperatures from 20 to 300 °C. A P-T phase diagram of bismuth telluride is proposed, which is different from diagram,…

Advanced Thermoelectric Materials and DevicesTopological Materials and PhenomenaAdvanced Thermodynamics and Statistical Mechanics

The structure of {1121} twin boundaries in H.C.P. crystals

Y. Minonishi、Shunya Ishioka、M. Koiwa 等 4 位作者1982-05-16physica status solidi (a)

A computer simulation study is made on the atomic structure of {1121} twin boundary using a truncated Lennard-Jones potential. It is found that twinned crystals never satisfy the mirror symmetry: in the twin, the alternate basal plane sare displaced by a √3/12 normal to the plane of shear in the opposite direction and…

Advanced Chemical Physics StudiesRare-earth and actinide compoundsQuasicrystal Structures and Properties

Epitaxy of CuI on Cu(111)

S. B. DiCenzo、G. K. Wertheim、D. N. E. Buchanan1982-05-15Applied Physics Letters

Thin epitaxial films of CuI have been grown on clean Cu(111) surfaces by chemical reaction with iodine vapor. A lattice match is obtained because the iodine (111) planes of CuI have the same symmetry and approximately the same spacing as the (√3×√3)R30° iodine adsorbate layer which forms initially on exposure of clean…

ZnO doping and propertiesCopper Interconnects and ReliabilityCopper-based nanomaterials and applications

Reflectance spectrum of crystalline and vitreous SiO2at low temperature

M. Rossinelli、M. A. Bösch1982-05-15Physical review. B, Condensed matter

The vacuum ultraviolet reflectance spectrum of crystalline and vitreous Si${\mathrm{O}}_{2}$ has been measured at low temperature. We find only minor differences between the room-temperature and 5-K spectra of both crystalline and vitreous Si${\mathrm{O}}_{2}$. These observations impose restrictions on the models to e…

Glass properties and applicationsThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence

Effect of radiation damage on the metal-insulator transition and low-temperature transport in the tetramethyltetraselenofulvalinium PF6salt [(TMTSF)2PF6]

Moo‐Yeol Choi、P. M. Chaikin、S. Z. Huang 等 6 位作者1982-05-15Physical review. B, Condensed matter

We have measured the resistance, magnetoresistance, and nonlinear conductivity in a series of tetramethyltetraselenofulvalinium phosphorus hexafluoride [${(\mathrm{TMTSF})}_{2}$P${\mathrm{F}}_{6}$] crystals which have been damaged with 2.5-MeV protons. For radiation dosages which correspond to \ensuremath{\sim}400-ppm…

Magnetism in coordination complexesRare-earth and actinide compoundsOrganic and Molecular Conductors Research

Optical spectra, energy levels, and crystal-field analysis of tripositive rare-earth ions in Y2O3. II. Non-Kramers ions in C2 sites

Richard P. Leavitt、John B. Gruber、N. C. Chang 等 4 位作者1982-05-15The Journal of Chemical Physics

Optical absorption and fluorescence spectra of the non-Kramers ions Pr3+, Tb3+, and Ho3+ in the C2 sites of Y2O3 are reported. A crystal-field analysis of these data and previously reported data for Eu3+ and Tm3+ is performed that is based on a Hamiltonian of C2 point-group symmetry, including J-mixing effects. A best…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsLanthanide and Transition Metal Complexes

Mechanical properties of chitosan films: Effect of solvent acid

Carlos A. Kienzle‐Sterzer、Dolores Rodriguez‐Sanchez、ChoKyun Rha1982-05-14Die Makromolekulare Chemie

Abstract The apparent Young's modulus shows a linear relationship with junction density of chitosan films. The linear relationship of apparent Young's modulus with chitosan concentration is also observed. The linear relationship depends of the acid used in the casting solution. Relaxation times were of the order of 10…

Nanocomposite Films for Food PackagingConducting polymers and applicationsPolymer Surface Interaction Studies

Liquid crystalline side chain polymers and their behaviour in the electric field

Helmut Ringsdorf、Rudolf Zentel1982-05-14Die Makromolekulare Chemie

Abstract The electro‐optical properties of liquid crystalline polymers with polar mesogenic units in the side chain were investigated. It could be shown, that in an electric field, they show all effects known from low molecular weight liquid crystals, e.g. the Freedericksz‐transition, the DAP‐effect, the formation of…

Organic Electronics and PhotovoltaicsLiquid Crystal Research AdvancementsNonlinear Optical Materials Research

Complete amino acid sequence of human brain calmodulin

Tatsuru Sasagawa、Lowell H. Ericsson、Kenneth A. Walsh 等 6 位作者1982-05-11Biochemistry

The complete amino acid sequence of calmodulin from human brain has been determined by using peptides derived from digests with trypsin. Staphylococcus aureus V8 protease, and cyanogen bromide. The peptides were purified by means of reversed-phase high-performance liquid chromatography and analyzed with a sequenator.…

Protein Structure and DynamicsRNA and protein synthesis mechanismsEnzyme Structure and Function

Calcium-dependent .alpha.-helical structure in osteocalcin

Peter V. Hauschka、Steven A. Carr1982-05-11OpenAlex

Osteocalcin is an abundant Ca2+-binding protein of bone containing three residues of vitamin K dependent gamma-carboxyglutamic acid (Gla) among its 49 (human, monkey, cow) or 50 (chicken) amino acids. Gla side chains participate directly in the binding of Ca2+ ions and the adsorption of osteocalcin to hydroxylapatite…

Enzyme Structure and FunctionMolecular spectroscopy and chiralityVitamin K Research Studies

Bird impact analysis package for turbine engine fan blades

M. S. Hirschbein1982-05-1023rd Structures, Structural Dynamics and Materials Conference

A computer program has been developed to analyze the gross structural response of turbine engine fan blades subjected to bird strikes. The program couples a NASTRAN finite element model and modal analysis of a fan blade with a multi-mode bird impact analysis computer program. The impact analysis uses the NASTRAN blade…

High Temperature Alloys and CreepHigh-Velocity Impact and Material BehaviorBladed Disk Vibration Dynamics

The crystal structure of tetragonal KH2PO4 and KD2PO4 as a function of temperature

R. J. Nelmes、G. Meyer、J. E. Tibballs1982-05-10Journal of Physics C Solid State Physics

The structures of the paraelectric (tetragonal) phase of KH2PO4 (KDP) and 95% deuterated KD2PO4 (DKDP) have been investigated using high-resolution (sin theta bmax/ lambda >1.1 AA-1) single-crystal neutron-diffraction techniques. Full three-dimensional data have been collected at Tc+5K and Tc+ approximately 150K for b…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Cation size effect on ionic thermocurrents in alkali halides

F. Cussó、F. Jaqué1982-05-10Journal of Physics C Solid State Physics

An experimental study of ionic thermocurrents in doped LiF, NaCl, KBr and KI has been carried out in order to study the dependence of the activation parameters with the ionic radius of the impurity R i . A simple model, which includes lattice distortion around the impurity, has also been developed. This model can expl…

Solid-state spectroscopy and crystallography

Evidence for a common origin of the Urbach tails in amorphous and crystalline semiconductors

D. J. Dunstan1982-05-10Journal of Physics C Solid State Physics

The absolute strengths of the exponential absorption tails of amorphous semiconductors can be correctly predicted from the band-to-band absorption spectra and the exponents of the tails only. This result shows that the tails are due to transitions between band-derived states, and that the mechanism giving rise to thes…

Glass properties and applicationsThin-Film Transistor TechnologiesPhase-change materials and chalcogenides

The structure and mechanism of formation of platelets in natural type Ia diamond

P. Humble1982-05-08Proceedings of the Royal Society of London A Mathematical and Physical Sciences

Abstract Observations have been made on medium- and large-sized platelets in a natural type Ia diamond. Attempts have been made to detect any regularity in the structure of the platelets by means of electron diffraction, but none was found. The displacement associated with the platelets has been determined to be extri…

Metal and Thin Film MechanicsHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

The kinetics of the aggregation of nitrogen atoms in diamond

T. Evans、Zengdu Qi1982-05-08Proceedings of the Royal Society of London A Mathematical and Physical Sciences

Abstract Most natural diamonds contain nitrogen as the main impurity. In some rare diamonds (termed type lb) the nitrogen is mainly present as single substitutional atoms. However, the large majority of diamonds (termed type Ia) contain the nitrogen atoms in various forms of aggregate. The different types of aggregate…

Geological and Geochemical AnalysisHigh-pressure geophysics and materialsDiamond and Carbon-based Materials Research

A theory of orientational ordering in uniaxial liquid crystals composed of molecules with alkyl chains

J.W. Emsley、G. R. Luckhurst、C.P. Stockley1982-05-08Proceedings of the Royal Society of London A Mathematical and Physical Sciences

Abstract The constituent molecules of thermotropic liquid crystals invariably contain an aromatic core to which is attached one and often two n-alkyl chains. Nuclear magnetic resonance investigations have revealed that the chain does not exist entirely in an all-trans configuration and that the orientational order of…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesMolecular spectroscopy and chirality